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TALGA GROUP LTD — Investor Presentation 2018
Oct 23, 2018
65925_rns_2018-10-23_dc278ed3-fe20-43d5-8c3d-954a53f44656.pdf
Investor Presentation
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ASX & Media Release 24 October 2018 ASX:TLG
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Talga Graphene Silicon Product Extends Capacity of Li-ion Battery Anode
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Positive test results from Talga graphene in Li-ion battery silicon anode
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~50% higher anode capacity over commercial graphite reference, resulting in extended battery life (range) for portable and EV markets
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Development continuing under UK-based Faraday Challenge programs
Australian advanced materials technology company, Talga Resources Ltd (“ Talga ”) ( ASX:TLG ), is pleased to announce positive initial test results from the development of its graphene silicon lithium-ion (“Li-ion”) anode in the UK.
The results are the first under Talga’s UK Government funded “Safevolt” project (see ASX: TLG 26 March 2018) - a Talga-led program run in conjunction with consortia partners, Johnson Matthey, the University of Cambridge and manufacturing research group, TWI.
Under Safevolt Talga is developing a high energy graphene silicon anode product, termed Talnode™-Si, targeting significantly higher capacity than state of the art commercial graphite anodes (see Figure 1 and 2).
Highlights of initial test results include:
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~50% higher reversible capacity (~550mAh/g) than commercial graphite (~350mAh/g)
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Coloumbic efficiency of 99.3% - 99.8%
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95% reversible capacity (after 45 cycles - tests ongoing)
Major Li-ion battery manufacturers are requiring higher energy density via increasing amounts of silicon in graphite anodes, however silicon use is hindered by a range of battery life and stability problems. These test results show Talnode™-Si with graphene is effective in stabilising the silicon as it expands, maintaining battery life while enabling much higher energy density.
Talga Managing Director, Mr Mark Thompson : “We are excited to see further success as we progress development of our next generation of battery products and materials to be produced from our Swedish resources.
Talnode™ - Si will suit the growing demand for Li-ion batteries with higher capacity to extend the range of electric vehicles and work time of portable electronic devices.
We are pleased to be at the fore-front of developing a Li-ion anode product that has a fast growing future, and uses both our emerging supplies of graphene and graphite.”
Talga Resources Ltd ABN 32 138 405 419 ASX: TLG & TLGOA Germany: TGX USA: TLGRF 1st Floor, 2 Richardson St, West Perth 6005 Australia
E: [email protected] T: +61 8 9481 6667 F: +61 8 9322 1935 W: www.talgaresources.com
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Figure 1 Scanning electron microscope image of Talnode™-Si.
Figure 2 Initial capacity tests of Talnode™-Si versus commercial graphite reference.
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Project Background
The Safevolt project is an enabler for industry wanting higher Li-ion battery capacity above the level of standard graphite (exceeding maximum 372mAh/g).
In theory, a silicon anode is capable of providing approximately 10 times the gravimetric (or 3 times the volumetric energy) of the standard graphite anode Li-ion battery. However, silicon experiences drastic volume change during charge and discharge cycles, causing sharply shorter battery life and/or failure.
The three keys to solving silicon anode life issues are stabilising the silicon as it expands, maintaining conducting percolation and solid electrolyte interface control.
Market
In some commercial Li-ion batteries (for example: BTR, Panasonic, Hitachi, Maxell among others), small amounts of silicon are already added to the carbon anode to enhance cell energy.
Recently, several automotive manufacturers have stated their intent to move to higher energy-toweight ratios in their next generation battery packs and other large groups in the anode supply chain have communicated the use of silicon technologies in graphite to produce silicon oxidebased graphite, for example:
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Volkswagen - Estimates that cell energy density will increase by 25% from 2018 to 2025 and are targeting 20% silicon anodes from 2020 ( Volkswagen Modular Electric Platform presentation, Dresden Germany, 17 Sep 2018 ).
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Hitachi - Piloting a Si-graphite anode to form higher energy density batteries ( Hitachi presentation, AABC 2018, Osaka Japan ).
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BTR - The worlds largest anode manufacturer has a silicon-graphite anode in production and is looking to increase silicon loadings ( BTR presentation, Benchmark Minerals Graphite + Anodes 2018, Newport Beach USA ).
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Samsung - Has patented and begun marketing graphene coated silicon anode materials.
Ultimately, higher capacity batteries can benefit industry by extending device operating times (or range in an EV). Higher capacity can also lead to lower costs, as the increased energy density decreases the cost per unit of energy (Kw/hr) for the total battery pack. This increased capacity is a critical metric for customers, and particularly China where lucrative new energy vehicle subsidies are tied to energy density.
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China regulatory authorities stipulate higher capacity targets for automotive Li-ion batteries in its five year plan and features silicon anodes in its roadmap ( China Industrial Association of Power Sources presentation, Advanced Automotive Battery Conference 2018, Osaka Japan ).
Moving Forward
Further cycling tests and optimisation of Talnode™-Si is underway at Talga’s battery material facility in the Maxwell Centre at Cambridge University in the UK. Interim samples are being prepared for delivery to end users in Asia under confidentiality and material transfer agreements.
Progress on the other Faraday projects, “Scale-up” and “Sodium” is continuing according to plan and updates will be provided as the programs proceed through their individual project stages.
About Talga
Talga Resources Ltd is an advanced materials technology company enabling stronger, lighter and more functional products for the multi-billion dollar global coatings, battery, construction and polymer composites markets via graphene and graphite products. The company has significant advantages owing to its 100% owned unique high grade graphite deposits in Sweden and inhouse processing and product technology. Joint development programs are underway with a range of international corporations. Company website: www.talgaresources.com
For further information please contact:
Mr Mark Thompson Managing Director Talga Resources Ltd T: + 61 (08) 9481 6667
Dr Sai Shivareddy Manager Products - Energy Storage Talga Technologies Limited T: +44 (0) 1223 420416
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TECHNICAL GLOSSARY
| Anode | The negative electrode in a battery during discharge. In Li-ion batteries, it consists of graphite and other carbons coated on copper. |
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| Aqueous anode formulation |
A chemical formulation that contains graphite mixed in a water based solution which is suitable to be coated on copper and dried to leave a pure graphite based layer to form the Li-ion battery anode. |
| Battery capacity | The total battery capacity, usually expressed in mAh/g available to perform work. The actual capacity of a particular battery is determined by a number of factors, including the material properties, cut-off voltage, discharge rate, temperature, method of charge and the age and life history of the battery. |
| Battery efficiency | Refer to coulombic efficiency. |
| Battery module | An assembly of cells in series and parallel encased in a mechanical structure. |
| Capacity | Capacity represents specific energy in ampere hours (Ah) or mAh/g. Ah is the discharge current a battery can deliver over time. |
| Capacity fade/ ageing |
Permanent loss of capacity with frequent use or the passage of time due to unwanted irreversible chemical reactions in the cell. |
| Cathode | Electrode that, in effect, oxidises the anode or absorbs the electrons. During discharge, the positive electrode of a voltaic cell is the cathode. When charging, that reverses and the negative electrode of the cell is the cathode