Sicil:72839 (ER:3063757) Numaralı II-A Grup Ruhsat Sahasına Ait UMREK- 2023 Kodlu Değerlendirme Raporu Ekleri Cilt 2

VİŞNE MADENCİLİK ÜRETİM SANAYİ VE TİC.

A. Ş.

Mustafa Kemal Mahallesi 2131. Cadde Aslanlar Plaza No:24/11 06510 Çankaya /ANKARA – TÜRKİYE T +90 312 503 73 99 • F +90 312 503 73 98 www.mitus.com.tr • [email protected]

Sicil:72839 (ER:3063757) Numaralı

II-A Grup Ruhsat Sahasına Ait

UMREK- 2023 Kodlu Değerlendirme Raporu Ekleri

VİŞNE MADENCİLİK ÜRETİM SANAYİ VE TİC. A.Ş.

için hazırlanmıştır.

1:2000 ÖLÇEKLİ DETAY MADEN JEOLOJİ HARİTASI

Mustafa Kemal Mahallesi 2131. Cadde Aslanlar Plaza No:24/11 06510 Çankaya /ANKARA – TÜRKİYE T +90 312 503 73 99 • F +90 312 503 73 98 www.mitus.com.tr • [email protected]

MİTUS ARAMA VE PROJE AŞ.

SONDAJ LOGU BOREHOLE LOG

TARİH : Date	25.01.2024
SONDAJ JEOLOĞU : Borehole Geologist	Jeo. Müh. M. Avni TAPTIK
KONTROL EDEN : Controlling	Jeo.Yük. Müh. Deniz GÖÇ

	PROJE ADI : (Project Name) LOKASYON : MADENİN CİNSİ : (Type of Ore)	ER NO : (Location)	3063757 Kalker			ER3063757_Vişne Madencilik Adana/ Ceyhan (Çokcapınar)			SONDAJ KOTU : (Borehole Elevation) (Borehole Depth) EĞİM YÖNÜ : (Dip direction)	90 EĞİM : (Dip) 0	181.102 107	BAŞLAMA TARİHİ : (Starting Date) BİTİŞ TARİHİ : (Ending Date) LOG ÖLÇEĞİ : (Log Scale)	KUYU ADI (Borehole Name)	28.12.2024 2.01.2024 1/100				KOOR. SİSTEMİ : (Coordinate Sysytem) X (KUZEY) : 743226 (X-Northing) Y (DOĞU) : (Y-Easting)	CVR-1	4098166	ED-50_Zon36
Derinlik (m) Depth (m)	Core Diameter Karot Çapı	Manevra Boyu (m) Run Length (m)	Core Length (m) Karot Boyu	3 Yoğunluk (gr/cm ) 3 İntensity (gr/cm )	Total Core Recovery Karot TCR (%)	Rock Quality Des RQD (%)	LİTOLOJİ Lithology	TANIMLAMA Description	Derinlik (m) Depth (m)	Numune No Sample No	Min-Pet/XRD Analiz Sonuçları Min-Pet/XRD Analysis Results Tanımlama Description	Derinlik (m) Depth (m)	Numune No Sample No	Al O % 3 2	CaO %	SiO % 2	Fe O % 32	Kimyasal Analiz Sonuçları Chemical Analysis Results MnO%	Cr O % 32	MgO%	TiO % 2	A.Z%
0 1 2 3	89 mm							(0.00-5.00) Dolomitic Limestone: Ayrışma yüzeyi gri, açık gri, taze kırık yüzeyi kirli beyaz renkli olup, sparitik dokulu, bol kırıklı ve çatlaklıdır.				0	18101	0.82	55.74	1.61	0.44	<0.01	<0.01	1.26	<0.01	39.98
4 5 6								(5.00-51.00) Limestone: Ayrışma yüzeyi gri, açık gri, taze kırık yüzeyi beyaz, bej, kirli beyaz renkli olup, mikritik				5
7 8 9	89 mm							dokulu, bol kırıklı ve çatlakllıdır.					18102/ 18103	0.2	55.79 5	0.36	0.09	<0.01	<0.01	0.25	<0.01	43.21
10 11 12 13	89 mm											10	18104	0.16	55.49	0.3	0.07	<0.01	<0.01	0.28	<0.01	43.59
14 15 16												15
17 18 19	89 mm												18105	0.15	55.79	0.24	0.06	<0.01	<0.01	0.29	<0.01	43.39
20 21 22 23												21
24 25 26	89 mm											26	18106	0.29	55.75	0.54	0.12	<0.01	<0.01	0.33	<0.01	42.85
27 28 29 30	89 mm												18107	0.21	55.96	0.48	0.06	<0.01	<0.01	0.34	<0.01	42.84
31 32 33												31
34 35 36	89 mm											36	18108	0.24	55.73	0.39	0.1	<0.01	<0.01	0.33	<0.01	43.09
37 38 39 40	89 mm												18109	0.12	55.86	0.21	0.07	<0.01	<0.01	0.27	<0.01	43.35
41 42 43												41
44 45 46	89 mm											46	18110	0.75	54.3	2.08	0.28	<0.01	<0.01	0.37	<0.01	41.98
47 48 49 50	89 mm												18111	0.2	55.62	0.8	0.07	<0.01	<0.01	0.27	<0.01	42.93
51 52 53	89							(51.00-56.00) Dolomitic Limestone: Ayrışma yüzeyi gri, açık gri, taze kırık yüzeyi kirli beyaz renkli olup, sparitik dokulu, bol kırıklı ve çatlaklıdır.				51	18112	0.15	43.68	1.01	0.05	<0.01	<0.01	10.86	<0.01	44.12
54 55 56 57	mm							(56.00-81.00) Limestone: Ayrışma yüzeyi gri, açık gri, taze kırık yüzeyi beyaz, bej, kirli beyaz				56
58 59 60	89 mm							renkli olup, mikritik dokulu, bol kırıklı ve çatlakllıdır.					18113	0.34	55.67	0.44	0.11	<0.01	<0.01	0.33	<0.01	42.98
61 62 63 64	89 mm											61	18114	0.43	55.88	0.69	0.15	<0.01	<0.01	0.66	<0.01	41.98
65 66 67												66
68 69 70	89 mm												18115	0.2	55.53	0.43	0.07	<0.01	<0.01	0.27	<0.01	43.35
71 72 73 74	89 mm											71	18116	0.48	55.43	2.37	0.15	<0.01	<0.01	0.33	<0.01	41.08
75 76 77												76
78 79 80 81	89 mm							(81.00-86.00) Dolomitic				81	18117	0.17	55.52	0.25	0.04	<0.01	<0.01	0.42	<0.01	43.48
82 83 84	89 mm							Limestone: Ayrışma yüzeyi gri, açık gri, taze kırık yüzeyi kirli beyaz renkli olup, sparitik dokulu, bol kırıklı ve çatlaklıdır.					18118	1.91	50.02	7.4	1.13	<0.01	<0.01	1.15	<0.01	37.76
85 86 87 88								(86.00-96.00) Limestone: Ayrışma yüzeyi gri, açık gri, taze kırık yüzeyi beyaz, bej, kirli beyaz renkli olup, mikritik dokulu, bol kırıklı ve çatlakllıdır.				86
89 90 91	89 mm											91	18119	0.3	55.94	0.53	0.11	<0.01	<0.01	0.41	<0.01	42.53
92 93 94 95	89 mm												18120/ 18121	0.545	55.87	1.455	0.295	<0.01	<0.01	0.485	<0.01	41.14
96 97 98								(96.00-107.00) Shale-Conglomerate Mudstone-Sandtsone Clayey Limestone: Ruhsat alanı içerisinde yaklaşık GB- KD doğrultusunda uzanan birim, farklı tür ve yaşta bloklar kapsayan;				96
99 100 101	89 mm							şeyl, çakıltaşı, çamurtaşı, kumtaşı ve killi kireçtaşı yer alamaktadır. Birimin hamurunu; açık sarı, krem, boz renkli ince kaba taneli, volkanik elemanlı çakıltaşı, siyah, siyahımsı yeşil renkli şeyl, yer yer tüf- tüfit ve volkanitten türemiş kumtaşları oluşturmaktadır.				101	18122	2.91	44.19	12.13	1.76	0.06	<0.01	1.93	<0.01	36.16
102 103 104 105	89 mm												18123	5.14	27.78	22.06	3.22	0.08	<0.01	3.86	0.31	36.16
106 107

TARİH : Date	25.01.2024
SONDAJ JEOLOĞU : Borehole Geologist	Jeo. Müh. M. Avni TAPTIK
KONTROL EDEN : Controlling	Jeo.Yük. Müh. Deniz GÖÇ

	PROJE ADI :	MİTUS ARAMA VE PROJE AŞ.				ER3063757_Vişne Madencilik				SONDAJ KOTU :		SONDAJ LOGU BOREHOLE LOG 209.953		KUYU ADI						CVR-2		EK 2
	(Project Name) LOKASYON : MADENİN CİNSİ :	ER NO : (Location)	3063757 Kalker			Adana/ Ceyhan (Çokcapınar)			(Borehole Elevation) SONDAJ DERİNLİĞİ :	(Borehole Depth) EĞİM YÖNÜ :	EĞİM : (Dip) 0	143.00 90	BAŞLAMA TARİHİ : (Starting Date) BİTİŞ TARİHİ : (Ending Date) LOG ÖLÇEĞİ :	(Borehole Name)	3.01.2024 4.01.2024 1/100				KOOR. SİSTEMİ : (Coordinate Sysytem) X (KUZEY) : 743172 (X-Northing) Y (DOĞU) :		4098017	ED-50_Zon36
	(Type of Ore)	Manevra Boyu (m)		3 Yoğunluk (gr/cm ) 3	Total Core Recovery		LİTOLOJİ Lithology	TANIMLAMA Description		(Dip direction)		Min-Pet/XRD Analiz Sonuçları Min-Pet/XRD Analysis Results Tanımlama	(Log Scale)						(Y-Easting) Kimyasal Analiz Sonuçları Chemical Analysis Results
Derinlik (m) Depth (m) 0	Core Diameter Karot Çapı	Run Length (m)	Core Length (m) Karot Boyu	İntensity (gr/cm )	Karot TCR (%)	Rock Quality Des RQD (%)		(0.00-102.00) Limestone: Ayrışma yüzeyi gri, açık gri, taze kırık yüzeyi		Derinlik (m) Depth (m)	Numune No Sample No	Description	Derinlik (m) Depth (m) 0	Numune No Sample No	Al O % 3 2	CaO %	SiO % 2	Fe O % 32	MnO%	Cr O % 32	MgO%	TiO % 2	A.Z%
1 2 3	89 mm							beyaz, bej, kirli beyaz renkli olup, mikritik dokulu, bol kırıklı ve çatlakllıdır.						18124	0.14	55.48	0.25	0.06	<0.01	<0.01	0.31	<0.01	43.69
4 5 6													5
7 8	89 mm													18125	0.05	55.49	0.15	0.02	<0.01	<0.01	0.32	<0.01	43.89
9 10 11													10
12 13 14	89 mm													18126	0.59	55.56	1.2	0.33	<0.01	<0.01	0.57	<0.01	41.65
15 16 17													15
18 19	89 mm													18127	0.08	55.44	0.14	0.04	<0.01	<0.01	0.95	<0.01	43.28
20 21 22													20
23 24 25	89 mm												25	18128	0.06	55.6	0.1	0.02	<0.01	<0.01	0.29	<0.01	43.83
26 27 28	89 mm													18129	0.05	55.87	0.08	0.02	<0.01	<0.01	0.25	<0.01	43.65
29 30													30
31 32 33	89 mm													18130	0.03	55.94	0.06	0.02	<0.01	<0.01	0.3	<0.01	43.58
34 35 36													35
37 38	89 mm													18131	0.04	55.61	0.07	0.02	<0.01	<0.01	0.31	<0.01	43.88
39 40 41													40
42 43 44	89 mm													18132	0.16	55.5	0.33	0.05	<0.01	<0.01	0.31	<0.01	43.57
45 46 47													46
48 49	89 mm													18133	0.18	54.06	5.26	0.07	<0.01	<0.01	0.28	<0.01	40.04
50 51 52													51
53 54 55	89 mm													18134	0.13	55.42	0.33	0.04	<0.01	<0.01	0.31	<0.01	43.67
56 57													56
58 59 60	89 mm													18135	0.43	55.63	1.22	0.19	0.02	<0.01	0.45	<0.01	41.89
61 62 63													61
64 65 66	89 mm													18136	0.19	55.77	0.43	0.09	<0.01	<0.01	0.31	<0.01	43.12
67 68	89												66	18137	0.19	55.75	0.31	0.07	<0.01	<0.01	0.19	<0.01	43.36
69 70 71	mm												71
72 73 74	89 mm													18138	0.68	55.95	1.24	0.21	<0.01	<0.01	0.38	<0.01	41.33
75 76													76
77 78 79	89 mm													18139/ 18163	0.365	55.92	0.735	0.165	<0.01	<0.01	0.525	<0.01	42.15
80 81 82													81
83 84 85	89 mm													18140	1.09	54.1	3.26	0.67	<0.01	<0.01	0.41	<0.01	40.16
86 87													87
88 89 90	89 mm													18141	1.04	54.71	3.09	0.59	<0.01	<0.01	0.41	<0.01	39.89
91 92 93													92
94 95 96	89 mm													18142	0.14	55.95	0.26	0.03	<0.01	<0.01	0.32	<0.01	43.18
97 98													97
99 100 101	89 mm													18143	0.5	55.98	1.83	0.34	<0.01	<0.01	0.37	<0.01	40.76
102 103 104								(102.00-123.00) Shale-Conglomerate Mudstone-Sandtsone Clayey Limestone: Ruhsat alanı içerisinde yaklaşık GB- KD doğrultusunda uzanan birim, farklı tür ve yaşta bloklar kapsayan;					102
105 106	89 mm							şeyl, çakıltaşı, çamurtaşı, kumtaşı ve killi kireçtaşı yer alamaktadır. Birimin hamurunu; açık sarı, krem, boz renkli ince kaba taneli, volkanik elemanlı çakıltaşı, siyah, siyahımsı yeşil renkli şeyl, yer yer tüf- tüfit ve						18144	8.72	23.1	33.9	5.5	0.08	<0.01	3.63	0.7	21.16
107 108 109								volkanitten türemiş kumtaşları oluşturmaktadır.					108
110 111 112	89 mm													18145	2.95	45.8	11.68	1.52	0.04	<0.01	1.47	<0.01	35.44
113 114													113
115 116 117	89 mm													18146	6.27	30.14	27.32	4.51	0.1	<0.01	4.34	0.44	24.96
118 119 120													118
121 122 123	89 mm													18147	2.9	44.98	13.29	1.87	<0.01	0.04	2.36	<0.01	33.65
124 125	89							(123.00-143.00) Dolomitic Limestone: Ayrışma yüzeyi gri, açık gri, taze kırık yüzeyi kirli beyaz renkli olup, sparitik dokulu, bol kırıklı ve çatlaklıdır.					123	18148	1.03	37.57	4.42	0.63	<0.01	<0.01	13.05	<0.01	42.99
126 127 128	mm												128
129 130 131	89 mm													18149	0.23	43.09	0.64	0.09	<0.01	<0.01	11.05	<0.01	44.72
132 133													133
134 135 136	89 mm													18150	0.26	55.19	0.55	0.1	<0.01	<0.01	2.11	<0.01	41.68
137 138 139													138
140 141 142	89 mm													18151	0.22	49.61	0.8	0.1	<0.01	<0.01	6.2	<0.01	42.93
143

MİTUS ARAMA VE PROJE AŞ.

SONDAJ LOGU BOREHOLE LOG

	PROJE ADI : (Project Name)		ER3063757_Vişne Madencilik							SONDAJ KOTU : (Borehole Elevation)		110.786			KUYU ADI (Borehole Name)						CVR-3
		ER NO :	3063757						SONDAJ DERİNLİĞİ :	(Borehole Depth)	20		BAŞLAMA TARİHİ :	(Starting Date)		4.01.2024				KOOR. SİSTEMİ : (Coordinate Sysytem)			ED-50_Zon37
	LOKASYON :	(Location)	Adana/ Ceyhan (Çokcapınar)								90 EĞİM : (Dip)			BİTİŞ TARİHİ : (Ending Date)		4.01.2024				X (KUZEY) : 337708 (X-Northing)
	MADENİN CİNSİ : (Type of Ore)		Kalker							EĞİM YÖNÜ : (Dip direction)	0			LOG ÖLÇEĞİ : (Log Scale)		1/100				Y (DOĞU) : (Y-Easting)		4133514
			3	3								Min-Pet/XRD Analiz Sonuçları Min-Pet/XRD Analysis Results								Kimyasal Analiz Sonuçları Chemical Analysis Results
Derinlik (m) Depth (m)	Core Diameter Karot Çapı	Manevra Boyu (m) Run Length (m)	Yoğunluk (gr/cm ) Core Length (m) Karot Boyu	İntensity (gr/cm )	Total Core Recovery Karot TCR (%)	Rock Quality Des RQD (%)	LİTOLOJİ Lithology	TANIMLAMA Description		Derinlik (m) Depth (m)	Numune No Sample No	Tanımlama Description		Derinlik (m) Depth (m)	Numune No Sample No	Al O % 3 2	CaO %	SiO % 2	Fe O % 32	MnO%	Cr O % 32	MgO%	TiO % 2	A.Z%
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15	89 mm 89 mm 89 mm							(0.00-5.00) Road Embankment: Sahadan çıkarılan pasa malzemesi kullanılarak yapılan yol dolgusu (5.00-20.00) Limestone: Ayrışma yüzeyi gri, açık gri, taze kırık yüzeyi beyaz, bej, kirli beyaz renkli olup, mikritik dokulu, bol kırıklı ve çatlakllıdır.						0 5 10 15	18152 18153 18154	2.9 0.85 1.05	50.03 55.64 55.56	4.66 1.45 1.64	1.11 0.27 0.32	<0.01 <0.01 <0.01	<0.01 <0.01 <0.01	0.59 0.42 0.46	0.15 <0.01 <0.01	39.88 40.98 40.67
16 17 18 19 20	89 mm														18155/ 18156	0.33	55.59	0.505	0.11	<0.01	<0.01	0.38	<0.01	42.93

25.01.2024 TARİH : Date
Jeo. Müh. M. Avni TAPTIK SONDAJ JEOLOĞU : Borehole Geologist
KONTROL EDEN : Jeo.Yük. Müh. Deniz GÖÇ Controlling

Mustafa Kemal Mahallesi 2131. Cadde Aslanlar Plaza No:24/11 06510 Çankaya /ANKARA – TÜRKİYE T +90 312 503 73 99 • F +90 312 503 73 98 www.mitus.com.tr • [email protected]

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT2330310

AGT2330310 12-2023

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 05.12.2023
İş Numarası / Job Number	: AGT2330310
Numune Sayısı / Number of Sample : 2
Proje Adı / Project	: 3063757 (Batch No: 3063757-0001)
Rapor Tarihi / Reported Date	: 07.12.2023

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES

WGHT	Received Sample Weight
PREP70-500	Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75 micron
XRF WR-01	XRF Press Pellet

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

Türk Akreditasyon Kurumu(TÜRKAK) deney raporlarının tanınması konusunda Avrupa Akreditasyon Birliği(EA) ve Uluslararası Laboratuvar Akreditasyon Birliği(ILAC) ile karşılıklı tanınma antlaşmasını imzalamıştır. / The Turkish Accreditation Agency(TURKAK) is signatory to the multilateral agreements of the European co-operation for the Accreditation(EA) and The International Laboratory Accreditation Cooperation(ILAC) for the mutual recognation of test reports. Laboratuvarımız TÜRK AKREDİTASYON KURUMU tarafından akredite edilmiştir. Akreditasyon kapsamındaki analizler "*" ile belirtilmiştir. Bu rapor laboratuvar izni olmaksızın kopyalanıp çoğaltılamaz. İmzasız ve mühürsüz raporlar geçersizdir. Sonuçlar sadece analizi yapılan numuneye aittir. Analizler kuru bazda ve 25 ± 3 °C'de yapılmıştır. / Our laboratory accredited by TURKISH ACCREDITATION AGENCY. This report shall not be reproduced other than in full except with permission of the labroratory. Testin reports witout signature and seal are not valid. Results are only belong to the analyzed sample. Analyses were made at 25 ± 3 °C. Şahit numunesinin arşivde saklama süresi 6 aydır ve analizlere ancak bu süre içinde itiraz edilebilir. Genişletilmiş ölçüm belirsizlikleri ve karar kuralı laboratuvardan talep edildiği durumlarda raporda belirtilir. / Rention period of witness samples in the archive are 6 months and analysis could have contested only during this time. Expanded measurement uncertainty and decision rule will stated in the report upon elient request. Deney ve/veya ölçüm sonuçları, genişletilmiş ölçüm belirsizlikleri (olması halinde) ve deney metodları bu sertifikanın tamamlayıcı kısmı olan takip eden sayfalarda verilmiştir. / The test and/or measurement results, the uncertaintes (if applicable) with confidence probability and test methods are given on the following pages which are part of this report.

CERTIFICATE OF ANALYSIS AGT2330310

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18549	ROCK	2.23	0.07	55.96	0.10	<0.01	<0.01	0.03	0.17	0.03	<0.01	<0.01	0.34	<0.01	<0.01	0.01	42.95
18550	ROCK	3.17	0.06	55.68	0.05	<0.01	<0.01	0.04	0.18	0.04	<0.01	<0.01	0.30	<0.01	<0.01	0.02	43.53

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240318

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240318
Numune Sayısı / Number of Sample : 5
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0002)
Rapor Tarihi / Reported Date	: 25.01.2024

		LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES
: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.		Received Sample Weight
: 17.01.2024		XRF Press Pellet
: AGT240318		Wet Method / Grav. Finish
		Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75
	MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION Numune Sayısı / Number of Sample : 5	WGHT XRF WR-01 WM LOI1000 PREP70-500

micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

Deney laboratuvarları olarak faaliyet gösteren ARGETEST TÜRKAK' tan AB-0742-T ile TS EN ISO/IEC 17025:2017 standartına göre akredite edilmiştir. ARGETEST accredited by TÜRKAK under registration number AB-0742-T for TS EN ISO/IEC 17025:2017 as test laboratory.

Laboratuvarımız TÜRK AKREDİTASYON KURUMU tarafından akredite edilmiştir. Akreditasyon kapsamındaki analizler "*" ile belirtilmiştir. Bu rapor laboratuvar izni olmaksızın kopyalanıp çoğaltılamaz. İmzasız ve mühürsüz raporlar geçersizdir. Deney raporunda yer alan analiz sonuçları müşteri tarafından getirilen numuneye aittir ve Argetest temsil özelliğinden sorumlu değildir. Analizler kuru bazda ve 25 ± 3 °C'de yapılmıştır. / Our laboratory accredited by TURKISH ACCREDITATION AGENCY. This report shall not be reproduced other than in full except with permission of the laboratory. Testing reports witout signature and seal are not valid. The analysis results included in the test report belong to the sample brought by the customer and Argetest is not responsible for its representativeness. Analyses were made at 25 ± 3 °C.

İİM: İşletme içi metod/In house method.

Şahit numunesinin arşivde saklama süresi 6 aydır ve analizlere ancak bu süre içinde itiraz edilebilir. Genişletilmiş ölçüm belirsizlikleri ve karar kuralı laboratuvardan talep edildiği durumlarda raporda belirtilir. / Rention period of witness samples in the archive are 6 months and analysis could have contested only during this time. Expanded measurement uncertainty and decision rule will stated in the report upon elient request. 1 of 2

CERTIFICATE OF ANALYSIS AGT240318

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18101	DRILL CORE	8.17	0.82	55.74	0.03	<0.01	<0.01	0.04	1.61	0.44	<0.01	<0.01	1.26	0.01	<0.01	0.06	39.98
18102	DRILL CORE	3.11	0.19	55.86	0.04	<0.01	<0.01	0.03	0.35	0.08	<0.01	<0.01	0.25	<0.01	<0.01	0.01	43.18
18103	DRILL CORE	3.33	0.21	55.73	0.03	<0.01	<0.01	0.04	0.37	0.10	<0.01	<0.01	0.25	<0.01	<0.01	0.02	43.24
18104	DRILL CORE	5.12	0.16	55.49	0.05	<0.01	<0.01	0.05	0.30	0.07	<0.01	<0.01	0.28	<0.01	<0.01	0.01	43.59
18105	DRILL CORE	4.62	0.15	55.79	0.05	<0.01	<0.01	0.04	0.24	0.06	<0.01	<0.01	0.29	<0.01	<0.01	<0.01	43.39

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240319

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION			LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES
Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.	WGHT	Received Sample Weight
Kabul Tarihi / Received Date	: 17.01.2024	XRF WR-01	XRF Press Pellet
İş Numarası / Job Number	: AGT240319	WM LOI1000	Wet Method / Grav. Finish
Numune Sayısı / Number of Sample : 2		PREP70-500	Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240319
Numune Sayısı / Number of Sample : 2
Proje Adı / Project	: 3063757 (BATCH NO : 3063757-0003)
Rapor Tarihi / Reported Date	: 25.01.2024

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO : 3063757-0003) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240319

	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Type
DRILL CORE	5.53	0.29	55.75	0.03	<0.01	<0.01	0.06	0.54	0.12	<0.01	<0.01	0.33	<0.01	<0.01	0.03	42.85
DRILL CORE	5.44	0.21	55.96	0.02	<0.01	<0.01	0.05	0.48	0.06	<0.01	<0.01	0.34	<0.01	<0.01	0.03	42.84
		Method WGHT Analyte MDL														XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240324

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240324
Numune Sayısı / Number of Sample : 6
Proje Adı / Project	: 3063757 (BATCH NO: 3063757-0004)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight

XRF WR-01	XRF Press Pellet
WM LOI1000	Wet Method / Grav. Finish
PREP70-500	Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75 micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

CERTIFICATE OF ANALYSIS AGT240324

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18108	DRILL CORE	7.07	0.24	55.73	0.03	<0.01	<0.01	0.08	0.39	0.10	<0.01	<0.01	0.33	<0.01	<0.01	0.03	43.09
18109	DRILL CORE	5.74	0.12	55.86	0.02	<0.01	<0.01	0.07	0.21	0.07	<0.01	<0.01	0.27	<0.01	<0.01	0.02	43.35
18110	DRILL CORE	7.38	0.75	54.30	0.03	<0.01	<0.01	0.05	2.08	0.28	<0.01	<0.01	0.37	<0.01	<0.01	0.15	41.98
18111	DRILL CORE	5.97	0.20	55.62	0.02	<0.01	<0.01	0.06	0.80	0.07	<0.01	<0.01	0.27	<0.01	<0.01	0.03	42.93
18112	DRILL CORE	5.8	0.15	43.68	0.02	<0.01	<0.01	0.10	1.01	0.05	<0.01	<0.01	10.86	<0.01	<0.01	0.02	44.12
18157	ROCK PULP	0.06	0.23	35.98	<0.01	<0.01	<0.01	0.51	3.76	2.89	0.48	<0.01	14.00	0.02	<0.01	0.07	33.02

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240325

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240325
Numune Sayısı / Number of Sample : 2
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0005)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

micron

PREP70-500 Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR

Laboratory Manager

İİM: İşletme içi metod/In house method.

CERTIFICATE OF ANALYSIS AGT240325

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18113	DRILL CORE	5.16	0.34	55.67	0.03	<0.01	<0.01	0.06	0.44	0.11	<0.01	<0.01	0.33	<0.01	<0.01	0.02	42.98
18114	DRILL CORE	6.65	0.43	55.88	0.03	<0.01	<0.01	0.09	0.69	0.15	<0.01	<0.01	0.66	0.01	<0.01	0.07	41.98

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240326

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION			LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES
Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.	WGHT	Received Sample Weight
Kabul Tarihi / Received Date	: 17.01.2024	XRF WR-01	XRF Press Pellet
İş Numarası / Job Number	: AGT240326	WM LOI1000	Wet Method / Grav. Finish
Numune Sayısı / Number of Sample : 2
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0006)		micron
Rapor Tarihi / Reported Date	: 25.01.2024

WGHT Received Sample Weight

XRF WR-01	XRF Press Pellet
WM LOI1000	Wet Method / Grav. Finish
PREP70-500	Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75 micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO:3063757-0006) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240326

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18115	DRILL CORE	6.55	0.20	55.53	0.03	<0.01	<0.01	0.07	0.43	0.07	<0.01	<0.01	0.27	<0.01	<0.01	0.03	43.35
18116	DRILL CORE	5.88	0.48	55.43	0.02	<0.01	<0.01	0.05	2.37	0.15	<0.01	<0.01	0.33	<0.01	<0.01	0.09	41.08

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240327

: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
: 17.01.2024
: AGT240327
Numune Sayısı / Number of Sample : 8
: 3063757 (BATCH NO: 3063757-0007)
: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight

XRF WR-01	XRF Press Pellet
WM LOI1000	Wet Method / Grav. Finish
PREP70-500	Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75 micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

CERTIFICATE OF ANALYSIS AGT240327

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18117	DRILL CORE	6.09	0.17	55.52	0.03	<0.01	<0.01	0.08	0.25	0.04	<0.01	<0.01	0.42	<0.01	<0.01	0.02	43.48
18118	DRILL CORE	6.4	1.91	50.02	0.03	<0.01	<0.01	0.13	7.40	1.13	<0.01	<0.01	1.15	0.03	<0.01	0.43	37.76
18119	DRILL CORE	5.75	0.30	55.94	0.03	<0.01	<0.01	0.09	0.53	0.11	<0.01	<0.01	0.41	<0.01	<0.01	0.06	42.53
18120	DRILL CORE	5.3	0.51	55.88	0.04	<0.01	<0.01	0.05	1.38	0.30	<0.01	<0.01	0.42	0.02	<0.01	0.09	41.30
18121	DRILL CORE	3.74	0.58	55.86	0.04	<0.01	<0.01	0.06	1.53	0.29	<0.01	<0.01	0.55	0.02	<0.01	0.10	40.98
18122	DRILL CORE	5.94	2.91	44.19	0.03	<0.01	<0.01	0.14	12.13	1.76	0.06	<0.01	1.93	0.04	<0.01	0.63	36.16
18123	DRILL CORE	4.66	5.14	27.78	0.02	<0.01	<0.01	0.08	22.06	3.22	0.08	<0.01	3.86	0.06	0.31	1.20	36.16
18158	ROCK PULP	0.06	0.38	35.98	<0.01	<0.01	<0.01	0.84	3.88	2.39	0.78	<0.01	14.03	0.03	<0.01	0.11	32.99

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240328

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240328
Numune Sayısı / Number of Sample : 2
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0008)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

micron

PREP70-500 Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO:3063757-0008) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240328

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18133	DRILL CORE	5.71	0.18	54.06	0.02	<0.01	<0.01	0.05	5.26	0.07	<0.01	<0.01	0.28	<0.01	<0.01	0.03	40.04
18134	DRILL CORE	4.9	0.13	55.42	0.02	<0.01	<0.01	0.05	0.33	0.04	<0.01	<0.01	0.31	<0.01	<0.01	0.02	43.67

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240329

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240329
Numune Sayısı / Number of Sample : 2
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0009)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish PREP70-500 Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO:3063757-0009) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240329

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18135	DRILL CORE	5.1	0.43	55.63	0.03	<0.01	<0.01	0.06	1.22	0.19	0.02	<0.01	0.45	0.01	<0.01	0.07	41.89
18136	DRILL CORE	3.23	0.19	55.77	0.03	<0.01	<0.01	0.05	0.43	0.09	<0.01	<0.01	0.31	<0.01	<0.01	0.02	43.12

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240330

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240330
Numune Sayısı / Number of Sample : 5
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0010)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

PREP70-500 Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

CERTIFICATE OF ANALYSIS AGT240330

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18137	DRILL CORE	6.32	0.19	55.75	0.03	<0.01	<0.01	0.05	0.31	0.07	<0.01	<0.01	0.19	0.01	<0.01	0.03	43.36
18138	DRILL CORE	6.92	0.68	55.95	0.03	<0.01	<0.01	0.04	1.24	0.21	<0.01	<0.01	0.38	<0.01	<0.01	0.13	41.33
18139	DRILL CORE	4.69	0.40	55.94	0.03	<0.01	<0.01	0.05	0.82	0.21	<0.01	<0.01	0.52	0.01	<0.01	0.06	41.98
18140	DRILL CORE	7.31	0.33	55.90	0.03	<0.01	<0.01	0.05	0.65	0.12	<0.01	<0.01	0.53	<0.01	<0.01	0.06	42.32
18163	DRILL CORE	3.47	1.09	54.10	0.03	<0.01	<0.01	0.04	3.26	0.67	<0.01	<0.01	0.41	0.02	<0.01	0.22	40.16

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240331

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240331
Numune Sayısı / Number of Sample : 4
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0011)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet

WM LOI1000	Wet Method / Grav. Finish
PREP70-500	Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75 micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

CERTIFICATE OF ANALYSIS AGT240331

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18141	DRILL CORE	7.26	1.04	54.71	0.03	<0.01	<0.01	0.04	3.09	0.59	<0.01	<0.01	0.41	0.02	<0.01	0.19	39.89
18142	DRILL CORE	8.17	0.14	55.95	0.04	<0.01	<0.01	0.04	0.26	0.03	<0.01	<0.01	0.32	0.02	<0.01	0.02	43.18
18143	DRILL CORE	7.51	0.50	55.98	0.04	<0.01	<0.01	0.05	1.83	0.34	<0.01	<0.01	0.37	0.03	<0.01	0.10	40.76
18144	DRILL CORE	3.57	8.72	23.10	0.01	<0.01	<0.01	0.60	33.90	5.50	0.08	<0.01	3.63	0.08	0.70	2.49	21.16

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240332

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240332
Numune Sayısı / Number of Sample : 2
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0012)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

PREP70-500 Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO:3063757-0012) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240332

	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Type
DRILL CORE	6.16	2.95	45.80	0.03	<0.01	<0.01	0.21	11.68	1.52	0.04	<0.01	1.47	0.03	<0.01	0.81	35.44
DRILL CORE	3.8	6.27	30.14	0.03	<0.01	<0.01	0.11	27.32	4.51	0.10	<0.01	4.34	0.09	0.44	1.67	24.96
		Method WGHT Analyte MDL														XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240333

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240333
Numune Sayısı / Number of Sample : 6
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0013)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION		LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES
Müşteri Adı / Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.		Received Sample Weight
: 17.01.2024	XRF WR-01	XRF Press Pellet
: AGT240333	WM LOI1000	Wet Method / Grav. Finish
Numune Sayısı / Number of Sample : 6		Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75
		WGHT PREP70-500

micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

CERTIFICATE OF ANALYSIS AGT240333

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18147	DRILL CORE	7.93	2.90	44.98	0.03	<0.01	<0.01	0.13	13.29	1.87	<0.01	0.04	2.36	0.05	<0.01	0.67	33.65
18148	DRILL CORE	5.49	1.03	37.57	0.02	<0.01	<0.01	0.08	4.42	0.63	<0.01	<0.01	13.05	0.02	<0.01	0.19	42.99
18149	DRILL CORE	5.44	0.23	43.09	0.02	<0.01	<0.01	0.09	0.64	0.09	<0.01	<0.01	11.05	0.01	<0.01	0.03	44.72
18150	DRILL CORE	4.06	0.26	55.19	0.02	<0.01	<0.01	0.04	0.55	0.10	<0.01	<0.01	2.11	0.01	<0.01	0.04	41.68
18151	DRILL CORE	4.4	0.22	49.61	0.01	<0.01	<0.01	0.07	0.80	0.10	<0.01	<0.01	6.20	0.01	<0.01	0.05	42.93
18160	ROCK PULP	0.06	0.05	35.83	<0.01	<0.01	<0.01	0.12	3.98	2.04	0.12	<0.01	15.32	<0.01	<0.01	0.01	33.42

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240334

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240334
Numune Sayısı / Number of Sample : 2
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0014)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet

WM LOI1000	Wet Method / Grav. Finish
PREP70-500	Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75 micron

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

CERTIFICATE OF ANALYSIS AGT240334

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18124	DRILL CORE	5.53	0.14	55.48	0.03	<0.01	<0.01	0.05	0.25	0.06	<0.01	<0.01	0.31	<0.01	<0.01	<0.01	43.69
18125	DRILL CORE	5.75	0.05	55.49	0.03	<0.01	<0.01	0.04	0.15	0.02	<0.01	<0.01	0.32	<0.01	<0.01	<0.01	43.89

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240335

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240335
Numune Sayısı / Number of Sample : 3
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0015)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

micron

PREP70-500 Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

CERTIFICATE OF ANALYSIS AGT240335

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18126	DRILL CORE	6.49	0.59	55.56	0.02	<0.01	<0.01	0.04	1.20	0.33	<0.01	<0.01	0.57	0.01	<0.01	0.04	41.65
18127	DRILL CORE	6.05	0.08	55.44	0.02	<0.01	<0.01	0.04	0.14	0.04	<0.01	<0.01	0.95	<0.01	<0.01	<0.01	43.28
18128	DRILL CORE	6.76	0.06	55.60	0.04	<0.01	<0.01	0.04	0.10	0.02	<0.01	<0.01	0.29	<0.01	<0.01	<0.01	43.83

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240336

Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.
Kabul Tarihi / Received Date	: 17.01.2024
İş Numarası / Job Number	: AGT240336
Numune Sayısı / Number of Sample : 5
Proje Adı / Project	: 3063757 (BATCH NO:3063757-0016)
Rapor Tarihi / Reported Date	: 25.01.2024

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

PREP70-500 Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

micron

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240336

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18129	DRILL CORE	4.33	0.05	55.87	0.04	<0.01	<0.01	0.04	0.08	0.02	<0.01	<0.01	0.25	<0.01	<0.01	<0.01	43.65
18130	DRILL CORE	3.89	0.03	55.94	0.03	<0.01	<0.01	0.04	0.06	0.02	<0.01	<0.01	0.30	<0.01	<0.01	<0.01	43.58
18131	DRILL CORE	5.18	0.04	55.61	0.03	<0.01	<0.01	0.04	0.07	0.02	<0.01	<0.01	0.31	<0.01	<0.01	<0.01	43.88
18132	DRILL CORE	5.34	0.16	55.50	0.02	<0.01	<0.01	0.03	0.33	0.05	<0.01	<0.01	0.31	<0.01	<0.01	0.03	43.57
18159	ROCK PULP	0.06	0.19	36.08	<0.01	<0.01	<0.01	0.44	3.78	1.26	0.36	<0.01	15.36	0.02	<0.01	0.05	33.37

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240337

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION			LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES
Müşteri Adı / Client	: VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş.	WGHT	Received Sample Weight
Kabul Tarihi / Received Date	: 17.01.2024	XRF WR-01	XRF Press Pellet
İş Numarası / Job Number	: AGT240337	WM LOI1000	Wet Method / Grav. Finish
Numune Sayısı / Number of Sample : 7
Proje Adı / Project	: 3063757 (BATCH NO: 3063757-0017)		micron
Rapor Tarihi / Reported Date	: 25.01.2024

WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

PREP70-500 Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

ADDITIONAL COMMENTS / Ek Açıklamalar

Abdullah BUHUR Laboratory Manager

İİM: İşletme içi metod/In house method.

CERTIFICATE OF ANALYSIS AGT240337

		Method WGHT															XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 XRF WR-01 WM LOI1000
	Analyte	Wgt	* Al2O3	* CaO	SrO	BaO	* Na2O	SO3	* SiO2	Fe2O3	MnO	Cr2O3	MgO	P2O5	TiO2	* K2O	* LOI1000
	Unit	kg	%	%	%	%	%	%	%	%	%	%	%	%	%	%	%
	MDL	0.1	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	0.01	-10
Sample	Type
18152	DRILL CORE	6.3	2.90	50.03	0.02	<0.01	<0.01	0.07	4.66	1.11	<0.01	<0.01	0.59	0.02	0.15	0.57	39.88
18153	DRILL CORE	6.09	0.85	55.64	0.03	<0.01	<0.01	0.09	1.45	0.27	<0.01	<0.01	0.42	0.10	<0.01	0.16	40.98
18154	DRILL CORE	8.24	1.05	55.56	0.03	<0.01	<0.01	0.08	1.64	0.32	<0.01	<0.01	0.46	0.01	<0.01	0.18	40.67
18155	DRILL CORE	2.52	0.34	55.51	0.03	<0.01	<0.01	0.07	0.53	0.12	<0.01	<0.01	0.40	0.01	<0.01	0.05	42.95
18156	DRILL CORE	4.41	0.32	55.67	0.03	<0.01	<0.01	0.07	0.48	0.10	<0.01	<0.01	0.36	0.02	<0.01	0.05	42.91
18161	ROCK PULP	0.06	0.61	48.09	<0.01	<0.01	<0.01	0.03	10.56	0.59	<0.01	0.36	0.66	<0.01	<0.01	0.03	39.03
18162	ROCK PULP	0.06	0.61	49.17	<0.01	<0.01	<0.01	0.04	9.88	0.63	0.05	0.29	0.67	<0.01	<0.01	0.03	38.63

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	National												Low.	Lv	Los	٠ 3.4	35.3	$\cdot$								٠
Smilaj Av			Doğal 84	Dept Dirta: Harris	Kant Birks Hains		Elisk Analist	Щ.	1768			USC8	Drept	angeles impelns Аргена Арения Descyl	angeles Asinina	Jagebis Assesse	Topittian	Proktor		Medies Mavid	Des.	Na2504 Ma2504 Don	Foreign En-	Time Seith Vasard.	Tane Yojendaby)	Tale ¹ Collected and the	ABotti Reaktivite	Potentel	34	Urgards Modds
Kexass Ade	They set Aub	(0, 1)	David & Mahating 114	Nant TEGHY)	Kiddle ten w?	it it Fallen 154	4208 Oams. (16)	Dey.	1.74 Mektu Notina	n. (N)	F1 174.0		C14 116 DEVIR INCS	Phila 500 DEMI	Deami (%) 100 INEVIR B	*Derseya* (%) 500 DEVIR ERIT	IN	make. KBIM la social	$W_{\text{ext}}$ Θú	MR (a/kg)	Kade (56)	Kivts 1760	$C$ crisiles $T$	Tadeksi 1563 100	To. thight. 16	E. (1/6/m) hop.	Kinyasel Anallin	TS EN 1097.6	Execu 1741	Taying
18005	BLOK-CFI	$\sim$	1.0	250		94.2	1.6									23.4				0.55	7.4	6.4			2,50		A BOLGESS	3.59	0.41	Organik ruadde si line jede veya golk as var.
18006	BLOK-CP2	$\sim$	23	2.65		90.1	3.9									22.2				0.29	3.4	7.4			DOM: 2.48		A ROCGEST	5.62	0.86	O gain & mixble so Ne yok vays gok 10.150
18007	TA OK-CPA		1.5.	2.63		91.2	2.6									24.4				0.38	7.9	70.			2.50		A BOLGEST	6.82	1.78.	Organik maddy in hic stik visy ook 32.137
TROOR	BLOCKTH		$1.8 -$	7,64		96.4	2.7									21.8				0.40	7.8	6.8			2.52		A ROLOFSE	3.27	PK15 0.80	Organik modde ya his yek veys and 22,110
FÍRMA ADE			VISNE MADENCILIK ÜRETIM SANAYİ VE TİC.A.S.														Raportavan			Jeolog Mah Halil Sila KÜÇÜKANET				Kontrol Edea :		Jeoloji Mün : Zafer AYCCORTIA
SCA 310/19			ER3063757. VisneMadencilik														lmes:			Haill Sila KU				lmas:			Zafor AVGORES
GELIS TARBE				21.12.2023			RAPOR NO							8068-23												Denetel Jenetol Belge		18760
LAPOR TARBE				24.01.2024			B.R.N.							25042698						Arta Sicil No:		8400				Dda Si	XTVo: 0245

* Nutrate transmission around box vera kapiter a sing almostig, warman shadajiyara na kayagian halatilanin dayala olinom neben ile merdani jarich kock barta la galan Mardan Isboranisman nimasin degibir.

*By desey some formuye dende ventro dowy some grafit let laborate services tow of mudor loaners reportenents to podentrate, delight lanear.

* the dever nowe formuly shareds add paper is left-laboratorizations to this indign vir sadoos formula behinden comparatories aiming

ï ٠

DANE CAPI DAĞILIMI DENEYİ RAPOR FORMU

$2 - 25$

$FR - 044$		Rev. Tar./No: 18.10.18 / 06	Deney standardı:		TS EN ISO 17892-4 Aralık 2016 Madde 5.2
Gönderen					VISNE MADENCILIK ÜRETIM SANAYİ VE TİC.A.S.
Ait olduğu proje		ER3063757 VisneMadescilik
Kuyu / sondaj no		18005,00
Numune adı		BLOK-CPI
Derinlik / Km
Numune kabul tarihi			21 Aralık 2023	Dency başlangıç tarihi		22 Aralık 2023
Kurutma sekli		TS EN ISO17892-1 / Aralık 2014		Dency bitis tarihi		23 Aralık 2023

Deney		Kap kütlesi		64,00	Toplam kuru numune kütlesi		283,10
	$T - T - L$	Mileage distance teachers."	Little Law Line	328.845	Wednesday wounded breaker provisional Author and the		29-29-27-27-27-2

Imza:

8068-2

DANE CAPI DAĞILIMI DENEYİ RAPOR FORMU

FR - 044	Rev. Tar./No: 18.10.18 / 06	Deney standardı:		TS EN ISO 17892-4 Aralık 2016 Madde 5.2
Gönderen		VİŞNE MADENCILİK ÜRETİM SANAYİ VE TİC.A.Ş.
Ait olduğu proje	ER3063757 VisneMadencilik
Kuyu / sondaj no	8006.00
Numune adı	BLOK-CP2
Derinlik / Km
Numune kabul tarihi		21 Aralık 2023	Deney başlangıç tarihi	22 Aralık 2023
Kurutma şekli	TS EN ISO17892-1 / Aralık 2014		Dency bitis tarihi	23 Aralık 2023

Im2a:

×

×

DANE CAPI DAĞILIMI DENEYİ RAPOR FORMU

12-23

$FR - 044$	Rev. Tar./No: 18.10.18 / 06	Deney standardı:	TS EN ISO 17892-4 Aralık 2016 Madde 5.2
Gönderen		VÍSNE MADENCILÍK ÜRETÍM SANAYÎ VE TİC.A.Ş.
Ait olduğu proje	ER3063757 VisneMadencelik
Kuyu / sondai no	18007.00
Numune adı	BLOK-CP4
Dennlik / Km
Numune kabul tarihi		21 Aralık 2023	Dency başlangıç tarihi 22 Aralık 2023
Kurutma sekli	TS EN ISO17892-1 / Aralık 2014		Deney bitis tarihi 23 Aralık 2023

Imza:

DANE CAPI DAĞILIMI DENEYİ RAPOR FORMU-

12-23

$FR - 044$	Rev. Tar./No: 18.10.18 / 06	Deney standardı:	TS EN ISO 17892-4 Aralık 2016 Madde 5.2
Gönderen		VISNE MADENCILIK ÜRETIM SANAYİ VE TİC.A.S.
Ait olduğu proje		ER3063757_VisneMadencilik
Kuyu / sondaj no	18008,00
Numune adı	BLOK-CP4
Derinlik / Km
Numune kabul tarihi		21 Aralık 2023	Deney başlangıç tarihi	22 Aralık 2023
Kurutma şekli	TS EN ISO17892-1 / Aralık 2014		Deney bitis tarihi	23 Aralık 2023

Imza:

(ZIN BELGE NO)

		AGREGALARIM TERMAL VE BOZUNMA OZELLIKLERI IÇIN DENEYLER- MAGNEZYUM SULFAT DENEYI (DONA KARSI MUKAVEMET)
Rev. Tar./No: FR - 73 13.08.12.00		Deney standard: TS EN 1367-2 12.04.2011
Gönderen		VISNE MADENCILIK ÜRETIM SANAYI VE TIC A S.
Ait olduğu proje	ER3063757 VisneMadencilik
Derinlik / Km
Numune kabul tarihi	21 Aralık 2023	Deney başlangıç tarihi	23 Aralık 2023
Kurutma şekli : TS EN ISO 17892-1 Aralık 2014		Dency bastangic tarihi.	28 Arabk 2023.

Numune No		Elek Aralıkları	Yaklasık alınması gereken miktar	Alinan deney numunesi miktaru	Yikama ve Kurutma Sonucunda 10mm Elekte Kalan Numune Miktarı	DON KAYBI	ORTALAMA DON KAYBI
			M	м.	м,	M ₅	MS
				9.	g.	$\%$	$\%$
Numune	$10$ mm	2 mm arası	$420 \pm 0.1$	420.0	396.2	5,9
2. Numune	$10$ mm	2 mm aras:	$430 \pm 0.1$	430.0	400.0	7,0	6,44 33876

Numune No.		Elek Aralıkları	Yaklaşık alınması gereken miktar	Alinan deney numunesi miktaru	Yıkama ve Kurutma Sonucunda 10mm Elekte Kalan Numune Miktary	DON KAYBI	ORTALAMA DON KAYBI
			м,	M.	M ₂	MS	MS
						$\%$	₩
- Numune	an an an a $10$ mm	2 mm arası	$420 \pm 0.1$	420.0	387,0	7,9
2. Numune	10 mm	2 mm arası	$430 \pm 0.1$	430,0	400,0	7,0	7.42

Elek Aralıkları Numune No		Yaklaşık alinması gereken miktar	Alinan deney numunesi miktaru	Yikama ve Kurutma Sonucunda 10mm Elekte Kalan Numune Miktarı	DON KAYBI	ORTALAMA DON KAYBI
			M	м,	м,	MS	мs
				9.		%	$\frac{96}{2}$
1. Numune	$10$ mm	2 mm arası.	$420 \pm 0.1$	420.0	392.9	6.5
2. Numune	$10 \text{ mm}$	2 mm arası	$430 \pm 0.1$	430.0	397.8	7.5	6,97

18006,0	Numune No.		Elek Aralıkları	Yaklasık alınması gereken miktar	Alinan deney numunesi miktaru	Tikama ve Kurutma Sonucunda 10mm Elekte Kalan Numune Miktan	DON KAYBI	ORTALAMA DON KAYBI
				м,	м.	M,	MS	MS
				я	g.		v,	%
	1. Numune	$10 \, \text{mm}$	2 mm arası	$420 \pm 0.1$	420.0	393.6	6,3	12120
	2. Numune	$10$ mm.	2 mm arasa	$430 \pm 0.1$	430.0	398.5	7,3	6,81
----	____							______

Raporlayan : Jeoloji Müh. Halil Sıla KÜÇÜKAVŞAR
Oda Sicil No : 1849

Imze

Kontol Eden : Jeoloji Müh Zafer AYGÖREN
Perietçi no : 18760 Imza:

12IN BELGE NO:

		(DONA KARSI MUKAVEMET)	AGREGALARIM TERMAL VE BOZUNMA ÖZELLIKLERI IÇIN DENEYLER- SODYUM SÜLFAT DENEYI
Rev. Tar./No: FR - 73 13:08:12:00	Deney standard: TS EN 1367-2 12.04.2011
Gönderen	VISNE MADENCILIK ÜRETIM SANAYI VE TIC.A.\$.
Ait olduğu proje	ER3063757 VisneMadencilik
Derinlik / Km
Numune kabul tarihi	21 Aralık 2023	Deney başlangıç tarihi	23 Aralık 2023
Kurutma şekli : TS EN ISO 17892-1 Aralık 2014		Dency baslangic tarihi	28 Aralık 2023

Numune No		Yaklaşık alinması gereken. Elek Aralıkları miktar		Alınan deney numunesi miktaru	Yikama ve Kurutma. Sonucunda 10mm Elekte Kalan Numune Miktan	DON KAYBL	ORTALAMA DON KAYBI
			м,	M,	м,	MS	M ₅
					g.	K.	$\%$
. Numune	$10 \text{ mm}$	2 mm arası	$420 \pm 0.1$	420.0	387,0	7,9
2. Numune	10 mm	2 mm arası	$430 \pm 0.1$	SEPRED 430.0	400.5	-2020 6,9	7,36

ORTALAMA DON KAYBI	DON KAYBI	Yıkama ve Kurutma Sonucunda 10mm Elekte Kalan Numune Miktan	Alinan deney numunesi miktaru	Yaklasık alinmasi gereken miktar	Numune No Elek Aralıkları		MARA
MS	MS	M ₂	м,	M,				18006 164200
$\%$	N
	8,9	382.5	420.0	$420 \pm 0.1$	2 mm arası	$10$ mm	Numune
8,42	7.9.	396,0	430.0	$430 \pm 0.1$	2 mm arası	$10$ mm	2. Numune

Numune No 18007		Elek Aralıkları	Yaklaşık alınması gereken miktar	Alinan deney numunesi miktaru	Yikama ve Kurutma Sonucunda 10mm Elekte Kalan Numune Miktarı	DON KAYBI	42441 ORTALAMA DON KAYBI
			м.	м,	м,	MS	MS
			g.			%	$\mathcal{H}$
1. Numune	$10.$ mm	2 mm arası	$420 \pm 0.1$	420.0	388.9	7.4.
2. Numune.	$-10$ mm	2 mm arası	$430 \pm 0.1$	430.0	393.8	8,4	7.91

Numune No		Elek Aralıkları	Yaklasık alınması gereken miktar	Alinan deney numunesi miktaru	Yıkama ve Kurutma Sonucunda 10mm Elekte Kalan Numune Miktan	DON KAYBI	ORTALAMA DON KAYBI
			м,	м.	M.	M _S	MS
				g.		蜢	$\%$
1. Numune	10 mm	2 mm arası	$420 \pm 0.1$	420.0	389,6	7,2	$\overline{\phantom{a}}$ 7,75
2. Numune	$10$ mm	2 mm arası	430 ± 0.1	430.0	394.5	8.3

Raporlayan : Jeoloji Müh. Halil Sıla KÜÇÜKAVŞAR
Oda Sicil No : 18400 Imza:

Kontal Eden : Jeoloji Müh.Zafer AYGÖREN

Imze:

LB-1088-T
68.54

$09 - 23$

(ZIN BELGE NO: 0156

LOS ANGELES DENEY METODU ILE AŞINMA DİRENCİ TAVİNİ

Rev. Tar./No:	FR - 085 Rev. Tar./No: 10.06.17 /01	Deney standards	TS EN 1097-2 / Temmuz 2010 Madde 5
Gönderen	VISNE MADENCILIK ÜRETIM SANAYI VE TIC.A.S.
	Ait olduğu proje ER3063757 VişneMadencilik
Kuyu / sondaj no
Numune adı	18005
Gelis Tarihi	21.12.2023	Deney Tarihi	29.12.2023

Smif	Top Adedi		Elek No	Deney numune	Yıkama eleği	500 DEVIR	Kütle Kaybı (%)	Ortalama(%)
		$($ log $)$	(mm)	kütlesi(g)		Deney Sonu Kütlesi(g)
Α	12	1.1/251*	50,00-25,00
A	12	$1 - 3/4$ "	25,00-19,00			4150	17,00	17,00
Ä	12	3/4"-1/2"	19,00-12,50
A	12	$1/2$ "-3/8"	12,50-9.50
B	11	$3/4'' - 1/2''$	19,00-12,50		1,6 mm.
B	11	$1/2 - 3/8$	12,50-9.50
C	8	$3/8 - 1/4$	$9,50-6,30$
C	8	$1/4 - 4'$	6.30-4.75
b	8	$4 - 10^{\circ}$	4.75-2,00			ö	6,4	6,4

LA % 23,40

Deneyi yapan :/Raporlayan
Jeoloji Müh. Hahil Sıla KÜÇÜKAVŞAR (Ka Siya) No. 18400 Imze:

Kentrel edes / Onsylasses:
Jeoloji Müh.Zafer AXOOREN Denetçi no : 18760 inza:

c
ń
٠

IZIN BELGE NO: 0158

LOS ANGELES DENEY METODU İLE AŞINMA DİRENCI TAYİNİ

Rev. Tar./No:	$FR - 085$ Rev. Tar./No: 10.06.17 /01	Deney standards	TS EN 1097-2 / Temmuz 2010 Madde 5
Gónderen	VISNE MADENCILIK ÜRETIM SANAYI VE TİC.A.S.
	Ait olduğu proje ER3063757_VişneMadencilik
Kuyu / sondaj no
Numune adi	8006
Gelis Tarihi	21.12.2023	Deney Tarihi	29.12.2023

Smif	Top Adedi		Elek No	Deney numune	Yikama eleği	500 DEVIR	Kütle Kaybı (%)	Ortalama(%)
		******* (hq)	(mm)	kütlesi(g).		Deacy Sonu Kütlesi(g)
A	12	$1.1/2 - 1$	50,00-25,00
À.	12 ^°	$1 - 3/4$	25,00-19,00			4210	15,80	15,80
A	12	$3/4'' - 1/2''$	19,00-12,50			1239
A	12	$1/2 - 3/8$	12,50-9,50
$\mathsf B$	11	$3/4 - 1/2$	19,00-12,50		1,6 mm.
B	11	$1/2^{\circ} - 3/8^{\circ}$	12,50-9,50
с	8	$308 - 1/4$ ^*	9,50-6,30
$\mathbf{c}$	$\bf8$	$1/4 - 4$	6,30-4,75
D	8	$4 - 10$	4,75-2,00			ö	6,4	6.4

LA % 22,20

Deneyî yapan :/Raporlayan
Jeoloji Müh. Halil Sila KÜÇÜKAVŞAR -Oda sorga : 18400

Kontrol eden / Onaylayan :
Jeoloji Müh.ZafgraSDGREN Denetçi no : 18760 Imza:

Imze:

AB-1088-T
36B.

IZIN BELISE NO. 0106

LOS ANGELES DENEY METODU İLE AŞINMA DİRENCİ TAYİNİ

Rev. Tar./No:	$FR - 085$ Rev. Tar./No: 10.06.17./01	Dency standards	TS EN 1097-2 / Temmuz 2010 Madde 5
Gönderen	VISNE MADENCILIK ÜRETIM SANAYİ VE TİC.A.S.
	Ait olduğu proje ER3063757_VişneMadencilik
Kuyu / sondai no
Numune ads	8007
Gelis Tarihi	21.12.2023	Deney Tarihi	29.12.2023

Sinif	Top Adedi		Elek No	Deney numune		500 DEVIR Yıkama eleği Dency Sonu Küdesi(g)	Kütle Kaybı (%)	Ortalama(%)
		$(\ln \varsigma)$	(mm)	kütlesi(g)
A	12.	$1.1/2^{\circ} - 1^{\circ}$	50,00-25,00
A.	12 ^°	$1 - 3/4$	25.00-19.00			4100	18,00	18,00
À.	12	$3/4 - 1/2$	19,00-12,50
A.	$12^{1}$	$1/2^ - 3/8^$	12.50-9.50
$\,$ B	CH 11	$3/47 - 1/27$	19.00-12,50		$1,6$ mm.
B.	11	$1/2^{\circ} - 3/8^{\circ}$	12,50-9.50
C	8	$3/8 - 1/4$ ^*	$0,50-6,30$
C	8	$1/4 - 4$	6,30-4,75
D	$\overline{\mathbf{8}}$	$4^{\circ} - 10^{\circ}$	4,75-2,00			0	6,4	6,4

24,40 LA %

Deneyi yapan :/Raporlayan
Jeoloji Muh. Halil Sila KÜÇÜKAVŞAR | OSSEncil No : 18400 Imza:

Kentrel edes / Onspiss un :
Jeoloji Müh Zgier AYGÖREN Denetçi no : 18760 Imza:

, ۷

$09 - 23$

IZIN BELGE NO: 0156

LOS ANGELES DENEY METODU İLE AŞINMA DİRENCİ TAYİNİ

Rev. Tar./No:	FR - 085 Rev. Tar./No: 10.06.17.01	Dency standards	TS EN 1097-2 / Temmuz 2010 Madde 5
Gönderen	VISNE MADENCILIK ÜRETIM SANAYI VE TIC.A.S.
	Ait olduğu proje ER3063757 VişneMadencilik
Kuyu / sondai no
Numune adi	8008
Geliş Tarihi	21.12.2023	Deney Tarihi	29.12.2023

Sinif	Top Adedi		Elek No	Deney numune		500 DEVIR Yıkama eleği	Kütle Kaybı (%)	Ortalama(%)
		$(\ln \varsigma)$	${m}{m}$	kütlesi(g)		Deney Sonu Kütlesi(g)
A	12	$1.1/2 - 1$	50,00-25,00
A.	12 ¹²	$1 - 3/4$ "	25,00-19,00			4130	17,40	17,40
$\mathsf A$	12	$3/4^{\circ} - 1/2^{\circ}$	19,00-12,50
Α	12	$1/2^ - 3/8^$	12,50-9,50
B	11	$3/4' - 1/2''$	19.00-12.50		1,6 mm.
B	11	$1/2$ $-3/8$	12.50-9,50
C	$\bf 8$	$3/8" - 1/4"$	9,50-6,30
C.	8	$1/4'' - 4''$	6.30-4.75
$\mathbf{D}$	$^{\circ}$	$4 - 10^{-}$	$4.75 - 2.00$			$\overline{0}$	6,4	6,4

23,80 LA %

Deneyi yapan :/Raporlayan
Jeoloji Müh. Halil Sila KÜÇÜKAVŞAR
Alixand No : 18400

Kentrel eden / Onaylayan :
Jeoloji Müh Zater AYGÖREN Denetçi no : 18760 Imza:

IZIN BELGE NO: 0156

Rev. Tar./No	FRK 17 05:07:2019 Rev. No. 17 artist	TS EN 931-9+A1
Gönderen	VISNE MADENCILIK ÜRETIM SANAYI VE TIC.A.Ş.
Ait olduğu proje-	ER3063757 VisneMadencifik
Vumune Tarifi	2 mm elekten geçen malzeme
Vumune kabul tarihi	21 Aralık 2023 Deney başlangıç tarih 23 Aralık 2023
Kurutma şekli	TS EN ISO 17892-1/ Aralık 2014	Deney bitis tarihi		27 Aralık 2023
Kuyu / sondaj no	18005
Numune adı.	BLOK-CP1
	(0-2) mm'lik deney numunesi kısmının kuru kütlesi		$M_1$ in	200.0	ø
	Kaolinit tarafından (eğer kullanılmışsa) adsorplanan çözelti hacmı		$V =$	0,0	ml
				6.9	ml

	llave edilen boya çözeltisinin toplam miktarı (0-2) mm aralığının beher kilogramı başına gram cinsinden boya.		$V_t$ =
	miktan olarak ifade edilen MB değeri $8,0 - 0,0$		$MB =$	0.35 boya
Kuyu / sondaj no.	$MB =$ x10 200.0 18006	$MB = 0.35$ g/kg		numune
	BLOK-CP2		$M_{+}$
	(0-2) mm'lik deney numunesi kısmının kuru kütlesi Kaolinit tarafından (eğer kullanılmışsa) adsorplanan çözelti hacmı		$V =$	200,0 0,0	g ml
Numune adı	llave edilen boya çözeltisinin toplam miktarı		$V_t =$	5,8	g/kg ml

1- Deneyde TS EN 933-9+A1 standardi kullanılmıştır.

3 -Numunelerin temsil olmamasından laboratuvarımız sorumlu değidir.

4- Numunelerin yeri ve derinliği müşteri beyanına göre yazılmaktadır.
5- Sorumlulyiy, beyanı veren kişi ve kuruluşa aittir.

Ferhat OZCAN
Tekniker

Zafer AYGÓRÉN
Denetçi Mühendis
Belge No: 18760 IJ

IZIN BELGE NO: 0156

Harr. Tart /Net	FRK117 05:07.2019 Rev.Not. / Tarihi.	TS EN 033-0-A1
Gönderen	VISNE MADENCILIK ÜRETIM SANAYI VE TIC.A.Ş.
Ait olduğu proje	ER3063757 VisneMadencilik
Numune Tarifi	2 mm elekten geçen malzeme
Numune kahal tarihi	21 Aralık 2023 Deney başlangıç tarih 23 Aralık 2023
Kurutma şekli	TS EN ISO 17892-1/ Aralık 2014	Deney bitiş tarihi		27 Aralık 2023
Kuyu / sondaj no	18007
Numune adı	BLOK-CP4
	(0-2) mm'lik deney numunesi kısmının kuru kütlesi		$M_1$	200,0	g
	Kaolinit tarafından (eğer kullanılmışsa) adsorplanan çözelti hacmı		$V =$
				0,0	ml
	Ilave edilen boya çözeltisinin toplam miktan		$V_i =$	7.5	ml
	(0-2) mm aralığının beher kilogramı başına gram cinsinden boya miktan olarak ifade edilen MB değeri		$MB =$	0.38	g/kg

Kuyu / sondaj no	$8,0-0,0$ $MB =$ x10 $MB = -$ 200.0 18008	$0.38$ g/kg		boya numune
	BLOK-CP4
Numune ad:	(0-2) mm'lik deney numunesi kısmının kuru kütlesi		M,=	200,0	g
	Kaolinit tarafından (eğer kullanılmışsa) adsorplanan çözelti hacmı		$V =$	0,0	ml
	llave edilen boya çözeltisinin toplam miktarı (0-2) mm aralığının beher kilogramı başına gram cinsinden boya		$V_1$ =	8.0	ml

1- Deneyde TS EN 933-9+A1 standardi kullanılmıştır.

3 -Numunelerin temsili olmamasından laboratuvarımız sorumlu değidir.

4- Numunelşiğn yeri ve derinliği müşteri beyanına göre yazılmaktadır.
5- Sorumlıllık , beyanı veren kişi ve kuruluşa aittir.

Zafer AYGOREN
Denetçi Mühenger Beige No: 18760

Ferhat OZGAN

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ï ٦	$\sim$ ۰
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GERÇEK YOĞUNLUK, GÖRÜNÜR YOĞUNLUK, TOPLAM VE AÇIK GÖZENEKLİLİK

Rev. Tar./No:				FR - 103 Rev. Tar/No: 10.06.	107.11					Dency standards		TSEN 1936 / Ocak 2010
Gönderen						VISNE MADENCILIK URETIM SANAYI VE TIC A.S.
Ait olduğu proje			ER3063757_VigneMadencilik
Knyu / sondaj no
Numine adi
Derinlik / Km
Numune kabul tarihi			21.12.2023					Desay haşlangıç tarihi		21 Arabk 2023
Kurutma sekli			TS EN ISO 17892-1 Arahk		2014			Deacy hitts tariht		23 Arabk 2023
Deney Su Sıcaklığı		20.02	(20°C' anight 966 (tud) rightwingon unine st.O., 02)
Sondaj Kuyu No	Numun £	Derinliği Ornek	Boy	Çap	Alan	Hacim	Ağırlık Doğal	Suya Doygun Ağırlık Wis	Agarisk Kuru	Yoğunluk Gerçek	Yoğunluk Görünür	Toplam Porozita	Görünür Porozite		Su Emme
						⋗	š		gw
		Ê	(cm)	(cm)	$(\rm cm^2)$	(cm ³ )	희	ø	9	kg/m ³	kg/m ²	ż	1	¥.	滤
18005	BLOK-CP1	×	6,00	6,00	28.27	169,65	410,00	411,41	409,71	2500.0	2410.3	3,59	1,70	S,	0,41
18006	BLOK-CP2	ä	5,70	5,70		145,45	342,50	344,07	341,14	2480.0	2340.7	5.62	2.84	2.02	0.86
18007	BLOK-CP4		5,58	5,58	25.52	136,46	320,00	324,18	318,51	2500,0	2329,5	6.82	5,68	4,16	1,78
19008	BLOK-CP4		6,00	6,00	28,27	169,65	415,00	416,80	414,36	2520.0	2437,6	327	2.44	1.44	0.59

Raperlayan :
Jeoloj Moh. Zeliha ÇALIŞOĞLU @GSSicil No : 18349

Kontrol eden / Omplayan :
Joshiji Mih Zafer AYGOREN – Desetçi no : 18760 ١

$m$ za:

$lmza$ :

	ī ۳
SECTION	٠ ÷ ٠
	ì ٠

SU EMME DENEYÎ (ATMOSFER BASINCLALTINDA) RAPOR FORMU

Rev. Tar./No:		FR - 105 Rev. Tar/Net 10.06.17/01		Dency standards	TS EN 13755 / Haziran 2014
Gönderen			VISNE MADENCILIK ÜRETIM SANAYİ VE TİC A.Ş.
Ait olduğu proje		ER3063757 VisneMadencilik
Kuyu / sondaj no
Nimmine adı
Derinlik / Km
Numine kabul tarihi		21 Aralık 2023	Deney başlangıç tarihi		27 Arabk 2023
Kurutma şekli		TS EN ISO 17892-1/ Aralık 2014 Deney hitiş tarihi		28 Aralık 2023
Ocak / Kuyu / Sondaj Adı	Numune ads	Km / Derinlik	Etüv sonu kuru kütle g	Doygun haldeki kütle и	Su emme oranı $\%$
18005	BLOK-CP1		409,71	411,41	0,41
18006	BLOK-CP2		341,14	344.07	0,86
18007	BLOK-CP4		318,51	324,18	1,78
18008	BLOK-CP4		414,36	416,80	0,59

Raporlayan:

Jeoloji Müh. Hall Sila KÜÇÜKAVŞAR Oda Sicil No : 18400

Imza:

Kontrol edes / Onaylayan:

Jeoloji Müh.Zafer_AYGÖREN Denetçi no: 18760 Imza:

AGREGALARIN KİMYASAL ANALİZİ ORGANİK MADDE ORANI TAYİNİ DENEY RAPORU

Günderen	VISNE MADENCILIK ÜRETIM SANAYİ VE TİC.A.S.
Ait olduğu proje	ER3063757_VisneMadencilik
Kuyu / sondaj no	ISUOS
Numune adı	BLOK-CPT
Derinflk/Km
Numune Kabul Tarihi	21.12.2023
Numune Deney Tarihi	24.12.2023
Detey standardi:	TS EN 1744-1 Nisan 2000 FR - 166 Rev. Tar./No: 01.02.19 / 00
Sicilihk (°C)	Denry Ortami	20
	Numane
Rutubet (%)	Deney Ortams
	Numune
	DENEY SONUCLE

	Isce Agrega Mensei ve Miktari-	$(W)$ $(x)$	500+75
NUMINE	Iri Agrega Menses ve Miktari	$(W)$ $O(2)$	240.3
	NaOH Cözeltisi.	(54)
	Cam Sisede NaOH Cozekisi Yüksekliği	(mn)	80
VERILER	Cözelti ve Agrega Yüksekliği	(mm)	120
	Renk Çözeltisini Mukayese İçin Bekletme Süresi	曲	24
SONUCLAR	Cozelti Rengi Mukayese Sonucu		Renksiz veya çok hafif sarı
	Acidemalar		Organik madde ya hiç yok veya çok az var

Denny yapan : Jeolog Mah.Hald Sile KUCUKASSAR OS SKING ISLA

Korná Edin : Juskýi MZh.ZatorAVGÖREN $Domf(\sqrt{n})$ : 18700

live.

hass.

AGREGALARIN KİMYASAL ANALİZİ ORGANİK MADDE ORANI TAYİNİ DENEY RAPORU

Génderen		VISNE MADENCILIK ÜRETİM SANAYİ VE TİCA.Ş.
Ait olduğu proje-		ER3063757 VisneMadencilià
Kuyu / sandaj no		18006
Numune adı		BLOK-CP2
Derinfik/Km
	Numune Kabul Tarihi	21.12.2023
	Numune Deney Tarihi	24.12.2023
	Denry standard: :	TS EN 1744-1 Nisan 2000	FR - 166 Rev. Tar./No: 01.02.19 / 00
Sienklik ("C)		Deney Ortami	$20-$
		Numune-
Rutabet (%)		Dency Ortami
		Numune
		DENEY SONUCU
NUMUNE BİLGİLERİ	Ince Agrega Mensei ve Miktarı	$(W)$ $(y)$	500x75
	Iri Agrega Mensei ve Miktare	$(W)$ $(kE)$ $2 + 0.3$
	NaOH Cozeltini	(94)	3
	Cam Sisede NaOH Căzeltisi Yüksekliği	(mm)	50
VERILER	Cozelti ve Agrega Yüksekliği	(mm)	120
	Renk Cizeltisini Mukayese İçin Bekletme Süresi	(b)	$^{24}$
SONUCLAR	Cözelti Rengi Mukayese Sonucu		Renksiz veya çok hafif sarı
	Acıklamalar.		Organik madde ya hiç yok veya çok az var

$\begin{split} \text{Dosep}(\text{syapar} = \text{Jselepi Math, Hall} \text{ Star EUCQU} \textbf{p} \textbf{f} \text{V} \textbf{SAR} \ \text{Dda State No} \textbf{f} \text{KU-0} \end{split}$ Inav

Kontol Eden : Jeoloji MižsZafer AYOÖREN

Denezi ny Pro Irvas

AGREGALARIN KİMYASAL ANALİZİ ORGANİK MADDE ORANI TAYİNI DENEY RAPORU

Gönderen			VISNE MADENCILIK ÜRETIM SANAYİ VE TİC.A.S.
Ait olduğu proje		ER3063757 VisneMadencilik
	Kuyu / sondaj no	18007
Numune adı		BLOK-CP4
Derinfik / Km
	Numune Kabul Tarihi	21.12.2023
	Numune Dency Tarihi	24.12.2023
	Denry standards:	TS EN 1744-1 Nisna 2000	FR - 166 Rev. Tar./No: 01.02.19700
Sierklik (C)		Deney Ortami	10
		Numune
Ratubet (%)		Deney Ortami
		Numune
		DENEY SONUCU
NUMUNE BILGILERI	Ince Agrega Mensei ve Miktarı	$(W)$ $(g)$	500±75
	Iri Agrega Measei ve Miktare	$(W)$ $(kg)$	$2 + 0.3$
	NaOH Cozeltisi	(96)	з
	Cam Sisede NaOH Citzeltisi Yüksekliği	(mm)	SO.
VERILER	Citzelti ve Agrega Yüksekliği	(mm)	120
	Renk Çözeltisini Mukayese İçin Bekletme Süresi	(h)	$^{24}$
SONUCLAR	Cözelti Rengi Mukayese Sonucu		Renksiz veya çok hafif sarı
	Açıklamalar:		Organik madde ya hiç yok veya çok az var

$\begin{minipage}{0.9\linewidth} \textbf{Decayity} & \textbf{Mod} \textbf{Total Set} \textbf{ROQUR} & \textbf{SAR} \\ & \textbf{Obs Set} \textbf{No} & \textbf{Mod} \textbf{No} \end{minipage}$ lines.

Konti Edes : Jeoleji Mih Zghr AYGÖREN

$Dang ₂ 18760$ louzy

AGREGALARIN KİMYASAL ANALİZİ ORGANİK MADDE ORANI TAYİNİ DENEY RAPORU

Giaderen		VISNE MADENCILIK ÜRETIM SANAYİ VE TİCA.Ş.
Ait alduğu proje		ER3063757 VisneMadencilik
Kuyu / sondaj no		18008
Numune adı		BLOK-CP4
Derinfik / Km
	Numune Kabul Tarihi	21.12.2023
	Numune Dency Tarihi	24.12.2023
	Deney standards:	TS EN 1744-1 Nisan 2000	FR - 166 Rev. Tar./No: 01.02.19 / 00
Sieaklik ("C)		Deney Ortami	28
		Numicine
Ratubet (%)		Dency Ortami
		Numune
		DENEY SONUCU
NUMUNE BÍLGILERI	Isee Agrega Mensei ve Miktari.	(301.123)	500±75
	Îri Agrega Mensei ve Miktarr.	(W) (kg)	$2 + 0.3$
	NaOH Cözeltisi	ess	3
	Cam Sisede NaOH Cézeltisi Vüksekliği	imm)	$\bar{x}0$
VERILER	Cözelti ve Agrega Yüksekliği	(mm)	120
	Renk Çözeltisini Mukayese İçin Bekletme Süresi	(h)	24
SONUCLAR	Çözelti Rengi Mukayese Sonucu		Renksiz veya çok hafif sarı
	Aciklamalar.		Organik madde ya hiç yok veya çok az var

$\begin{minipage}{0.9\linewidth} \textbf{Dway} \textbf{type} & \textbf{Jads} \textbf{Mish Hall Sds KUCCENJMSAR} \ \textbf{Ods Sval No/JMS40} & \textbf{Ods} \textbf{Sval No/JMS40} \end{minipage}$

Kosel Edm : Jeoleji Mijorji ka AYGÖREN

Despoto: 18700 $\frac{1}{2}$

Inax

C.Atıf Kansu Cd: Oğuzlar Mh. 1378 . Sk. 7/A Balgat- ANKARA Tel: 0312 285 55 56 Fax: 0312 285 55 57 www.cozumjecteknik.com.tr e-mail:[email protected]

ALKALİ REAKTİVİTE KİMYASAL ANALİZ RAPORU

Deneyi İsteyen Firma		VISNE M/
Ait Olduğu Proje		ER30637
Numune Tarifi
Numune Alinis Tarihi
Numune Kabul Tarihi		21.12.2023
Deney Başlama Tarihi	5	22.12.2023
Deney Bitis Tarihi		27.12.2023
Laboratuvar No

VISNE MADENCILIK ÜRETIM SANAYİ VE TİC.A.S. ER3063757 VisneMadencilik

Re: Sc Alkali Azalması Sıra No Numunenin Adı Cözünen Silika Değerlendirme (mmol/L) $(mmol/L)$ 18005 BLOK-CP1 È. 178,8 65.3 A BÖLGESİ $\overline{2}$ 18006 BLOK-CP-2 190,5 70.5 A BÖLGESİ 3 18007 BLOK-CP-4 168,3 69,3 A BÖLGESİ $\overline{4}$ 18008 BLOK-CP-4 206,8 76.3 A BÖLGESİ

A BÖLGESİ : ASR yönünden zararsız olan agregalar.

B BÖLGESİ : ASR yönünden potansiyel zararlı olan agregalar.

C BÖLGESİ: ASR yönünden zararlı olan agregalar.

NOT:

1- Deneyde TS 2517 standardı kullanılmıştır.

3 -Numunelerin temsili olmamasından laboratuvarımız sorumlu değidir.

4- Numunelerin yeri ve derinliği müşteri beyanına göre yazılmaktadır.

Sorumluluk , beyanı veren kişi ve kuruluşa aittir.

Deney Sorumlus Ferhat ÖZO Teknik

Onaylayan Zafer AYGORE Denetçi Mühendis Belge No: 18760

SERTİFİKALAR

Mustafa Kemal Mahallesi 2131. Cadde Aslanlar Plaza No:24/11 06510 Çankaya /ANKARA – TÜRKİYE T +90 312 503 73 99 • F +90 312 503 73 98 www.mitus.com.tr • [email protected]

Tel: +27 (0) 11 923 0800 Fax: +27 (0) 11 392 4715 web: www.amis.co.za 11 Gewel Street (off Hulley Road), D1 Isando Business Park, Kempton Park, 1609 P.O. Box 856, Isando, 1600, Gauteng, South Africa, a division of the Set Point Group

AMIS0250

Certified Reference Material

Fluorite, Witkop Flourspar Mine Zeerust, South Africa

Certificate of Analysis

Recommended Concentrations and Limits1. 2. (at two Standard Deviations)

Certified Concentrations

F ISE3.	8.99	±	0.46	%
U M/ICP	6.5	±	0.8	ppm
Specific Gravity	2.93	±	0.08

Provisional Concentrations

Th M/ICP 1.20 ± 0.22 ppm

Manufacturers recommended limits for use of the material as control samples, based on two standard deviations, calculated using "Between Laboratory" statistics for treatment of the data for trivial, non-trivial and technically invalid results. See sections 1, 9 and 12.
1. There is additional certified major element data presented on p2 and uncertified trace element data presented as an appendix.
1. Or, by applying a chemical conversion factor Fx2.0547= CaF2; CaF2= 18.472%

Major Element Recommended Concentrations and Limits (at two Standard Deviations)

Certified Concentrations

CaO	36.32	±	0.42	%
Fe2O3	2.93	±	0.06	%
MgO	14.77	±	0.90	%
MnO	0.84	±	0.06	%
SiO2	3.93	±	0.20	%
LOI	33.50	±	0.60	%

Provisional Concentrations

Al2O³ 0.44 ± 0.10 %

Informational Means

K2O	0.12	%
P2O5	0.04	%
TiO2	0.02	%

1. Intended Use: AMIS0250 can be used to check analysis of samples of fluorite bearing rocks with a similar grade and matrix.

It is a matrix matched Certified Reference Material, fit for use as control samples in routine assay laboratory quality control when inserted within runs of samples and measured in parallel to the unknown. Its purpose is to monitor inter-laboratory or instrument bias and within lab precision. It can be used, indirectly, to establish the traceability of results to an SI system of units.

The recommended concentrations and limits for this material are property values based on a measurement campaign (round robin) and reflect consensus results from the laboratories that participated in the round robin.

Slight variations in analytical procedures between laboratories will reflect as slight biases to the recommended concentrations (see 19). Good laboratories will report results within the two standard deviation levels with a failure rate of <10 %.

The CRM can also be used for method development and for the calibration of equipment.

2. Origin of Material: AMIS0250 is a commissioned CRM made up of material supplied by ENRC from the Witkop Flourspar Mine; 18km south of the town of Zeerust and 115 km west of Rustenburg, in the North West Province of South Africa. The Witkop fluorspar deposits are large bedded replacement deposits of the classical Mississippi Valley type. They occur in the Transvaal Basin, within 2550 million year old dolomites of the Malmani Subgroup, Transvaal Supergroup. Fluorspar mineralisation occurs mainly associated with stromatolites in the Middle Frisco Zone and appears to have been introduced post deposition by hydrothermal brines. The fluorite occurs as a filling in permeable beds; within small gas cavities in the stromatolites.

3. Mineral and Chemical Composition: Mineralogically this ore is primarily dolomite with fluorite. Major other minerals are calcite, mica, and talc (3% to 10%); with traces of quartz, sulphides and chlorite. The sulphides make up <3%, dominantly pyrite, with minor pyrhotite, sphalerite and galena.

4. Appearance: The material is a very fine powder. It is colored a Medium Light Grey (Corstor 10Y 6/2).

5. Handling instructions: The material is packaged in Laboratory Packs and Explorer Packs that must be shaken or otherwise agitated before use. Normal safety precautions for handling fine particulate matter are suggested, such as the use of safety glasses, breathing protection, gloves and a laboratory coat.

6. Method of Preparation: The ore is crushed, then dry-milled and air classified to 100% <54µ. This fine powder is mixed in a blender for 14 hours and then split down into numbered 1 kg tubs. These lots are sampled for quality control and for round robin analysis. Quality control will typically comprise sampling 30 tubs selected from the whole stream. Round robin samples are selected the same way, so that one laboratory will receive samples from the beginning, end, and from throughout the batch.

7. Methods of Analysis requested:

1. Fluoride Ion Selective Electrode.
1. Multi element scan to include U & Th. Multi-acid total digestion, ICP-OES or ICP-MS.
1. Majors ( Al2O3, CaO, Cr2O3, Fe2O3, K2O, MgO, MnO, Na2O, SiO2, TiO2. LOI. ) XRF fusion.
1. SG ( gas pycnometer ).

8. Information requested:

1. State and provide brief description of analytical techniques used.
1. State aliquots used for all determinations.
1. Results for individual analyses to be reported ( not averages )
1. All results for Rare Earth Elements to be reported in ppm (not as oxides).
1. All results for multi-element scans to be reported in ppm.
1. All results for major elements to be reported in %, as oxides.
1. Report all QC data, to include replicates, blanks and certified reference materials used.

9. Method of Certification: Sixteen laboratories were each given eight randomly selected packages of sample. Fourteen of the laboratories submitted results.

Final limits were calculated after first determining if all data was compatible within a spread normally expected for similar analytical methods done by reputable laboratories. Data from any one laboratory was then removed from further calculations when the mean of all analyses from that laboratory failed a "t test" of the global means of the other laboratories. The means and standard deviations were then re-calculated using all remaining data. Any analysis that fell outside of the new two standard deviations was removed from the ensuing data base. The mean and standard deviations were again calculated using the remaining data.

The "between-laboratory" standard deviation is used in the calculation to eliminate technically and statistically invalid data. Upper and lower limits are based on the standard deviation of the remaining data, which reflect individual analyses and can be used to monitor accuracy in routine laboratory quality control. This is different to limits based on standard deviations derived from grouped set of analyses (see 12), which provide important measures for precision and trueness, but which are less useful for routine QC.

Standards with an RSD of near or less than 5 % are termed "Certified", RSD's of between near 5 % and 15 % are termed "Provisional", and RSD's over 15 % are termed "Informational".

10. Participating Laboratories: The 14 out of 16 laboratories that provided results timeously were (not in same order as in the table of assays):

1 Activation Laboratories Pty Ltd (ActLabs) CA
2 ALS Chemex Laboratory Group Brisbane Australia
3 ALS Chemex Laboratory Group Johannesburg SA
4 ALS Chemex Laboratory Group Perth WA
5 Genalysis Laboratory Services W Australia
6 Set Point Laboratories (Isando) SA
7 SGS Australia Pty Ltd (Newburn) WA
8 SGS Geosol Laboratories Ltda (Brazil)
9 SGS Mineral Services Callao (Peru)
10 SGS Mineral Services Lakefield (Canada)
11 SGS South Africa (Pty) Ltd Booysens JHB
12 SGS Toronto (Canada)
13 Ultra Trace (Pty) Ltd WA
14 Vergenoeg Mining Company (SA)

11. Assay Data: Data as received from the laboratories for the important certified elements listed on p1 are set out below.

Lab	F	U	Th	Al2O3	CaO	Cr2O3	Fe2O3	K2O	MgO	MnO	Na2O	P2O5	SiO2	SO3	TiO2	LOI	SG
Code	ISE	M/ICP	M/ICP	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF		XRF pycnometer
	%	ppm	ppm	%	%	%	%	%	%	%	%	%	%	%	%	%

A	8.66			0.23	36.14		3.31	0.12	15.38	0.98		0.05	3.74			33.42	2.94
A	8.91			0.27	36.12		3.39	0.12	15.40	0.96		0.05	3.79			33.34	2.99
A	8.76			0.33	36.18		3.38	0.12	15.88	0.98		0.05	3.89			33.36	2.93
A	9.00			0.22	36.02		3.32	0.12	15.37	0.98		0.05	3.68			33.35	2.96
A	8.81			0.28	35.95		3.33	0.12	15.36	0.98		0.05	3.79			33.25	2.94

A	9.00			0.27	36.00		3.28	0.12	15.18	0.98		0.06	3.76			33.24	2.97
A	8.86			0.28	36.13		3.34	0.12	15.43	0.99		0.05	3.76			33.13	2.93
A	8.81			0.28	35.80		3.31	0.12	15.44	0.99		0.05	3.72			33.12	2.94
B	9.93	6.35	1.40

B	9.36	6.58	1.30
B	9.35	6.65	1.30
B	9.72	6.23	1.40
B	9.40	6.60	1.40
B	9.68	6.97	1.30

B	9.42	6.91	1.30
B	9.29	6.53	1.30
C		5.70	1.10														2.94
C		6.30	1.20														2.93
C		6.00	1.20														2.94

C		5.90	1.10														2.93
C		6.20	1.20														2.92
C		6.10	1.20														2.92
C		6.70	1.20														2.88
C		5.80	1.10														2.93

D	9.03	5.05
D	9.18	5.47
D	9.10	4.80
D	8.92	5.00

D	9.12	5.09
D	9.04	5.05
D	9.00	4.88
D	8.90	5.06
E				0.67			4.59					0.04	4.12

E				0.67			4.59					0.03	4.08
E				0.68			4.58					0.03	4.10
E				0.67			4.57					0.03	4.09
E				0.71			4.66					0.03	4.35
E				0.67			4.57					0.04	4.09

E				0.66			4.57					0.03	4.16
E				0.67			4.58					0.03	4.11
F	7.81	6.81	1.24	0.41	36.50		2.93	0.11	14.60	0.79	0.06		3.98		0.02	33.10
F	7.40	6.57	1.17	0.40	36.60		2.96	0.11	14.50	0.80	0.06		3.91		0.02	32.80
F	8.14	6.59	1.19	0.41	36.60		2.93	0.11	14.60	0.79	0.06		3.97		0.02	33.00

F	7.26	6.46	1.16	0.40	36.50		2.94	0.11	14.50	0.80	0.05		3.90		0.02	32.90
F	7.75	6.90	1.22	0.40	36.50		2.94	0.11	14.50	0.80	0.05		3.88		0.02	33.00
F	7.63	6.73	1.18	0.41	36.60		2.95	0.10	14.60	0.80	0.05		3.96		0.02	33.00
F	7.75	6.51	1.13	0.41	36.50		2.95	0.11	14.60	0.80	0.04		3.98		0.02	32.70
F	7.53	6.89	1.22	0.41	36.60		2.93	0.11	14.60	0.79	0.05		3.94		0.02	32.50

G	8.85	6.90	1.30	0.36	36.50		2.95	0.10	14.45	0.84	0.02		3.96			33.34
G	8.91	7.10	1.40	0.35	36.20		2.90	0.10	14.25	0.82	0.03		3.94			33.00
G	8.53	7.80	1.60	0.35	36.00		2.89	0.10	14.15	0.82	0.03		3.89			33.34
G	8.82	7.10	1.30	0.35	36.30		2.92	0.10	14.30	0.83	0.02		3.88			32.52
G	9.19	7.00	1.40	0.37	36.70		2.98	0.10	14.40	0.84	0.02		4.03			33.10

G	8.78	6.60	1.30	0.38	36.20		2.93	0.10	14.25	0.82	0.02		4.12			33.29
G	9.01	6.80	1.30	0.41	36.70		3.02	0.10	14.45	0.84	0.01		4.42			32.63
G	8.67	7.70	1.40	0.36	36.10		2.89	0.10	14.20	0.82	0.01		3.86			32.78
H	8.21		1.40	0.42	36.40		2.95	0.10	15.00	0.84		0.02	3.91			33.80

H	7.87		1.40	0.44	36.30	0.02	2.90	0.11	15.00	0.85		0.04	4.03		0.02	33.70
H	8.06		1.30	0.43	36.60	0.01	2.93	0.10	14.90	0.85		0.05	3.94		0.01	33.70
H	8.50		1.30	0.44	36.70	0.02	2.95	0.10	15.00	0.85		0.04	3.97		0.01	33.70
H	7.65		1.30	0.44	36.90	0.01	2.97	0.11	15.00	0.86		0.04	3.99		0.02	33.70
H	8.88		1.20	0.42	36.30		2.90	0.10	14.90	0.83		0.02	3.83		0.02	33.80

H	8.50		1.20	0.44	36.40	0.01	2.94	0.10	14.90	0.85		0.03	3.92		0.01	33.80
H	8.45		1.30	0.44	36.90		2.93	0.10	15.10	0.87		0.04	4.01		0.01	33.80

	Assay data (cont)
Lab	F	U	Th	Al2O3	CaO	Cr2O3	Fe2O3	K2O	MgO	MnO	Na2O	P2O5	SiO2	SO3	TiO2	LOI	SG
Code	ISE	M/ICP	M/ICP	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF	XRF		XRF pycnometer
	%	ppm	ppm	%	%	%	%	%	%	%	%	%	%	%	%	%
I	9.15	5.70	0.80	0.49	36.16		2.91	0.11	14.53	0.85	0.06	0.05	3.85		0.02	33.65	2.98
I	9.14	6.00	1.10	0.50	36.16		2.90	0.11	14.56	0.85	0.06	0.05	3.90		0.02	33.75	2.96
I	9.17	6.00	1.00	0.49	36.37		2.91	0.11	14.64	0.85	0.06	0.05	3.87		0.02	33.65	2.94
I	9.22	5.80	1.00	0.49	36.11		2.88	0.11	14.53	0.85	0.05	0.05	3.89		0.02	33.66	2.94
I	9.23	5.70	1.00	0.49	36.14		2.88	0.11	14.50	0.85	0.05	0.05	3.91		0.02	33.66	2.97
I	9.24	6.00	1.10	0.51	36.11		2.88	0.11	14.58	0.84	0.05	0.05	3.88		0.02	33.54	2.98
I	9.14	6.00	1.00	0.50	36.08		2.88	0.11	14.56	0.85	0.04	0.05	3.88		0.02	33.58	2.95
I	9.11	6.20	1.10	0.50	36.18		2.89	0.11	14.56	0.85	0.05	0.05	3.87		0.02	33.58	2.95
J		6.50	1.20														2.83
J		6.70	1.10														2.85
J		6.90	1.30														2.88
J		6.70	1.00														2.89
J		6.60	1.00														2.88
J		6.70	1.50														2.85
J		7.30	1.10														2.87
J		6.80	1.20														2.86
L	9.34	6.96	1.23														2.89
L	8.95	6.89	1.23														2.89
L	9.02	6.87	1.22														2.89
L	9.89	6.68	1.18														3.01
L	9.25	6.64	1.16														2.94
L	9.47	6.67	1.16														2.99
L	9.74	6.18	1.18														2.89
L	9.11	7.13	1.22														2.93
M	9.03	6.90	1.90	0.48	36.68	0.01	3.15	0.01	15.76	0.92	0.04	0.04	3.85		0.02	33.84	2.93
M	8.93	7.60	1.20	0.44	36.41	0.01	3.18	0.02	15.80	0.92	0.07	0.04	3.87		0.02	33.84	2.96
M	8.58	6.80	1.10	0.47	36.50	0.01	3.17		15.85	0.92	0.04	0.04	3.87		0.03	33.81	3.01
M	8.79	6.20	1.20	0.49	36.44	0.01	3.16	0.02	15.66	0.92	0.06	0.04	3.84		0.02	33.75	3.02
M	9.07	6.50	0.90	0.41	36.74	0.01	3.14	0.02	15.74	0.91	0.07	0.04	3.90		0.02	33.81	2.95
M	9.09	7.30	1.10	0.41	36.56	0.01	3.18	0.01	15.71	0.91	0.04	0.04	3.81		0.02	33.77	3.01
M	8.87	7.40	1.00	0.48	36.38	0.01	3.13	0.01	15.86	0.91	0.05	0.04	3.81		0.02	33.77	2.96
M	8.84	6.40	1.00	0.47	36.37	0.01	3.16	0.01	15.66	0.91	0.04	0.03	3.89		0.03	33.80	2.94
O	8.77	6.50	1.30	0.41	36.30	0.01	2.95	0.11	14.50	0.85		0.03	3.91	1.70	0.01	33.25	2.84
O	8.79	6.70	1.30	0.40	36.30	0.01	2.93	0.11	14.50	0.85		0.03	3.89	1.72	0.01	33.48	2.86
O	8.83	6.30	1.20	0.40	36.10	0.01	2.92	0.11	14.55	0.85		0.03	3.86	1.68	0.01	33.39	2.88
O	8.90	6.30	1.20	0.41	36.30	0.01	2.92	0.10	14.50	0.85		0.03	3.86	1.71	0.02	33.31	2.87
O	8.75	6.60	1.20	0.40	36.30	0.01	2.95	0.11	14.55	0.86		0.03	3.90	1.71	0.01	33.80	2.88
O	8.76	6.70	1.30	0.40	36.20	0.01	2.95	0.11	14.50	0.85		0.03	3.86	1.74	0.01	33.53	2.87
O	8.70	6.30	1.20	0.40	36.40	0.01	2.95	0.11	14.55	0.85		0.03	3.93	1.75	0.01	33.73	2.88
O	8.61	6.40	1.20	0.40	36.30	0.01	2.93	0.11	14.60	0.86		0.03	3.93	1.74	0.01	33.58	2.88
P	9.11	6.40	1.20	0.51	36.10		2.99	0.18	14.50	0.86			4.04	1.60	0.03	33.73	2.95
P	9.17	6.40	1.10	0.51	36.20		2.95	0.18	14.50	0.85			4.06	1.58	0.03	33.77	2.95
P	9.22	6.30	1.20	0.51	36.10		2.94	0.18	14.40	0.85			3.94	1.52	0.02	33.76	2.96
P	9.08	6.10	1.10	0.54	36.10		2.95	0.18	14.50	0.85			4.13	1.52	0.03	33.68	2.94
P	9.07	6.60	1.20	0.49	36.20		3.00	0.18	14.40	0.84			3.96	1.55	0.03	33.66	2.95
P	8.52	6.20	1.00	0.49	36.10		2.96	0.18	14.40	0.84			3.91	1.44	0.03	33.78	2.98
P	8.95	6.70	1.20	0.50	36.40		2.97	0.18	14.60	0.85			4.06	1.56	0.03	33.65	2.95
P	8.47	6.40	1.10	0.48	36.20		2.95	0.18	14.50	0.85			3.92	1.57	0.02	33.71	2.95

12. Measurement of Uncertainty: The samples used in the certification process were selected in such a way as to represent the entire batch of material and were taken from the final packaged units; therefore all possible sources of uncertainty (sample uncertainty and measurement uncertainty) are included in the final combined standard uncertainty determination.

The uncertainty measurement takes into consideration the between lab and the within lab variances and is calculated from the square roots of the variances of these components using the formula:

Combined standard uncertainty=sqrt((between lab.var/no of labs) + ( mean square within lab.var /no of assays))

These uncertainty measurements may be used, by laboratories, as a component for calculating the total uncertainty for method validation according to the relevant ISO guidelines.

Analyte	Method	Unit	S '	σL ²	SW ³	CSU ⁴
F	ISE	%	0.232	0.159	0.162	0.057
U	M/ICP	ppm	0.391	0.270	0.258	0.090
Th	M/ICP	ppm	0.110	0.077	0.064	0.024
Al2O3	XRF	%	0.049	0.052	0.016	0.020
CaO	XRF	%	0.209	0.162	0.139	0.060
Fe2O3	XRF	%	0.032	0.025	0.025	0.011
K2O	XRF	%	0.026	0.030	0.003	0.011
MgO	XRF	%	0.449	0.459	0.071	0.163
MnO	XRF	%	0.034	0.038	0.007	0.014
P2O5	XRF	%	0.008	0.009	0.003	0.004
SiO2	XRF	%	0.100	0.082	0.054	0.028
TiO2	XRF	%	0.006	0.006	0.004	0.003
LOI	XRF	%	0.301	0.284	0.118	0.102
SG	pycnometer		0.043	0.036	0.025	0.013

S - Std Dev for use on control charts.
σ ^L - Betw Lab Std Dev, for use to calculate a measure of accuracy.
S W - Within Lab Stc Dev, for use to calculate a measure of precision.
CSU - Combined Standard Uncertainty, a component for use to calculate the total uncertainty in method validation.

13. Certified values: The Certified, Provisional and Indicated values listed on p1 of each certificate fulfill the AMIS statistical criteria regarding agreement for certification and have been independently validated by Dr Barry Smee, BSc, PhD, P.Geo, (B.C.).

14. Metrological Traceability: The values quoted herein are based on the consensus values derived from statistical analysis of the data from an inter laboratory measurement program. Traceability to SI units is via the standards used by the individual laboratories, the majority of which are accredited, who have maintained measurement traceability during the analytical process.

15. Certification: AMIS0250 is a new material.

16. Period of validity: The certified values are valid for this product, while still sealed in its original packaging, until notification to the contrary. The stability of the material will be subject to continuous testing for the duration of the inventory. Should product stability become an issue, all customers will be notified and notification to that effect will be placed on the www.amis.co.za website.

17. Minimum sample size: The majority of laboratories reporting used a 0.5g sample size for the ICP. This is the recommended minimum sample size for the use of this material.

18. Availability: This product is available in Laboratory Packs containing 1kg of material and Explorer Packs containing custom weights (from 50g to 250g) of material. The Laboratory Packs are sealed bottles delivered in sealed foil pouches. The Explorer Packs contain material in standard geochem envelopes, vacuum sealed in foil pouches.

19. Recommended use: The data used to characterize this CRM has been scrutinized using outlier treatment techniques. This, together with the number of participating laboratories, should overcome any "inter-laboratory issues" and should lead to a very accurate measure for the given methods, notwithstanding the underlying assumption that what the good inter-laboratory labs reported was accurate. However an amount of bad data might have had an effect, resulting in limits which in some situations might be too broad for the effective monitoring of a single analytical method, laboratory or production process. Users should set their own limits based on their own data quality objectives and control measurements, after determining the performance characteristics of their own particular method, using a minimum of 20 analyses using this CRM. User set limits should normally be within the limits recommended on p1 and 2 of this certificate.

20. Legal Notice: This certificate and the reference material described in it have been prepared with due care and attention. However AMIS, Set Point Technology (Pty) Ltd, Mike McWha, Dr Barry Smee and Smee and Associates Ltd; accept no liability for any decisions or actions taken following the use of the reference material.

26 June 2012

Certifying Officers:

African Mineral Standards: _______________________________________

Mike McWha BSc (Hons), FGSSA, MAusIMM, Pr.Sci.Nat

Geochemist: ____________________________________________________

Barry W. Smee BSc, PhD, P.Geo, (B.C.)

Analyte	Method	Unit	Mean	2SD	RSD%	n
Al	M/ICP	%	0.24	0.03	6.98	87
As	M/ICP	ppm	23.63	7.27	15.38	86
Ba	M/ICP	ppm	56.22	15.67	13.94	95
Be	M/ICP	ppm	0.17	0.08	24.03	85
Bi	M/ICP	ppm	0.09	0.04	22.98	70
Ca	M/ICP	%	24.26	2.16	4.46	76
Cd	M/ICP	ppm	4.79	0.66	6.89	89
Ce	M/ICP	ppm	23.31	4.00	8.57	89
Co	M/ICP	ppm	4.31	0.76	8.75	90
Cr	M/ICP	ppm	51.36	25.92	25.24	80
Cs	M/ICP	ppm	0.69	0.10	7.25	70
Cu	M/ICP	ppm	41.11	12.31	14.97	77
Dy	M/ICP	ppm	0.54	0.08	6.91	38
Er	M/ICP	ppm	0.35	0.07	10.54	40
Eu	M/ICP	ppm	0.19	0.03	7.25	39
Fe	M/ICP	%	2.04	0.16	3.87	90
Ga	M/ICP	ppm	0.91	0.52	28.54	91
Gd	M/ICP	ppm	0.66	0.10	7.74	39
Ge	M/ICP	ppm	0.10	0.13	60.67	31
Hf	M/ICP	ppm	0.19	0.08	21.56	85
Ho	M/ICP	ppm	0.11	0.02	8.93	39
In	M/ICP	ppm	0.02	0.01	21.12	68
K	M/ICP	%	0.10	0.02	7.95	91
La	M/ICP	ppm	16.51	2.83	8.57	89
Li	M/ICP	ppm	7.93	1.92	12.12	81
Lu	M/ICP	ppm	0.04	0.02	17.58	55
Mg	M/ICP	%	8.64	0.83	4.78	87
Mn	M/ICP	ppm	6298	493	3.92	91
Mo	M/ICP	ppm	0.79	0.31	19.44	88
Na	M/ICP	%	0.04	0.01	15.02	80
Nb	M/ICP	ppm	0.47	0.18	19.33	84
Nd	M/ICP	ppm	6.24	0.59	4.75	39
Ni	M/ICP	ppm	14.68	6.97	23.73	86
P	M/ICP	ppm	158.10	50.85	16.08	79
Pb	M/ICP	ppm	11.36	3.84	16.90	86
Pd	M/ICP	ppm	4.40	0.24	2.72	8
Pr	M/ICP	ppm	2.11	0.27	6.35	39
Rb	M/ICP	ppm	4.03	0.62	7.74	80
Re	M/ICP	ppm	0.00	0.00	27.26	32
S	M/ICP	%	0.70	0.11	7.51	87
Sb	M/ICP	ppm	1.46	0.41	14.06	87
Sc	M/ICP	ppm	0.57	0.59	51.81	49
Se	M/ICP	ppm	0.66	0.79	60.07	39
Si	M/ICP	%	1.95	0.04	1.06	8
Sm	M/ICP	ppm	0.69	0.04	3.05	35
Sn	M/ICP	ppm	0.41	0.43	52.87	50
Sr	M/ICP	ppm	41.24	5.80	7.03	94
Ta	M/ICP	ppm	0.34	0.66	97.54	25
Tb	M/ICP	ppm	0.09	0.04	22.83	64

Appendix – uncertified trace element statistics

AMIS0461

Certified Reference Material

Limestone, South Africa

Certificate of Analysis

AMIS

(A Division of Torre Analytical Services (Pty) Limited) (Reg. No. 1989/000201/07) A: 11 Avalon Road, West Lake View Ext 11, Modderfontein, South Africa P: PO Box 856, Isando, 1600, Gauteng, South Africa T: +27 (0) 11 923-0800 W: www.amis.co.za

	TABLE OF CONTENTS ………………………………………………………………………………………………
	LIST OF TABLES LIST OF APPENDICES
	SUMMARY STATISTICS

$\mathbf 1$ .	Certified Concentrations and Uncertainties
2.	Intended Use
3.	Abbreviations and Symbols
4.	Uncertified Concentration Values
5.	Units
6.	Analytical and Physical Methods
7.	Origin of Material
8.	Approximate Mineral and Chemical Composition
9.	Health and Safety
	10. Method of Preparation
	11. Handling
	12. Methods of Analysis Requested
	13. Information Requested of Participating Laboratories
	14. Certification of Mean and Estimation of Measurement Uncertainty 8
	15. Participating Laboratories
	16. Accepted Assay Data
	17. Reported Values
	18. Validation of Accuracy (Trueness)
	19. Metrological Traceability
	20. Period of Validity
	21. Minimum Sample Size
	22. Availability
	23. Recommended use in Quality Control
	24. Legal Notice
	REFERENCES
	APPENDICES

LIST OF TABLES

Table 1. Certified major oxides concentrations, two standard deviations, combined and expanded uncertainty4
Table 2. Provisional major oxides concentrations, two standard deviations, combined and expanded
uncertainty4
Table 3. Abbreviations, symbols and descriptions. 5
Table 4. Data used to calculate the certified values after removal of outliers. 10
Table 5. Uncertified element concentrations statistics. 15
Table 6. A single-factor ANOVA table showing key elements. Where P is the total number of groups, or laboratories. P-1 is 1 less than number of laboratories, P (n-1) is the number of data values minus number of groups (equals degrees of freedom for each group added together), and P-1 + P(n-1) is 1 less than number of data points. MS is the mean squares of between laboratories and within
laboratories. After Ellison et al., (2009), Table 6.2, page 6119 Table 7. CRM certified value, quoted expanded uncertainty U, the coverage factor for the CRM,
k=2.25 and mean for n=9 replicates and corresponding standard deviation for the replicate data20 Table 8. T-distribution table for t-critical values (t crit.) for a two-tailed t-test at a 95% level of
confidence23

LIST OF APPENDICES

Appendix 1: Uncertified Element Statistics15
Appendix 2. Certification of Reference Material and Estimation of Measurement Uncertainty15
Appendix 3. Example: Comparison of Mean and Certified Value for Validation of Accuracy 20
Appendix 4. Using the CRM in Quality Control21
Appendix 5. Conversion to Air-dry Basis 22
Appendix 6. T-distribution table 23

SUMMARY STATISTICS

Recommended Concentrations and Limits (at two Standard Deviations)

Major Oxides

Certified Concentrations

Analyte	Method	4Certified(µ)	6Two Standard deviation (2s) ±	Unit
Al2O3	XRF1	0.80	0.11	%
CaO	XRF1	48.31	1.67	%
Cr2O3	XRF1	0.378	0.030	%
Fe2O3	XRF1	0.782	0.13	%
K2O	XRF1	0.03	0.01	%
MgO	XRF1	0.833	0.071	%
MnO	XRF1	0.05	0.01	%
SiO2	XRF1	10.1	0.68	%
CCE	ASTM C253	86.60	1.95	%
LOI	LOI2	38.71	0.39	%

Provisional Concentrations

Analyte	Method	8Provisional	6Two Standard deviation (2s) ±	Unit
Na2O	XRF1	0.02	0.01	%
SO3	XRF1	0.05	0.03	%
TiO2	XRF1	0.05	0.02	%

1. Certified Concentrations and Uncertainties

AMIS0461 is a new standard material, developed and certified in May, 2017. Table 1 gives the certified major oxides concentrations, combined and expanded uncertainty for certified reference material. Table 2 shows the provisional major oxides concentrations, two standard deviations, combined and expanded uncertainty.

Table 1. Certified major oxides concentrations, two standard deviations, combined and expanded uncertainty.

Analyte	Method	4Certified(µ)	N	n	k	% RSD	5Combined uncertainty (uc)	6Two Standard deviation (2s) ±	7Expanded uncertainty (U) ±	Unit
Al2O3	XRF1	0.80	14	112	2.16	6.9	0.055	0.11	0.1	%
CaO	XRF1	48.31	15	120	2.14	1.7	0.837	1.67	2	%
Cr2O3	XRF1	0.378	7	56	2.45	4.0	0.015	0.030	0.04	%
Fe2O3	XRF1	0.782	15	120	2.14	8.3	0.065	0.13	0.1	%
K2O	XRF1	0.03	11	84	2.23	18.5	0.006	0.01	0.01	%
MgO	XRF1	0.833	12	96	2.20	4.2	0.035	0.07	0.1	%
MnO	XRF1	0.05	9	72	2.31	11.0	0.005	0.01	0.01	%
SiO2	XRF1	10.1	13	104	2.18	3.4	0.34	0.68	0.7	%
CCE	ASTM C253	86.60	2	16	12.71	1.1	0.976	1.95	12	%
LOI	LOI2	38.71	14	112	2.16	0.5	0.194	0.39	0.4	%

Table 2. Provisional major oxides concentrations, two standard deviations, combined and expanded uncertainty.

Analyte	Method	8Provisional	N	n	k	% RSD	5Combined uncertainty (uc)	6Two Standard deviation (2s) ±	7Expanded uncertainty (U) ±	Unit
Na2O	XRF1	0.02	6	44	2.57	33.1	0.006	0.01	0.02	%
SO3	XRF1	0.05	5	40	2.78	29.5	0.014	0.03	0.04	%
TiO2	XRF1	0.05	11	85	2.23	17.4	0.009	0.02	0.02	%

1. XRF is X-ray Fluorescence
1. LOI is Loss on Ignition
1. CCE is Calcium Carbonate Equivalent, ASTM is American Society for Testing and Minerals
1. The certified value µ, is an unweighted grand mean of the means of N accepted sets of data from different laboratories and n number of test sample replicates. The certified value is traceable to SI units and is reported on a dry basis.
1. The combined uncertainty of the certified value is the within-laboratory reproducibility standard deviation derived from the analysis of variance of results from N number of laboratories and n number of sample replicates.
1. The two standard deviations (2s) is calculated as for example: u^c x 2 = 0.23 x 2=0.46%. See section 23, page 12 for recommended use in quality control.
1. Expanded uncertainty (U) at a confidence level of 95% is determined by multiplication of the combined uncertainty (uc) with a coverage factor (k) found from N-1 degrees of freedom (see Appendix 6 for t-distribution table). Example: U = 2.36 x 0.23=0.54%.
1. Provisional: the reported provisional concentrations are to be used as indicative values only.

2. Intended Use

AMIS0461 is a matrix matched Certified Reference Material, fit for use as a control sample in routine assay laboratory quality control when inserted within runs of test samples and measured in parallel to test samples. This material can also be used for method development, use as independent calibration verification check standard (i.e. if not used as a calibration standard in an instrument calibration), or for validation of accuracy in a method validation exercise (see Appendix 3). The recommend procedure for the use of this CRM as a control standard in laboratory quality control is to develop a Shewhart chart, where a mean value and corresponding 1, 2 and 3 standard deviations are derived from replicate measurements of the CRM (see Appendix 4). This CRM can also be used to assess inter-laboratory or instrument bias and establish within-laboratory precision and withinlaboratory reproducibility. The certified concentrations and expanded uncertainty for this material are property values based on an inter-laboratory measurement campaign and reflect consensus results from the laboratories that participated in the exercise.

3. Abbreviations and Symbols

Abbreviations and symbols used in this document are shown in Table 3.

Table 3. Abbreviations, symbols and descriptions.

Abbreviation/Symbol	Description
Alpha (α)	Significance level (denoted by alpha, 'α') of 0.05 or 5%
ANOVA	Analysis of variance by statistical means
BIF	Banded iron formation
CRM	Certified reference material
df	Degrees of freedom, typically, n-1, or N-1
Fcalc	Calculated F statistic from ANOVA or Fisher's test
F-critical or Fcrit	F-critical value from F-distribution table
GOI	Gain on ignition
H0	Null hypothesis
H1	Alternate hypothesis
g/t	Grams per tonne
k	Coverage factor, e.g. k=2 for 95% level of confidence
LOC	Level of confidence or confidence level
LOD	Limit of detection
LOQ	Limit of quantitation
LOI	Loss on ignition
MS	Mean squares (ANOVA)
MSb	Mean squares between(ANOVA)
MSw	Mean squares within (ANOVA)
N	Number of labs
n	Number of replicates
μ	Property or certified value of a CRM

Table 3: Continued

Abbreviation/Symbol	Description
p	'p-value' a measure of the strength of evidence against H0
P	Total number of data points in ANOVA
ppm	Parts per million. Equivalent to g/t
RSD	Relative standard deviation usually expressed as % at a 68% LOC
Replicates	Replication is the repetition of an experimental condition so that the variability associated with an analysis can be estimated (ASTM E1847)
s	Standard deviation
sr	Within laboratory repeatability as derived from ANOVA
ss	Between laboratory standard deviation as derived from ANOVA
SS	Sum of squares in ANOVA
SST	Total variation in ANOVA
SSB	Between group (laboratory) variance
SSW	Within group (laboratory) variance
2s	Two times standard deviation
SI	Standard International system of units
tcalc	Calculated t statistic from a one-sample, two-tailed t-test
t-critical or tcrit	t-critical value at given alpha and degrees of freedom
Tonne	A metric ton, is a unit of mass equaling 1000 kilograms
=TINV(5%,df)	MS Excel function for t-critical value at LOC 95% and df
U	Expanded uncertainty at a given k
u	Standard uncertainty at k=1
uc	Combined standard uncertainty at k=1
µm	Micron, is an SI derived unit of length equaling 1×10−6 of a meter

4. Uncertified Concentration Values

Appendix 1 gives uncertified concentrations for other elements present in the CRM.

5. Units

All results for major oxides are reported as oxides in percentages.

6. Analytical and Physical Methods

A complete list of analytical and physical methods as generic method codes with a brief description of the methods is available on the AMIS web site www.amis.co.za

7. Origin of Material

Limestone is a sedimentary rock composed primarily of calcium carbonate (CaCO3) in the form of the mineral calcite. It most commonly forms in clear, warm, shallow marine waters. It is usually an organic sedimentary rock that forms from the accumulation of shell, coral, algal, and fecal debris. It can also be a chemical sedimentary rock formed by the precipitation of calcium carbonate from lake or ocean water.

8. Approximate Mineral and Chemical Composition

Limestone is by definition a rock that contains at least 50% calcium carbonate in the form of calcite by weight. All limestones contain at least a few percent other materials. These can be small particles of quartz, feldspar, clay minerals, pyrite, siderite, and other minerals. It can also contain large nodules of chert, pyrite, or siderite.

9. Health and Safety

The material is a very fine powder coloured Very light grey (5Y 8/1). Safety precautions for handling fine particulate matter are recommended, such as the use of safety glasses, breathing protection, gloves and a laboratory coat.

10. Method of Preparation

The particle size distribution for this material was shown to have a nominal top size of 54µm (95% passing 54µm). The procedure of preparation in brief is as follows: the material was crushed, dry-milled and air-classified to <54µm. It was then blended in a bi-conical mixer, systematically divided and sealed into 1kg Laboratory Packs. Explorer Packs are then subdivided from the Laboratory Packs as required. Final packaged units were then selected on a random basis and submitted for analysis to an independent laboratory accredited with the ISO17025:2005 standard of general requirements for the competence of testing and calibration laboratories. The results obtained from this laboratory are then evaluated statistically by AMIS for homogeneity.

11. Handling

The material is packaged in Laboratory Packs and Explorer Packs that must be shaken or otherwise agitated before use. The analyte concentrations are quoted on a dry basis, therefore the user needs to determine the moisture content in order to convert any obtained assay values to an air-dry basis (see Appendix 5 for an example calculation).

12. Methods of Analysis Requested

1. Majors (Al2O3, CaO, Cr2O3, Fe2O3, K2O, MgO, MnO, Na2O, SiO2, SO3, TiO2, P2O5, V2O5, and LOI) XRF
1. Calcium Carbonate Equivalent (CCE) by ASTM C25 Method

13. Information Requested of Participating Laboratories

The following information was requested of the participating laboratories for the development of this CRM:

1. State aliquots used for all determinations.
1. All results for major elements to be reported as oxides in percentages.
1. Report all QC data, to include replicates, blanks and certified reference materials used.
1. State and provide brief description of analytical techniques used.
1. Send a PDF and excel of the results. (Excel template format was sent to the labs. If you have not received it, please email Melesha and she will send it through)

14. Certification of Mean and Estimation of Measurement Uncertainty

The samples used in this certification process have been selected in such a way as to represent the entire batch of material and were taken from the final packaged units; therefore all possible sources of uncertainty are included in the combined standard uncertainty determination. Initially the data submitted by all of the laboratories are subjected to a z-score test, equation [1] to exclude outliers and the remaining data sets examined for their normality in distribution. This is followed by the exclusion of further outliers as defined by the IUPAC Harmonised Protocol of 1995 in which both Cochran and Grubbs tests are applied until all outliers are identified, equations [2], [3], [4] and [5]. A grand mean and standard deviation is re-calculated using all remaining data (Thompson, 2008; Carr, 2011) (see Appendix 2). These data are then subjected to an analysis of variance (ANOVA) as per equations, [10],[11],[12],[13] and [14] in Appendix 2. The mean squares for data within and between laboratories derived from ANOVA are used to compute the within-laboratory reproducibility, or combined standard uncertainty as shown in Appendix 2, equation [15], [16] and [17]. The Horwitz function is applied to assess the performance of the data under consideration with respect to precision as relative standard deviation (equations [6], [7] and [8]). Should the ratio of the observed %RSD and a calculated %RSD be <2, the observed %RSD is accepted (Horwitz & Albert, 2006). A final certified value is then found by calculating a grand mean of equally weighted individual laboratory means [9] (ISO Guide 35, 2003; Barwick & Pritchard, 2011).

An uncertainty statement on AMIS certificates is typically presented as:

The expanded uncertainty (U) is determined by multiplication of the combined uncertainty (uc) with a coverage factor (k) found from N-1 degrees of freedom and a t-critical value at a level of confidence of 95% (EURACHEM / CITAC Guide CG 4., (2012), (see Table 8, Appendix 6 for a t-critical table). N is the number of laboratory means used in the establishment of the certified value. Since the estimated values of the CRM approximate a normal distribution with combined uncertainty, uc, the certified value of the CRM is understood to lie in the interval defined by U with a level of confidence of 95 % (Thompson & Lowthian, 2011).

Appendix 2 gives detail on the principles used for certification of the reported assay values and estimation of measurement uncertainty.

15. Participating Laboratories

Twenty one laboratories were each given eight randomly selected packages of the CRM. Eighteen laboratories of the twenty one laboratories submitted results in time for certification.

The 18 laboratories that provided results timeously are:

1. AfriSam (South Africa) (Pty) Ltd Centre of Product Excellence
1. ALS Chemex Laboratory Group Johannesburg SA
1. Antech Zimbabwe
1. ARGETEST
1. Bureau Veritas Minerals Ultra Trace Pty Ltd
1. "Dorfner Anzaplan Analysenzentrum und Anlagenplanungsgesellschaft mbH"
1. Idwala Lime- Danielskull
1. Genalysis Laboratory Services (W Australia P)
1. Intertek Utama Services (Indonesia)
1. SCI-BA Laboratories and Scientific Consulting
1. SGS Mineral Services Lakefield (Canada)
1. SGS South Africa
1. Set Point Laboratories (Isando) SA
1. PPC Rwanda
1. ALS Chemex Laboratory Group Lima (Peru)
1. ALS OMAC (Ireland)
1. UIS
1. SA Lime and Gypsum

16. Accepted Assay Data

Data from the 18 laboratories used for certification are set out in Table 4.

XRF Al2O3	XRF CaO	XRF Cr2O3	XRF Fe2O3	XRF K2O	XRF MgO	XRF MnO	XRF Na2O	XRF SiO2	XRF TiO2	LOI























































0.71	47.25	0.38145	0.77	0.03	0.86	0.05	0.02	10.2	0.06	38.5

Table 4. Data used to calculate the certified values after removal of outliers.

Assay Data (Continued)

XRF Al2O3	XRF CaO	XRF Cr2O3	XRF Fe2O3	XRF K2O	XRF MgO	XRF MnO	XRF Na2O	XRF P2O5	XRF SiO2	XRF TiO2	XRF SO3	LOI
%	%	%	%	%	%	%	%	%	%	%	%	%
0.76	48.43	0.38	0.74	0.03	0.86	0.05	0.02		10.20	0.07		38.50
0.72	48.27	0.37	0.74	0.03	0.86	0.05	0.02		10.20	0.06		38.50
0.71	48.12	0.38	0.74	0.03	0.87	0.05	0.02		10.10	0.06		38.60
0.73	47.82	0.38	0.73	0.04	0.86	0.05	0.02		10.10	0.06		38.60
0.69	48.21	0.38	0.74	0.04	0.87	0.05	0.02		10.10	0.05		38.60
0.71 0.79	48.23 48.40	0.38	0.74 0.83	0.04 0.03	0.87 0.84	0.05 0.05	0.02 0.02		10.10 7.64	0.05 0.05		38.60 38.50
0.81	48.50		0.82	0.03	0.84	0.05	0.02		7.80	0.05		38.60
0.83	48.20		0.82	0.04	0.84	0.05	0.01		7.56	0.05		38.60
0.81	48.20		0.82	0.04	0.84	0.05	0.02		7.88	0.05		38.50
0.81	47.80		0.80	0.02	0.85	0.05	0.02		7.81	0.05		38.50
0.80	48.50		0.81	0.03	0.84	0.05	0.01		7.73	0.05		38.60
0.82	47.90		0.80	0.03	0.84	0.05	0.01		7.62	0.04		38.50
0.79 0.77	48.00 48.15		0.83 0.82	0.03 0.02	0.85 0.77	0.05	0.01 0.01		7.56 10.07	0.05 0.05		38.50 39.10
0.78	48.00		0.80	0.03	0.76		0.02		10.07	0.05		39.00
0.77	48.04		0.81	0.03	0.78		0.03		10.05	0.05		39.00
0.78	48.25		0.80	0.02	0.77		0.02		10.08	0.05		39.00
0.79	48.36		0.81	0.03	0.75		0.03		10.07	0.05		39.10
0.77	48.20		0.81	0.03	0.77		0.02		10.05	0.05		38.80
0.78	48.19		0.82	0.03	0.77		0.02		10.04	0.05		39.00
0.77	48.12		0.80	0.03	0.77		0.03		10.04	0.05		39.00
0.80 0.81	49.96 49.82		0.87 0.89	0.03 0.03	0.85 0.84				9.89 10.05	0.05 0.04		38.77 38.77
0.80	50.16		0.87	0.03	0.86				9.93	0.05		38.76
0.80	49.74		0.88	0.03	0.86				9.90	0.04		38.79
0.80	49.79		0.89		0.87				10.00	0.05		38.73
0.80	50.02		0.92		0.86				9.96			38.76
0.80	50.07		0.88		0.84				9.87			38.76
0.81	50.09		0.91		0.87				9.80			38.77
0.76	47.77		0.80		0.83				10.16			39.05
0.76 0.77	47.79 47.81		0.80 0.80		0.83 0.83				10.19 10.15			39.04 39.06
0.77	47.81		0.81		0.83				10.19			39.00
0.76	47.84		0.81		0.82				10.17			39.00
0.77	47.76		0.81		0.81				10.12			39.02
0.76	47.85		0.79		0.84				10.11			39.01
0.77	47.88		0.79		0.83				10.13			38.98
0.78	49.50		0.77						10.07			38.63
0.77 0.77	49.30 49.90		0.84 0.78						10.04 10.00			38.66 38.67
0.79	49.40		0.77						9.99			38.66
0.77	49.20		0.85						9.96			38.66
0.78	49.80		0.76						9.93			38.65
0.75	49.40		0.78						10.05			38.67
0.77	49.40		0.75						10.02			38.61
0.79	47.56		0.65									38.64
0.79	47.75		0.65									38.61
0.78 0.78	47.63 47.47		0.66 0.66									38.90 38.64
0.79	47.65		0.65									38.66
0.78	47.46		0.65									38.69
0.82	47.51		0.64									38.69
0.78	47.55		0.64									38.71
	48.30		0.81
	48.30		0.81
	48.10		0.77
	48.00 47.80		0.77 0.76
	47.80		0.76
	48.20		0.77
	48.20		0.78

17. Reported Values

The certified values listed in this certificate fulfil the AMIS statistical criteria (see section 14) regarding agreement for certification and have been independently validated by Allan Fraser.

18. Validation of Accuracy (Trueness)

This CRM can be used to validate accuracy (trueness) as required in method validation as stated in the ISO17025:2005 standard, clause 5.4. See Appendix 3 for an example on the validation of accuracy using replicate data derived from the analysis of a CRM.

19. Metrological Traceability

The values quoted herein are based on the consensus values derived from statistical analysis of the data from an inter-laboratory measurement program. Traceability to SI units is via the standards used by the individual laboratories the majority of which are accredited to the ISO17025:2005 general requirements for the competence of testing and calibration laboratories and who have maintained measurement traceability during the analytical process.

20. Period of Validity

The certified values are valid for this product, while still sealed in its original packaging, until notification to the contrary. The stability of the material will be subject to continuous testing for the duration of the inventory. Should product stability become an issue, all customers will be notified and notification to that effect will be placed on the www.amis.co.za website.

21. Minimum Sample Size

The majority of laboratories reporting used a 0.5g sample size for the ICP-OES and a 30g sample size for the fire assay. These are the recommended minimum sample sizes for the use of this material.

22. Availability

This product is available in Laboratory Packs containing 1kg of material and Explorer Packs containing custom weights (from 50 to 250g) of material. The Laboratory Packs are sealed bottles delivered in sealed foil pouches. The Explorer Packs contain material in standard geochem envelopes, nitrogen flushed and vacuum sealed in foil pouches.

23. Recommended use in Quality Control

Users should set their own limits i.e. 1, 2 and 3 standard deviations from an obtained mean value based on at least 10 replicate analyses using this CRM (see Appendix 4 for detail on the use of this CRM in quality control).

24. Legal Notice

This certificate and the reference material described in it have been prepared with due care and attention. However AMIS, a division of Torre Analytical Services (Pty) Ltd, Thivhafuni Matodzi, and Allan Fraser; accept no liability for any decisions or actions taken following the use of the reference material.

04 May 2017

Certifying Officers:

Version: 0.02

Amended: 13 September 2017 Certified CCE, 19 September 2017 Added ASTM C25 (method)

African Mineral Standards: _______________________________________

Thivhafuni Matodzi

Geochemist:__________________________________________________

Allan Fraser M.Sc. (Geology), N.D. (Analytical Chem.), Pr.Sci.Nat.

REFERENCES

Abzalov, M. (2011). Sampling Errors and Control of Assay Data Quality in Exploration and Mining Geology, Applications and Experiences of Quality Control. Ivanov, O., (Ed.), InTech, DOI: 10.5772/14965. Available from: http://www.intechopen.com/books/applications-and experiences-of-quality-control/sampling-errors-and-control-of-assay-data-quality-in exploration-and-mining-geology. Accessed 25th September, 2016.
ASTM E122-09e1, Standard Practice for Calculating Sample Size to Estimate, With Specified Precision, the Average for a Characteristic of a Lot or Process, ASTM International, West Conshohocken, PA, 2011, www.astm.org
Barwick V.J., Pritchard E. (Eds). (2011). Eurachem Guide; Terminology in Analytical Measurement Introduction to VIM 3 (2011). ISBN 978-0-948926-29-7.
Carr R.H. (2011). Estimating errors using graphs and taking good data. California State University Los Angeles. March 2011. 14. http://web.calstatela.edu/faculty/kaniol/Err-Gph-Meas-IBooklet.pdf. Retrieved: 29 August, 2016.
Cochran, W.G. (1950). The Comparison of Percentages in Matched Samples. Biometrika, 37, 256- 66.
Ellison, S., Barwick, V., Duguid Farrant, T. (2009). Practical statistics for the analytical scientist, a bench guide. 2nd Edition. RSC Publishing. 25-172.
ERM Application Note 1. (2005). Comparison of a measurement value with a certified value. European Commission – Joint Research Centre Institute for Reference Materials and Measurements (IRMM). 1-2.
EURACHEM / CITAC Guide CG 4. (2012). Quantifying uncertainty in analytical measurement. 3rd Edition. Editors: Ellison, S. L. R., Williams, A. 4-121.
Eurolab Technical Report No.1/2007. (2007). Measurement uncertainty revisited: Alternative approaches to uncertainty evaluation. European Federation of National Associations of Measurement, Testing and Laboratories. 43-46.
Fraser, A.W. (2015). Minimising uncertainty in measurement and improving limit of detection in gold bearing ores from concentrations predicted by linear regression in atomic absorption spectrometry. M.Sc. thesis (unpublished), University of Johannesburg: 199 pages.
Grubbs, F.E. (1969). Procedures for detecting outlying observations in samples. Technometrics, 11, 1969. 1-21.
Horwitz, W., Albert, R. (2006). The Horwitz Ratio (HorRat): A useful index of method performance with respect to precision, Journal of Association of Official Analytical Chemists International, 89: 1095-1109.
ISO/IEC 17025:2005(E).(2005). General requirements for the competence of testing and calibration laboratories. 2 nd Edition: 14-59.
ISO Guide 35 (2003). Certification of reference materials General and Statistical principles, 3rd edition. ISO/REMCO WG 1.
ISO 5725-2:1994. Accuracy (trueness and precision) of measurement methods and results -- Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method.
Long, J., Winefordner, J. (1983). Limit of detection a closer look at the IUPAC definition. Analytical Chemistry 55: 712A - 724A.
Miller, J., Miller, J. (2010). Statistics for analytical chemistry. 6 th Edition. New York: Ellis Horwood.36- 126.
Nelsen T.C., Wehling P. (2008). Collaborative studies for quantitative chemical analytical methods. AACC International Report. Cereal Foods World. September – October 2008, Vol. 53, No. 5. 285-288.
Skoog, D., West, D. (1982). Fundamentals of analytical chemistry. 4th Edition. CBS College Publishing. Holt Saunders International Editions:39-73.
Thompson, M. (Ed.) (2008). Test for 'sufficient homogeneity' in a reference material. Analytical Methods Committee, AMCTB 17A, ISSN 1757-5958.
Thompson, M. (Ed.) (2010). Internal quality control in routine analysis. AMC Technical Brief. Analytical Methods Committee. AMCTB No.46. 2010. Issn 1757-5958.
Thompson, M., Lowthian, P. (2011). Notes on statistics and data quality for analytical chemists. Imperial College Press: 15-115.

APPENDICES

Appendix 1: Uncertified Element Statistics

Uncertified element statistics are shown in Table 5.

Table 5. Uncertified element concentrations statistics.

Element	Gen Method	N	Mean	s	RSD %	Unit
BaO	XRF	20	0.02	0.01	40.66	%
Cl	Various methods	24	<100	<0.001	<0.001	ppm
CuO	XRF	8	0.01	<0.001	6.04	%
Fe	XRF	8	4551.00	48.00	1.05	ppm
Mn	XRF	8	396.90	8	1.96	ppm
Mn2O3	XRF	7	0.08	<0.001	<0.001	%
Mn3O4	XRF	8	0.06	<0.001	1.96	%
S	Combustion/LECO	15	0.01	<0.001	31.05	%
S	XRF	8	0.02	<0.001	11.08	%
V2O5	XRF	9	0.01	<0.001	27.44	%
ZrO2	XRF	8	0.01	<0.001	5.34	%
P2O5	XRF	3	0.008	0.002	28.89	%

……………………………………………………………...

Appendix 2. Certification of Reference Material and Estimation of Measurement Uncertainty (Prepared by Allan Fraser)

In the establishment of a consensus value for the CRM, outlier tests are carried out followed by performance statistics and the estimation of the measurement uncertainty. In practice, it is highly likely that data generated by multiple laboratories as an inter-laboratory comparison of material for certification, will contain erroneous as well as extreme measurements (outliers). The influence of outliers on summary statistics needs to be minimised by the application of procedures for outlier identification on raw data. The application of z-scoring, Cochran test for suspect repeatability variances, along with Grubbs test as single and paired tests for suspect measurement values allows for the detection of outliers (IUPAC, 1995). Method performance in terms of precision as relative standard deviation is judged by the application of the Horwitz ratio, which gives an indication of whether the observed relative standard deviation at the concentration levels of analyte determined are acceptable (Horwitz & Albert, 2006).

In the absence of an extensive uncertainty budget, measurement uncertainty is estimated from the reproducibility standard deviation from inter-laboratory data and reported as an expanded uncertainty at typically a level of confidence of 95% (Miller & Miller, 2010).

The steps below give detail on the establishment of a consensus value through the elimination of outliers, method performance and estimation of measurement uncertainty using standard uncertainties and the analysis of variance.

Outlier Removal

An initial purge of outliers in inter-laboratory analyses of a candidate reference material is done using z-scoring followed by the exclusion of further outliers as defined by the IUPAC Harmonised Protocol of 1995. Here both Cochran and Grubbs tests are applied until all outliers are identified.

Z-Score

A z-score is calculated using equation [1]:

$$
z = \frac{x - x_a}{s_p} \tag{1}
$$

Where, is the result of a submitted sample, is the mean and is the standard deviation of the submitted results from all of the participating laboratories. Z-Scores are interpreted as follows:

||≤2 satisfactory performance 2<||≤3 questionable performance ||>2 unsatisfactory performance

(Thompson & Lowthian, 2011)

Data with z-scores exceeding 2 are discarded and are not included for further assessment.

Cochran Test

The test of Cochran (1950) as shown in equation [2] is applied to any suspect repeatability variances:

$$
C_{calc} = \frac{s_{max}^2}{\sum_{i=1}^l s_i^2}
$$
[2]

Where, , ² and ∑ 2 =1 , are the calculated values for Cochran's test, data set with the maximum variance and the sum of the variances of all of the participating laboratory datasets. The value is compared with a critical value, at a level of confidence of 95% and an alpha of 0.05% (see Ellison, et al., 2009, Appendix A, Table A.3a, page 209 for a table of critical values for the test of Cochran at LOC 95%).

According to ISO 5725-2 (1999), results from a laboratory with a suspect repeatability variance can be excluded if it is shown by the Cochran test to be an outlier. Therefore, if > , the laboratory with the maximum variance is removed. The data found to be excluded should not be >2/9, or 22% of the total data.

Grubbs Test

The test of Grubbs (1969) calculates a test statistic, G. In the detection of a single outlier, ¹ is found by using

$$
G_{1\,calc} = \frac{|Suspect\ value - \bar{x}|}{s} \tag{3}
$$

where the sample mean and standard deviation, ̅ and s, are calculated with the suspect value included. The ¹ statistic is compared to a critical value for N measurements. See Ellison, et al., 2009, Appendix A, Table A.2, page 208 for a table of critical values for the test of Cochran at LOC 95%. If the data set contains two or more suspect values at either the high end of the dataset or at the low end, or at both ends of the data range, the Grubbs test is adapted to detect such outliers by the calculation of ²

$$
G_{2\,calc} = \frac{|x_n - x_1|}{s} \tag{4}
$$

where, and ¹ are the suspect values that occur at the opposite ends of the dataset.

When there are two suspect values at the at the same end of the dataset two separate standard deviations of all of the data, ∗ is the standard deviation of the data with the two suspect values excluded with ³ given by:

$$
G_{3\,calc} = \frac{(n-3)s^*}{(n-1)s^2} \tag{5}
$$

Method Performance

The Horwitz function is used to assess the performance of the data under consideration, with respect to precision (Horwitz & Albert, 2006). A calculated %RSD is found using the Horwitz expression

$$
\%RSD = \pm 2^{(1-0.5\log C)} \tag{6}
$$

where, C is the analyte concentration in percent divided by 100 and log is the natural logarithm. The observed %RSD is calculated as

$$
Observed\ \%RSD = \frac{s}{Mean}x100\tag{7}
$$

where s is the standard deviation of n replicates.

The ratio of the observed %RSD and the calculated %RSD gives the Horwitz ratio (HorRat):

$$
HorRat = \frac{\%RSD \ Observed}{\%RSD \ Calculated}
$$
[8]

A HorRat <2 indicates that the method is of adequate precision. Should the HorRat be >2 the overall data are discarded and the candidate material considered not suitable for certification as the precision is excessive for the concentration of the analyte being determined (Nelsen & Wehling, 2008).

Grand Mean

The grand mean (̿) i.e. the certified value of a dataset is the total of all the data values divided by the total sample size (n) :

$$
\bar{x} = \sum_{n=1}^{\infty} \frac{x}{n}
$$
[9]

Certified Value

From ANOVA as per the description in section 14, an 'appropriate precision' as shown in [10] is calculated for sufficient homogeneity (Thompson, 2008):

$$
s_r \le 0.3u_c \tag{10}
$$

Where, is the within laboratory repeatability, as determined from [16]. Once [10] is satisfied, a grand mean [9] is calculated and this is taken to be the certified value.

Total Variation (SST)

The total variation (not the variance) comprises the sum of the squares of the differences of each mean with the grand mean.

$$
SST = \sum (x - \bar{x})^2
$$
[11]

Between Group Variation (SSB)

The variation due to the interaction between the laboratories is denoted SSB or Sum of Squares Between laboratories and given by [12]. If the laboratory means are close to each other (and therefore the Grand Mean) SSB will be a small value. There are P samples involved with one datum value for each sample (the sample mean), so there are P-1 degrees of freedom.

$$
SSB = \sum n(\bar{x} - \bar{\bar{x}})^2
$$
[12]

The variance due to the interaction between the laboratories is denoted MSB for Mean Square Between groups and is the SSB divided by its degrees of freedom.

$$
MS = \frac{SSB}{n-1} \tag{13}
$$

Within Group Variation (SSW)

The variation due to differences within individual samples is denoted SSW for Sum of Squares Within laboratories. The degrees of freedom are equal to the sum of the individual degrees of freedom for each sample. Since each sample has degrees of freedom (df) equal to one less than their sample sizes, and there are k samples, the total degrees of freedom is P less than the total sample size: df = n - P.

$$
SSW = \sum df \cdot s^2 \tag{14}
$$

The variance due to the differences within individual samples is denoted MSW for Mean Square Within groups. This is the within group variation divided by its degrees of freedom:

$$
MSW = \frac{SSW}{P - n} \tag{15}
$$

From equations [9] through [15], the ANOVA table as shown in Table 6 is developed.

Table 6. A single-factor ANOVA table showing key elements. Where P is the total number of groups, or laboratories. P-1 is 1 less than number of laboratories, P (n-1) is the number of data values minus number of groups (equals degrees of freedom for each group added together), and P-1 + P(n-1) is 1 less than number of data points. MS is the mean squares of between laboratories and within laboratories. After Ellison et al., (2009), Table 6.2, page 61.

Source	Sum of Squares	df	Mean Sum of Squares	F	p	Fcrit
Between Laboratories	SSB	P-1	MSB=SSB/df	MSB/MSW	=FDIST(x,df,df)	F-table
Within Laboratories	SSW	P(n-1)	MSW=SSW/df	_	_	_
Total	SSB+SSW	P-1 + P(n-1)	_	_	_	_

Combined Standard Uncertainty

The combined standard uncertainty (uc) represents the effects of random events such as days, instruments, and analysts on the precision of the analytical procedures of all accepted data of the participating laboratories. Using the output from ANOVA, the combined standard uncertainty (uc) is determined from the square root of the sum of squares of the variances of the within laboratory repeatability, and the between laboratory precision, :

$$
u_c = \sqrt{s_r^2 + s_s^2}
$$
[16]

Within laboratory repeatability is determined as

$$
s_r = \sqrt{MSB} \tag{17}
$$

and, the between laboratory precision as

$$
s_s = \sqrt{\frac{(MSW - MSB)}{n}}
$$
[18]

where is the mean squares of the within laboratory variance, is the mean squares for the between laboratories and in this case, is the number of replicates in a group of the accepted data (Thompson & Lowthian, 2011).

Expanded Uncertainty

The expanded uncertainty (U) at a confidence level of 95% is determined by multiplication of the combined uncertainty (uc) by a coverage factor (k) found from N-1 degrees of freedom (df), where N is the number of laboratory means accepted in the establishment of the certified value. The t-critical value for 5% significance can be found in a t-critical table (see Error! Reference source not found., or from S Excel as =TINV (5%, df).

Uncertainty Statement

Typically, an uncertainty statement is presented as follows: Au =0.77±0.04 g/t, where the number following the symbol ± is the numerical value of an expanded uncertainty, U = kuc, with U determined from a combined standard uncertainty multiplied by a coverage factor k = 2 or, a t-critical value for N-1 accepted laboratories. Since it can be assumed that the possible estimated values of the standard are approximately normally distributed with standard uncertainty, uc, the certified value of the CRM is believed to lie in the interval defined by U with a level of confidence of approximately 95 %, e.g. a mean value of 0.77±0.04g/t will have intervals of: 0.73<0.77<0.81 g/t.

Appendix 3. Example: Comparison of Mean and Certified Value for Validation of Accuracy (Prepared by Allan Fraser)

According to ERM (2005); Eurolab (2007); Abzalov (2011) and Carr (2011), the validation of accuracy for a given mean and certified value requires the inclusion of the measurement uncertainty of the CRM in a t-test for statistical significance. The classical Student's t-test as shown in [19], does not take into account the measurement uncertainty of the CRM. To compensate for this, Eurolab Technical Report No.1/2007 recommends equation [20] for the validation of CRMs with stated measurement uncertainties.

$$
t_{calc} = \frac{|\bar{x} - \mu|}{\frac{S}{\sqrt{n}}}
$$
[19]

$$
t_{calc} = \frac{|\bar{x} - \mu|}{\sqrt{(u_{\mu})^2 + \frac{s^2}{n}}}
$$
[20]

Where, is the calculated t-statistic, ̅the mean of n replicates with a standard deviation of s for a CRM of μ certified value. The standard uncertainty u is the stated expanded uncertainty (U) of the CRM divided by the coverage factor (k) as stated on the certificate of analysis. Note that the | | bars indicate that the absolute value between the mean and the certified value is to be used, i.e. ignore the sign.

An example in which [20] is used for validation of accuracy is given below.

Example

A CRM is independently replicated nine times for Al2O³ concentration by XRF analysis, i.e. 9 individual fused glass beads were prepared. The observed mean and standard deviation of the replicate data are shown with the certified value and expanded uncertainty in Table 7. In validation of accuracy, the hypothesis question is: Is the difference between the observed mean and the certified value statistically significant at a level of confidence of 95%? Alternatively put, is there sufficient evidence to conclude that the data i.e. replicates generated, are inaccurate?

The relevant hypotheses are:

Null hypothesis: H0: Mean = Certified value of CRM with stated measurement uncertainty. The acceptance of H⁰ means that accuracy is demonstrated; i.e. insufficient evidence to reject H0; Alternate hypothesis: H1: Mean ≠ Certified value of CRM with stated measurement uncertainty. The acceptance of H¹ means that accuracy is not demonstrated, i.e. there is sufficient evidence to accept H1;

Table 7. CRM certified value, quoted expanded uncertainty U, the coverage factor for the CRM, k=2.25 and mean for n=9 replicates and corresponding standard deviation for the replicate data.

CRM Certified Value	Expanded Uncertainty (U)	Coverage Factor (k)	Mean (n=9)	n	Standard Deviation (s)
4.62%	0.08%	2.25	4.59	9	0.01015

The standard uncertainty (u) is found by dividing the expanded uncertainty by the coverage factor:

$$
u = \frac{0.08}{2.25} = 0.0356 \, \%
$$

Using the observed mean for the replicate data (n=9) obtained for the CRM and substituting into [20]:

$$
t_{calc} = \frac{|\bar{x} - \mu|}{\sqrt{0.0356^2 + \frac{0.01015^2}{9}}} = \frac{|4.59 - 4.62|}{\sqrt{0.00126 + 0.00001145}} = 0.84
$$

Therefore, = 0.84 and (5%, 8) = 2.31 (df is 8, therefore, tcrit=2.31, see Appendix 6, page 23) which is >0.84. Similarly, the p-value=0.43 which is >0.05. This is strong evidence in favour of accepting the null hypothesis that there is no significant statistical difference between the certified value and the observed mean. Therefore, under the conditions that the uncertainty associated with the certified value is known the accuracy is validated for the CRM tested. If the null hypothesis is accepted that the mean obtained is not statistically different from the certified value, then the principle of traceability has been conformed to.

…………………………………………………………………………..

Appendix 4. Using the CRM in Quality Control (Prepared by Allan Fraser)

QC chart control limits should not be determined by the certified value and stated measurement uncertainty of the certified reference material used. These parameters although "certified" will never be known; it is only the corresponding statistical estimates, i.e. standard deviation and the mean calculated from replicated results that are known and these should be used in quality control charts. However, should the laboratory chose to use the certified value as the mean then the quoted 2s value for the CRM can be used in the quality control chart.

It is recommended that a Shewhart chart be developed for the use if this CRM is to be used as a control sample in laboratory quality control. A Shewhart chart is a plot of sequential assay results obtained from quality control material such as an AMIS CRM. The warning and control limits are based on the standard deviation obtained from the mean of the replicates of a CRM (Ellison, et al., 2009; Thompson, 2010).The procedure in preparing a Shewhart chart is as follows:

1. Analyse 10 to15 replicates or more of the AMIS CRM;
1. Apply the Grubbs test for outliers;
1. Determine the mean of the replicates after application of the Grubbs test;
1. Determine the standard deviation, using equation [21], of the replicates;
1. Calculate the standard deviation, s from:

$$
s = \sqrt{\frac{\sum (x_i - \bar{x})^2}{n - 1}}
$$
[21]

where, is an individual measurement in the data set, ̅ is the mean of the data set at n-1 degrees of freedom (df) and n is the number of replicates. The sample standard deviation can be found using the MS Excel formula "=stdev.s (number1;)".

1. Verify accuracy of the mean value using equation [20];
1. Once accuracy is verified, calculate ±2s and ±3s, where s is the standard deviation calculated from [21].
1. Construct the Shewhart control chart around the mean of n replicates;
1. Use ±2s as the warning limits;
1. Use ±3s as the control limits;
1. It is recommended that if 2 to 3 points are outside warning the limits analyse another sample and if it then within warning limits, continue. If it is outside the warning limits, stop and troubleshoot;
1. It is recommend that if any point is outside control limits, analyse another portion (sample) of the CRM. If it is within control limits, continue. If it is outside control limits, stop and troubleshoot;
1. For reference purposes, the CRM certified value can be plotted on the Shewhart chart alongside the mean value.

On a regular basis the accuracy of the replicates of the CRM should be assessed in terms of the certified value of the CRM using equation [20].

…………………………………………………………………………..

Appendix 5. Conversion to Air-dry Basis (Prepared by Allan Fraser)

Since AMIS certified analyte values are reported on a dry-basis, the user laboratory is required to dry a portion (accurately weigh out 1.0 grams in duplicate) of the CRM material in air at 105^oC in a drying oven to constant mass to determine the moisture content. Use a crucible with a flat inner surface with a surface area not smaller than 10 cm² with the CRM material spread evenly over same; this represents a 0.1 gram spread per cm² . In correcting the certified value for moisture content, a moisture correction factor is calculated:

$$
Moisture\ correction\ factor\ (MCF) = \frac{100 - %Moisture\ at\ 105^{\circ}C}{100}
$$
[22]

= [23]

Example

The moisture content determined at 105^oC on a CRM is 0.500%. The certified analyte concentration for the CRM is 12.62±0.52% (dry basis). Calculating the moisture correction factor using [22] gives:

$$
Moisture correction factor = \frac{100 - 0.500}{100} = 0.995
$$

Multiplying the factor of 0.995 by the certified value as stated on the certificate of analysis on a dry basis (as in [23]) gives the analyte concentration on an air-dry basis:

$$
0.995\ x\ 12.62\% = 12.56\%
$$

The stated measurement uncertainty also needs to be corrected using [22] and [23], e.g. 0.995 x 0.52 = 0.51(7), rounded to 0.52%. The air-dry basis concentration i.e. 12.56±0.52% is to be used as the certified value with its corresponding measurement of uncertainty.

…………………………………………………………………………

Appendix 6. T-distribution table

Table 8. T-distribution table for t-critical values (t crit.) for a two-tailed t-test at a 95% level of confidence.

df	Two-tailed	df	Two-tailed
1	12.71	23	2.06
2	4.30	24	2.06
3	3.18	25	2.06
4	2.78	26	2.05
5	2.57	27	2.05
6	2.44	28	2.04
7	2.36	29	2.04
8	2.30	30	2.04
9	2.26	35	2.03
10	2.22	40	2.02
11	2.20	45	2.01
12	2.17	50	2.00
13	2.16	55	2.00
14	2.14	60	2.00
15	2.13	70	1.99
16	2.12	80	1.98
17	2.11	90	1.98
18	2.10	100	1.98
19	2.09	120	1.98
20	2.08	Infinity	1.96
21	2.08
22	2.07

………………………………………………………………………………………………………………………

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P.No S.No		¥
-1			742015 4097929	184.	743109	4097981
$\mathcal{R}$	$\overline{z}$ 1		742800 4097925		12	743022 4097901 742999 4097944
			742664 8097934 4 742893 4098068	144	15	742961 4067852
м			5 742791 4008543
	6.		742854 4098300
÷.			742999 4096318
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Ruhsat, İşletme İzin ve ÇED Muafiyet Alanı Sınır Koordinatları

UTM KOORDINATLAR
DATUM: ED-50			COGRAFIK KOORDINATLAR
	PROJEKSIYON: 6 DERECE
DOM: 33			DATUM WGS-84
ZON : 36
Sıra N.	SAGA (Y)	YUKARI (X)	ENLEM (Y)	BOYLAM (X)
R.L.	742915.000	4097928.000	36.99450892	35.72929628
R ₂	742886.000	4097925.000	36.99448939	35.72896978
R ₃	742864.000	4097934.000	36.99457611	35.72872572
R.4	742893.000	4098068.000	36.99577518	35.72909441
R.5	742791.000	4098343.000	36 99827765	35.72803792
R.6	742884.000	4098309.000	36.99794750	35.72907098
R.7	742939.000	4098318.000	36.99801433	35.72969130
R.8	742945.000	4098317.000	36.99800377	35.72975833
R.9	743092.000	4098263.000	36.99747956	35.73139112
R.10	743260.000	4098301.000	36.99778086	35.73317704
R.11	743169.000	4097981.000	36.99492049	35.73216460
R.12	743022.000	4097951.000	36.99468837	35.73050480
R.13	742999.000	4097944.000	36.99463128	35.73024436
R.14	742961.000	4097932.000	36.99453305	35.72981394
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Kırma-Eleme Tesisi Alanı Sınır Koordinatları

UTM KOORDINATLAR
DATUM: ED-50			COĞRAFİK KOORDİNATLAR
	PROJEKSIYON: 6 DERECE
DOM: 33
ZON: 36			DATUM: WGS-84
Sira N.	SAGA (Y)	YUKARI (X)	ENLEM (Y)	BOYLAM (X)
К1	742989.206	4098278.111	36.99764218	35.73024205
K2	743070.356	4098253 951	36.99740367	35.73114524
К3	743061.374	4098218.952	36.99709085	35,73103313
K4	743026.374	4098232.890	36.99722541	35.73064472
K5	743014.914	4098206.662	36.99699129	35.73050759
K6	742959.472	4098235.677	35.99726773	35.72989459
		Alan: 0,44 Hektar

UTM KOORDINATLAR
DATUM: ED-50			COGRAFIK KOORDINATLAR
	PROJEKSIYON: 6 DERECE
DOM: 33
ZON: 36			DATUM : WGS-84
Sıra N.	SAGA (Y)	YUKARI (X)	ENLEM (Y)	BOYLAM (X)
S1	742858.809	4098303.818	36.99790727	35.72878652
82	742984.769	4098271.779	36 99758624	35.73019020
S3	742959.472	4098235.677	36.99726773	35.72989459
S4	742981.078	4098224.331	36.99716004	35.73013348
S5	742956.684	4098182.094	36.99678601	35.72984604
S6	742891.021	4098154.218	36.99655193	35.72909996
87	742895.047	4098204.704	36.99700551	35.72916140

Pasa Depolama Alanı Sınır Koordinatları

UTM KOORDINATLAR
DATUM : ED-50			COGRAFIK KOORDINATLAR
	PROJEKSIYON : 6 DERECE
DOM: 33
$ZON = 36$			DATUM WGS-84
Sıra N.	SAGA (Y)	YUKARI (X)	ENLEM (Y)	BOYLAM (X)
P1	742884.000	4098309.000	36.99794750	35.72907098
P2	742939.000	4098318.000	36.99801433	35.72969130
P3	742945.000	4098317.000	36.99800377	35.72975833
P4	743001.829	4098296.124	36.99780108	35.73038956
P6	742984.769	4098271.779	36.99758624	35.73019020
P6	42880.057	4098298.185	36.99785085	35.72903334
			Alan: 0.31 Hektar

T.C. ADANA VALILIĞİ ÇEVRE VE ŞEHİRCILIK IL MÜDÜRLÜĞÜ

Sayi: 90438820 E-2015747-220-03 8643 Konu : Kalker Ocağı, Kırma-Eleme Tesisi, Kirec Firini, Kirec Söndürme ve Paketleme Tesisi

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VİŞNE MADENCILİK ÜRETİM SAN. VE TİC. A.Ş. - ÇUKUROVA ŞUBESİ (Çokçapınar Köyü Arşandağı Mevkii)

Ceyhan / ADANA

(a) 18/06/2015 tarihli ve DYS 2015-9175 kayıt sayılı başvuru. Ilgi : (b) 28/09/2015 tarihli ve DYS 2015-14665 kayıt sayılı başvuru.

İlgi (a) yazıda; Adana İli, Ceyhan İlçesi, Çokçapınar Mahallesi (Köyü) Arşandağı Mevkiinde bulunan Kalker Ocağı (IR: 72839), Kireç Fırını, Kireç Söndürme ve Paketleme Tesisi (121.500.000 kg/yıl sönmemiş kireç kapasiteli) ile ilgili, Kireç üretim tesisi ve kireç ocağı (Kireç Ocağı Ruhsat No: 72839, Ruhsat Alanı 11,98 hektar) için Çukurova Kireç San. ve Tic. Ltd. Şti. adına, 16.12.2003 tarih ve 25318 sayılı Resmi Gazetede yayımlanarak yürürlüğe giren Çevresel Etki Değerlendirmesi Yönetmeliği Geçici 3. Maddesi kapsamında alınmış 2006 tarihli Çevresel Etki Değerlendirmesi Yönetmeliğinden muaf kararının bulunduğu, Çukurova Kireç Sanayi ve Ticaret Ltd. Şti. olan firma unvanının Çukurova Kireç Sanayi ve Ticaret A.Ş. olarak değiştirilmesine istinaden 24.09.2013 tarih ve 8515 sayılı yazımız ile unvan değişikliği konusunda ÇED Yönetmeliği kapsamında değerlendirme yapıldığı ve Çukurova Kireç Sanayi ve Ticaret A.Ş. alarak faaliyet gösterilmekte iken 02.04.2014 tarih ve 8541 sayılı Türkiye Ticaret Sicil Gazetesinde ilan edilerek firma unvanının Vişne Madencilik Sanayi ve Ticaret A.Ş.-Çukurova Şubesi olarak değiştiği belirtilmekte olup; konu ile ilgili Çevresel Etki Değerlendirmesi Yönetmeliği kapsamında yeniden değerlendirme yapılması istenilmektedir.

Ilgi (b) yazıda ise tesiste yer alan Kırma-Eleme Tesisinin de 16.12.2003 tarihinden önce kurulu ve çalışır durumda olduğu belirtilmiş ve bu konuda ilgili belgeler İl Müdürlüğümüze sunulmuş olup; ilgi (a) yazı ile yapılan CED Yönetmeliği çerçevesinde değerlendirme talebinin Kırma-Eleme Tesisinide kapsayacak şekilde yeniden yapılması talep edilmiştir.

25/11/2014 tarih ve 29186 sayılı Resmi Gazete'de yayımlanarak yürürlüğe giren ÇED Yönetmeliği Geçici 2. Maddesinde, "Çevresel Etki Değerlendirmesi Yönetmeliğinin ilk yayım tarihi olan 7/2/1993 tarihinden önce üretime veya işletmeye başladığı belgelenen projeler Çevresel Etki Değerlendirmesi kapsamı dışındadır." denilmektedir. İlgi (a) ve (b) yazılar ve eklerinin incelenmesi neticesinde Kalker Ocağı (IR: 72839 Ruhsat Alanı 11,98 hektar), Kırma-Eleme Tesisi, Kireç Fırını, Kireç Söndürme ve Paketleme Tesisi (121.500.000 kg/yıl sönmemiş kireç kapasiteli) aynı faaliyetin, aynı adreste ve aynı kapasite ile Vişne Madencilik Sanayi ve Ticaret A.Ş.-Çukurova Şubesi olarak yürütülmesi konusu Çevresel Etki Değerlendirmesinden muaf olarak değerlendirilmiş olup; 25/11/2014 tarih ve 29186 sayılı ÇED Yönetmeliği kapsamında yapılacak bir işlem bulunmamaktadır

Ancak, planlanan yatırım ile ilgili olarak, 5491 sayılı kanunla değişik 2872 sayılı Çevre Kanunu ile bu Kanuna istinaden çıkarılan Yönetmeliklerin ilgili hükümlerine uyulması ve diğer mer'i mevzuat çerçevesinde öngörülen gerekli izinlerin alınması, ekolojik dengenin bozulmamasına, çevrenin korunmasına ve geliştirilmesine yönelik tedbirlere riayet edilmesi, faaliyet konusunun ve/veya yakıt değişmesi, kapasite artırımına gidilmesinin planlanması vb. durumlarda değişiklik gerçekleştirilmeden önce İl Müdürlüğümüze başvuru yapılması gerekmektedir.

Gereğini rica ederim.

T Tohum

Hanlar IDEN Vali a. Vali Yardımcısı

T.C. ADANA VALILIĞİ ÇEVRE VE ŞEHİRCILIK İL MÜDÜRLÜĞÜ

Savi: 90438820 E-2015747-220-03 Konu : Kalker Ocağı ÇED değerlendirme.

VISNE MADENCILIK ÜRETIM SAN. VE TİC. A.Ş. - ÇUKUROVA ŞUBESI (Çokçapınar Mahallesi Arşandağı Mevkii)

Ceyhan / ADANA

(a) 12.01.2017 tarih ve 2017-582 kayıt sayılı başvurunuz. $\text{Ilg}$ : (b) 16.02.2017 tarih ve 2017-2338 kayıt sayılı yazınız.

İlgi (a) yazıda; Adana İli, Çeyhan İlçesi, Çokçapınar Mahallesi (Köyü) Arşandağı Mevkiinde, Vişne Madencilik Üretim San. ve A.Ş. uhdesinde bulunan 72839 Ruhsat Sicil Numaralı sahada gerçekleştirilen Kalker (Kireçtaşı) Ocağı, Kırma-Eleme Tesisi, Kireç Üretim Tesisi ve Kireç Söndürme ve Paketleme Tesisi ile ilgili 02.10.2015 tarih ve 8643 sayılı ÇED Muafiyet yazısının bulunduğu belirtilmekte olup; 121.500 ton/yıl sönmemiş kireç üretim kapasitesine sahip tesisin, kalker ocağında üretmesi gereken tüvenan kalker miktarının yazı ile tarafınıza verilmesi istenilmektedir.

02.10.2015 tarih ve 86432 sayılı yazımızda, Kalker Ocağı (IR: 72839 Ruhsat Alanı 11,98 hektar), Kırma-Eleme Tesisi, Kireç Fırını, Kireç Söndürme ve Paketleme Tesisi (121.500.000 kg/yıl sönmemiş kireç kapasiteli) faaliyetinin, aynı adreste ve aynı kapasite ile Vişne Madencilik Sanayi ve Ticaret A.Ş.-Çukurova Şubesi olarak yürütülmesi konusu Çevresel Etki Değerlendirmesinden muaf olarak değerlendirilmiş ve 25/11/2014 tarih ve 29186 sayılı ÇED Yönetmeliği kapsamında yapılacak bir işlem bulunmağı belirtilmiş olup, 72839 Ruhsat Sicil Numaralı Kalker (Kireçtaşı) Ocağındaki üretim kapasitesi belirtilmemiştir.

Ilgi (a) ve ilgi (b) yazıların eklerinde II Müdürlüğümüze sunulan belgelerden sönmemiş kireç üretim tesisinin ve kalker (kireçtaşı) ocağının Çevresel Etki Değerlendirmesi Yönetmeliğinin ilk yayım tarihi olan 07.02.1993 tarihinden önce üretime geçtiği anlaşılmakta olup, 121.500 ton/yıl sönmemiş kireç üretebilmek için 267,300 ton/yıl Kireçtaşına ve bu kireçtaşını üretebilmek için de 672.000 ton/yıl tüvenan kalker ihtiyaç olduğu Ceyhan Ticaret Odasından Alınma 09.02.2017 tarih ve 2017/3 numaralı Kapasite Raporunda belirtilmiştir.

Bu kapsamda, 72839 Ruhsat Sicil Numaralı Kalker (Kireçtaşı) Ocağında 672.000 ton/yıl tüvenan kalker üretilmesi konusunda 25/11/2014 tarih ve 29186 sayılı ÇED Yönetmeliği kapsamında yapılacak bir işlem bulunmamakla birlikte 02.10.2015 tarih ve 86432 sayılı ÇED kapsam dışı yazısı geçerliliğini korumaktadır.

Ancak, 5491 sayılı kanunla değişik 2872 sayılı Çevre Kanunu ile bu Kanuna istinaden çıkarılan Yönetmeliklerin ilgili hükümlerine uyulması ve diğer mer'i mevzuat çerçevesinde öngörülen gerekli izinlerin alınması, ekolojik dengenin bozulmamasına, çevrenin korunmasına ve geliştirilmesine yönelik tedbirlere riayet edilmesi, faaliyet konusunun değişmesi ve/veya kapasite artırımına gidilmesinin planlanması vb. durumlarda değişiklik gerçekleştirilmeden önce İl Müdürlüğümüze başvuru yapılması hususunda;

Gereğini rica ederim.

Ahmet KIRILMAZ Çevre ve Şehircilik İl Müdürü

Bu Belge Elektronik

Imza İle İmzalanmıştır

Mehmet MERT Sicil: 3073074

Cevre ve Şehircilik İl Müdürlüğü Güzelyalı Mahallesi 81021 Sok. No: 4 Çukurova/ ADANA Ayrıntılı Bilgi İçin İrtibat: Nuri BAŞARAN (Kimyager) Telefon: (0 322) 235 0717 Faks (0 322) 2350656

Bu belge 5070 sayılı elektronik imza kanununa göre güvenli elektronik imza ile imzalanmıştır.

Evrak teyidine http://evrakdogrulama.csb.gov.tr adresinden Belge Num.:50438820-220.03-E.1587 ve Barkod Num.:9778457 bilgileriyle erişebilirsiniz.

Çevre Şehircilik İl Müdürlüğü

ADANA VALILIĞI

U.
H

CEVRE İZİN BELGESİ

Başlangıç Tarihi Bitiş Tarihi Belge No Tesis Adı

ADANA,ÇOKÇAPINAR Mahallesi, ARŞANDAĞI MEVKİİ KÜME EVLER, No: 5-1, VİŞNE MADENCİLİK ÜRETİM SANAYİ VE TİC.A.Ş. : CEYHAN, Türkiye 223211900.0.1 Hava Emisyon : 9250410552 29.07.2026 29.07.2021 Çevre İzin ve Lisans Konusu İşletme Vergi No Tesis Adresi

Yukarıda adı ve açık adresi belirtilen tesise Çevre İzin ve Lisans Yönetmeliği kapsamında ÇEVRE İZİN BELGESİ verilmiş olup 28.07.2021 tarihli ve 73971906-150/E.8477 sayılı yazı ile birlikte geçerlidir. Ayrı kullanılmaz.

Çevre ve Şehircilik İl Müdürü Re-imzalidar Halit ERGİN

5070 sayılı Elektronik İmza Kanunu gereği bu belge elektronik imza ile imzalanmıştır.

adana valiligi adama valibgi adana valiligi adama valiligi adana valiligi i adana valilià

Sağa $(Y)$ Vukarı (X)	742915 4097928	742886 4097925	742864 4097934	742893 409806K	742791 4098343	. 742884 48938309	. $-742939$ 4098318
Saga (Y) Yukarı (X)	S.NOKTA 742945 4098317	9 NOKTA 743092 1098263	ID.NOKTA 143250 1008301	LNOKTA 74311/4 4097981	2 NOKTA 743022 4997951	ELNORTA 742999 4197944	HAOKEA 742961 1007032

Not. Adam II Özel İdaresi Tarafından düzenlenen 12.11.2013 mith ve 564 sayılı rubsata istirinden unvan değişikliği üzerine düzenlenmiştir.

8- İşyeri açma ve çalışma ruhsatı alanı : 11.98 Hektar

9- Işletme yöntemi

10- İşyerinin GSM sınıfı-

11- Veriliş tarihi

: LSmif GSM

: Acik Isletme

: 29.09.2015/651

ADANA SANAYİ ODASI				Geçerlilik Süresi Sonu	KAPASİTE RAPORU		Rapor Tarihi :01.12.2023	Jakive (	Top8
				25.05.2025			Rapor No	:2023/772
Firma Ünvanı Tescilli Markaları Vergi Dairesi/No Isyeri SGK No MERSIS No		SIRKETI ÇUKUROVA SUBESI :Hasan Tahsin V.D.Bşk. / 9250410552 :2.2352.01.01.1031598.001.05.79 :09250410552000025			VİŞNE MADENCİLİK ÜRETİM SANAYİ VE TİCARET ANONİM:		Sanayi Sicil No :618103 Oda Sicil No Ticaret Sicil No :7163 Faaliyet Kodu :08.11.06 (NACE)		:5120
Üretimin Yapıldığı Yer	Adres				: Çokçapınar Mahallesi, 5301 Cadde, No:3, İç Kapı:1 CEYHAN / ADANA
		Isyeri Tel (Kodlu): 322-6362202 e-posta : [email protected]			Faks: 322-6362248 Web: www.visnemadencilik.com
Merkez	Adres	İZMİR			Kültür Mahallesi, Şehit Nevres Bulvan, Kızılay İş Merkezi, 3/7, Alsancak, KONAK /
		Büro Tel (Kodlu): 232-4630003			Faks: 232-4631106
Cretim Konulari		:Kırmataş üretimi
Üretim Tesisinin Durumu			Sermaye Kıymetler Durumu (TL)
Kiracı Arazi (m2)		Makine ve Toçhizat Değeri			10.660,021		Mühendis:		Personel Durumu
Toplam Kapalı	120,000	Tescilli Sermayesi			100.000.000		Teknisyen :
Saha (m2)	3.000						Usta :		ä
Bins Insant Tipi	CELÍK- KONST.						Isci :		33
							Idari Pers.		4
Üretim Faaliyetine Başlama Taribi : 08.04.2014							Toplam :		44
	Yabancı Sermaye
Ulkesi		Oranı (%)		Patent	Know How		Gayri Maddi Hak
Sertifikalar :						Lisans		Ulkesi
Yukarıda ünvanı yazılı işletmenin, işyerinde mevcut makine ve teçhizatının yürürlükteki yöntem ve kriterlere göre teorik olarak hesaplanan azami üretim kapasitesi ile tüketim kapasitesini kapsayan bu kapasite raporu 30.11.2023 günü tarafımızdan düzenlerimistir. RAPORTÓR
				LEKSPER			2.EKSPER
Zahide TOPRAK Sanayi Sorumlusu			SÜLEYMAN SIRRI AĞBAS				EGE KUMCU
				Insaat Mühendisi			Makine Mühendisi




Zahide TOPRAK
Sanayi Hizmetleri Birimi

ADANA SANAYÎ ODASI - Ticaret Sicil No: 7163 / Vergi No: 9250410552
VÎSNE MADENCÎLÎK ÛRETÎM SANAYÎ VE TÎCARET ANONÎM SÎRKETÎ ÇUKUROVA SUBESÎ

TABLO : I MAKİNE VE TEÇHİZAT (FİRMAYA AİT)

ADRES : Çokçapınar Mahallesi, 5301 Cadde, No:3, İç Kapı:1 CEYHAN / ADANA

Konkasör tesisi

Makine Kodu	Adet Makine ve Techizat(Cinsi Ve Teknik Özellikleri)			Puan Yerli/İthal Gücü (KW)
	3 Vidalı Elevatör Besleme Üniteleri		0 Y	30.0
	3 Aspiratör Fam ve Sulu Fan Uniteleri		0 ¹ Y	60.0
	Kirec Silosu		0 Y
	Seperatör Ayırıcı Sistemi		0 Y	0.0
	10 Helezon Sistemleri		0 ¹ Y	22.5
	4 Kağıt Torba Yükleme Ekipmanları		0 Y	55.0
	Trafo ve müstemilatları (400 kw.)		0 ^Y	6.0
	1 Trafo ve müştemilatları (2000 kw.)		0 Y	0.0
	1 Jeneratör (40 kw.)		0 ¹	0.0
	4 Sulama sistemleri			0.0
	1 Rock Drill		0 Y 0 _X	0.0
28.92.40	Ceneli kinci			250.0
28.92.40	3 Elek sistemi		0 Y	132.0.
28.22.17	22 Bant sistemi		0 Y	22.5
28.92.40	1 Sekonder çeneli kırıcı		0 ^Y	100.0
28.92.40	1 DMK kinci (döner paletli kinci)		0 Y	75.0
28.92.40	1 Cekiçli Kırıcı		0 Y	250.0
	1 Izgaralı besleme bunkeri	0 Y		22.5
	5 Ürün bunkeri	0 Y		30.0
28:13.24	2 Kompresör	oly		0.0
28.92.27	1 Paletli ekskavatör (261 kw)	0 ^Y		13.0
28.92.25	1 Lastik tekerlekli yükleyici (163 kw)	0 Y		0.0
	4 Damperli kamyon (4x295 kw)	0 Y		163.0
	1 Arazöz (sulama aracı) (150 kw)	0 Y		0.0
	2 Torbalı filtre sistemi	0 ^Y		150.0
	Toplam:	0 Y		0.0

1851.21 BG

TOBB tarafından 04.12.2023 tarih ve 48561 no ile onaylanmıştır. En son 25.05.2025 tarihine kadar geçerlidir. Sayfa 2/6

ADANA SANAYÎ ODASI - Ticaret Sicil No: 7163 / Vergi No: 9250410552
VÎŞNE MADENCÎLÎK ÛRETÎM SANAYÎ VE TÎCARET ANONÎM ŞÎRKETÎ ÇUKUROVA ŞUBESÎ

TABLO : II YILLIK ÜRETİM KAPASİTESİ

Madde Kodu	[Ürün Adı(Cins-Özellik Ticari Ve Teknik Adı)
08.12.12.30.02	$MICIR$ $(1,2,3$ nolu)	Miktar	Birin
08.11.20.50.04		433.758.000 kilogram
	TAS TOZU	233.562.000 kilogram

TOBB tarafından 04.12.2023 tarih ve 48561 no ile onaylanmıştır. En son 25.05.2025 tarihine kadar geçerlidir. Sayfa 3/6

ADANA SANAYÎ ODASI - Ticaret Sicil No: 7163 / Vergi No: 9250410552
VÎSNE MADENCILÎK ÛRETÎM SANAYÎ VE TÎCARET ANONÎM ŞÎRKETÎ ÇUKUROVA SUBESÎ

TABLO : III KAPASİTE HESARI

(Raporun hangi maksatla düzenlendiği : Yenileme)

Firma işyerinde kurulu bulunan tesiste kırmataş üretimi yapılmaktadır. Kapasite hesabında Grup 2901 Kırmataş imalatı kriterleri kullanılmıştır.

İşletme ruhsat bilgileri:

İli: Adana

İlçesi : Ceyhan

Köyü : Çokçapınar

Ruhsat Numarası: 72839

Ruhsat Grubu : II-A Grup

Ruhsatın yürürlüğe giriş tarihi : 25.05.2015

Ruhsatın bitim tarihi: 25.05.2025

Erisim Numarası: 3063757

Ruhsat alanı: 11.98 hektar

Ruhsat safhası: İsletme

Ruhsat sahibi : Vișne Madencilik Ūr. San. ve Tic. A.Ş.

Vergi Daire ve No : Kordon V.D. Bşk. 9250410552

Adres : Şehit Nevres Bulvarı No:3 Kat 7 Alsancak/Konak/İzmir

*** Konkasör (kırmataş tesisi) kapasitesi :

335 ton/s. kapasiteli tesiste agrega malzeme kırılarak 1,2,3 nolu mıcır ve taş tozu üretimi yapılmaktadır.

Konkasör kapasitesi: 335 ton/s., R: 0.83 K: 335.000 kg/s. x 8 sa. x 300 gün x 0.83 = 667.320.000 kg/yil agrega

Agrega üretimi dağılımı:

K1:667.320.000 x %65 = 433.758.000 kg/yil (1,2,3 nolu) Micir

K2:667.320.000 x %35 = 233.562.000 kg/yil Taştozu

İhtiyaç maddeleri : Taş (kalker vb.): 667.320.000 kg/yıl (kendi ocağından karşılanıyor) Motorin: (2605 kw. x 0.2500 x 8 x 300) 1.563.000 kg/yil

TOBB tarafından 04.12.2023 tarih ve 48561 no ile onaylanmıştır. En son 25.05.2025 tarihine kadar geçerlidir. Sayfa 4/6

ADANA SANAYÎ ODASI - Ticaret Sicil No: 7163 / Vergi No: 9250410552
VÎŞNE MADENCILÎK ÛRETÎM SANAYÎ VE TÎCARET ANONÎM SÎRKETÎ CUKUROVA SUBESÎ

$\sigma = -\frac{1}{2} \frac{d\phi}{d\phi}$

TABLO : IV YILLIK TÜKETİM KAPASİTESİ

Madde Kodu		Tüketim Maddeleri(Cins-Özellik Ve Teknik Adı)	Birim
19.20.26 $\lambda$	Motorin	×	kilogram	Miktar	Yazı ile
					$\substack{1.563,000\ \text{sOcBin}}$
			×

















		×

	OK.






	Zahide TOPRAK Sanayi Hizmetleri Birimi	TC

			0 5 ARALIK 2023

	ASLI GIBIDIR

TOI 26.48561 no ile onaylanmıştır. En son 25.05 2025 tarihine kadar geçerlidir. Sayfa 5/6

ADANA SANAYÎ ODASI - Ticaret Sicil No: 7163 / Vergi No: 9250410552
VÎŞNE MADENCÎLÎK ÛRETÎM SANAYÎ VE TÎCARET ANONÎM ŞÎRKETÎ ÇUKUROVA ŞUBESÎ İşbu kapasite raporu; oda tarafından ekspertiz tarihi itibariyle tespit edilmiş bilgileri içermekte olup, 6 sayfadan oluşmaktadır ve firmanın TOBB tarafından 24.11.2021 tarih ve 45754 sayı ile onaylı kapasite raporunu geçersiz kılar. İnceleyen:
TOBB Sanayi Müdürlüğü Ali Ihsan ERTEN Makine Mühendisi 1. Kapasite raporları TOBB tarafından belirlenen Usul ve Esaslar ile kriterler çerçevesinde düzenlenmektedir. 2. Inceleme tarihindeki çalışma şartları dikkate almarak, firmaların teorik olarak hesaplanan azami üretim kapasitesini ve bu kapasiteye ulaşılması şauşma şaruan ulkakate alınarak, nimaların izonik olarak nesaplanan azamı üretim kapasitesini ve bu
kapasiteye ulaşılması halinde ortalama olarak belirlenen hammadde ve yarı mamullerin cins ve miktarı 4.Birlikteki elektronik ortamda tutulan kapasite raporlarına ait kayıtlar esastır. 5.Bu kapasite raporundaki bilgilerin doğruluğundan eksper heyeti sorumludur. ODA ONAYI TÜRKİYE ODALAR VE TÜRKİYE ODALAR VE BORSALAR BIRLIGI BORSALAR BIRLIĞI ONAYI ONAYI TARIH VE NO $04.12.2023 * 048561$ Bota KOCAMAN Müjdat BAYRAMOĞLU Bu kapasite raporu 1. sayfada Birlikçe tespit Genel Sekreter edilen "Geçerlilik süresi sonu" na kadar Metalurji Mühendisi yürürlüktedir. Zahide TOPRAK U 5 ARALIK 2023 Sanayi Hizmetleri Birimi ASLI GIBIDIR

TOBB tarafından 04.12.2023 tarih ve 48561 no ile onaylanmıştır. En son 25.05.2025 tarihine kadar geçerlidir. Savfa 6/6

T.C. ADANA VALİLİĞİ İl Emniyet Müdürlüğü

izin Belge No
PATBIS No

g ł. $2023/18$
01-2023-01215

$1.0$

$f_{\rm eff}$

SALE

Verilis Tarihi: Q8/06/2023
	Bitis Tarihi: 25/05/2025
Güncelleme Tarihi:
Güncelleme Nedeni :

PATLAYICI MADDE SATIN ALMA VE KULLANMA İZİN BELGESİ

Belge Doğrulama Adresi: https://eimzglego.gov.tr

IZIN BELGESİ SAHIBINİN
ADI SOYADI / UNVANI	Vişne Madencilik Üretim Sanayi ve Ticaret A.Ş.
ADRESI	Vergi No: 9250410552 : Alsancak Şehit Nevres Bulvarı No:3/7 Konak / İZMİR
SORUMLU KİŞİ	: Utku YÜKSEL
ATESLEYİCİLER	T.C. No: 11105212026 : Adem KARA (24665024706). Hasan KUŞDEMİR (12898289276), Hacı Mehmet İRKİN (46162989982), Bilal PEKEL (67549276938), Mehmet GÜRZ (66697305316), Ramazan ADIBELLI (51124510852), İslam İRKİN (46099992086), Sercan ARIN (20095085942), Mehmet KANDEMIR (17413602622), Ferhat URUN (39532444532), Turgay TIRAS (47959255860), Mehmet KANDEMIR (17413602622), İsmail YEL (30272518996),
NAKİLCİLER	: Adem KARABOYUN (53488387040), Ahmet ÜNAL (11035099020), Ali ORAL (45433254224), Ali SARI (37972936488), Ali YILDIRIM (28615851916), Arif ÜN (16798000764), Arif PEHLIVAN (10387215300), Atilia AYDINCI (13339276206), Bilai PEKEL (67549276938), Bozan YAĞMURLU (38260347856), Caner HAMZA (26770491534), Cuma KABA (42283341524), Cihat KUVVET [13486111634], Cumali KOCA (15346251658), Emincan AYSAN (51595397464), Erdoğan SOYDAN (11086191636). Erhan YILMAZ (13732184290). Erkan AVAG (14851026478). Fatih FINDIK (13915158384), Gökhan KAYA (12073393682), Hacı Mehmet İRKİN (46162989982), Hakan YARADAN (41981040388), Hamdi ŞENTÜRK (20092707298), Haydar SUNGUR (33016936988), Hilmi KÜÇÜKERDEM (13462113348), Hüseyin Kazi ARSLUNTAN (16999161462), Hüseyin YEL (30158522758), İbrahim KAYA (15064183064), İbrahim COŞKUN (21194489198). İsmail GÖKHAN (27406501566), Kasım ZENCİR (42361339146), Kazım KAYIŞ (32606030594), Melih MERSIN (18055039630), Memis CAKALCI (64609378632), Mevlüt CÖKLÜ (22166298152), Murat KARA (40753018884), Mustafa KOZAN (11030382042), Mustafa Yalçın GÖL (17210176982), Necmi BAŞLI (12001162496), Nuh ORMAN (26408157474), Nurettin ELİDEMİR (14572155730). Önder BAYRAM (29363033302), Özgür POLAT (39682711232). Özgür TAŞDEMİR (14650025856), Ramazan ADIBELLİ (51124510852), Ramazan GÜNDOĞAN (14005047304), Recep TURGUT (15850033320), Sarper DUR (71560145098), Selçuk ERGEN (47458169194), Sercan ARIN (20095085942), Sertaç AVCI (16270114170), Sezayi KOÇAK (16705080872), Süleyman SARIGÜL (45580232458), Süleyman SARIGÜL (45535233998), Şenol SENTÜRK (20017709758), Veysel DAĞ (13279120454), Yalçın SAĞLAMTUNÇ (22081024188), Yusuf ALAGOZ (15448045674)
DEPO ADRESI VE KAPASITESI	: 1 - Nitronet Patlayıcı Maddeler ve Kimya Sanayi Ticaret Limited Şirketi' nin Osmaniye İli Cevdetiye Beldesi Karakız Yarığı mevkiinde bulunan (200) ton kapasiteli sürekli yerüstü hafif sutreli sabit patlayıcı madde deposunun (4.000) kg'lık kısmı, (PATBİS NO: 80-2019-00005)
	2 - Akgün Patlayıcı Maddeler Ticaret ve Limited Şirketi' nin İlimiz Çukurova İlçesi, Salbaş Beldesi, Fadıl Köyü, Akyar mevkiinde bulunan yüz (100) ton kapasiteli sabit patlayıcı madde deposunun (10.000) kg. lik kısmı, (PATBİS NO:01-2019-00001)
	3 - Kaysan Silah Sanayi ve Ticaret Limited Şirketi' nin Kahraman Maraş İli, Onikişubat İlçesi, Onsen Pinarbaşı Mahallesinde bulunan yetmiş beş (75) ton' luk Deposunun (9.000) kg. lık kısmı, (PATBIS NO:46-2019-00001)
	4 - Nobel Explosives Patlayıcı Maddeler Sanayi ve Ticaret Anonim Şirketi' nin Ankara İli, Mamak İlçesi, Lalahan Karşıyaka Mahallesi 51411 Ada, 1-2 Parsel Ekincik Mevkii Serpmeler No:12 Adresindeki 500 ton kapasiteli deposunun (5.000) kg. lık kısmı, (PATBİS NO:06-2019-00003)
	Bu belge, güvenli elektronik imza ile imzalanmıştır. Belge Doğrutama Kodu:3:2d31b4-66f1-40fa-a12f-haf998e61e2d Belge Doğrulama Adresi: https://ein.org

SATIN ALINACAK PATLAYICI MADDELERİN :

CINSI	MIKTARI
	Günlük	Yıllık
Dinamit [kg] Anfo (kg)	104	12.480
	3.400	408,000
Elektrikli Kapsull (adet) Elektriksiz Kapsul		360
(adet)	164	19.680

Bu belge 6551 sayılı Kanunun uygulamasını gösterir 87/12028 karar sayılı Tüzüğün 118'inci maddesine istinaden, İlimiz Ceyhan İlçesi Çokçapınar Mahallesi mevkiinde bulunan RN:72839 numaralı II (a) grubu (kalker) işletme ruhsat sahasında kullanılmak üzere verilmiştir.

ACIKLAMALAR:

1) Bu belge Tehlikeli Maddeler ve Tehlikeli Atık Zorunlu Mali Sorumluluk Sigorta Poliçesi ile birlikte geçerlidir.

2) Tüzüğün 53. maddesi gereği; patlayıcı maddelerin nakli için yerel kolluktan Taşıma İzin Belgesi alınataktır.

3) Tahsis edilen patlayıcı maddeler sadece bu belgede ismi bulunan nakil görevlilerince taşınacak ve sadece ismi bulunan ateşleyicilerce kullanılacaktır.

4) Belgede cinsi bulunmayan patlayıcılar cinsi bulunan patlayıcıların altına eklenecektir. Ateşleyici ve nakilcilerin sayısının fazla olması ve belgeye sığmaması durumunda bu kişiler için ayrı liste düzenlenecek, liste Valilik makamınca onaylanacak ve belgeyi düzenleyen birimin mührüyle mühürlenecektir.

5) Belgedeki patlayıcı madde isimleri talebe göre düzenlenerek silinebilecektir.

NOT :Adana Çevre, Şehircilik ve İklim Değişikliği İl Müdürlüğünün E.90438820-100-6499656 sayılı sayılı ihtiyaç raporuna istinaden patlayıcı madde miktarları belirlenmiştir. Buna göre Yılda 12 ay çalışılarak, 2-3 gün arayla ayda 10, yılda en fazla 120 patlatma yapılacaktır. Her patlatmada 80 delik delinerek 160 adet elektriksiz kapsül, 3 adet elektrikli kapsul ve 4 adet sıralar arası gecikme kapsulü kullanılacak. Her delikte 42.5 kg anfo, 1.3 kg. dinamit ve 2 adet elektriksiz kapsul kullanılacaktır.

Muzaffer SAHINER Vali a. Vali Yardımcısı

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9081_rns_2025-01-27_8eab248f-9267-4138-9473-b5976b401726.pdf

Sicil:72839 (ER:3063757) Numaralı II-A Grup Ruhsat Sahasına Ait UMREK- 2023 Kodlu Değerlendirme Raporu Ekleri Cilt 2

VİŞNE MADENCİLİK ÜRETİM SANAYİ VE TİC.

Sicil:72839 (ER:3063757) Numaralı

II-A Grup Ruhsat Sahasına Ait

UMREK- 2023 Kodlu Değerlendirme Raporu Ekleri

VİŞNE MADENCİLİK ÜRETİM SANAYİ VE TİC. A.Ş.

1:2000 ÖLÇEKLİ DETAY MADEN JEOLOJİ HARİTASI

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MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT2330310

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240318

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240318

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240319

ADDITIONAL COMMENTS / Ek Açıklamalar

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO : 3063757-0003) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240319

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240324

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240324

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240325

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

CERTIFICATE OF ANALYSIS AGT240325

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240326

WGHT Received Sample Weight

ADDITIONAL COMMENTS / Ek Açıklamalar

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO:3063757-0006) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240326

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240327

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240327

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240328

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

ADDITIONAL COMMENTS / Ek Açıklamalar

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO:3063757-0008) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240328

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240329

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish PREP70-500 Dry at 80 degree, crush 1 kg 70% < 2 mm / pulverization 500 g. 85% < 75

ADDITIONAL COMMENTS / Ek Açıklamalar

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO:3063757-0009) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240329

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240330

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240330

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240331

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240331

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240332

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

ADDITIONAL COMMENTS / Ek Açıklamalar

Client : VİŞNE MAD.ÜRETİM SAN. VE TİC.A.Ş. Project : 3063757 (BATCH NO:3063757-0012) Report Date : 25.01.2024 Page : 2 of 2

CERTIFICATE OF ANALYSIS AGT240332

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240333

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240333

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240334

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240334

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240335

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240335

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240336

MÜŞTERİ BİLGİLERİ / CLIENT JOB INFORMATION LABORATUVAR PROSEDÜRLERİ / LABORATORY PROCEDURES WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

CERTIFICATE OF ANALYSIS AGT240336

CERTIFICATE OF ANALYSIS /ANALİZ RAPORU AGT240337

WGHT Received Sample Weight XRF WR-01 XRF Press Pellet WM LOI1000 Wet Method / Grav. Finish

ADDITIONAL COMMENTS / Ek Açıklamalar

CERTIFICATE OF ANALYSIS AGT240337

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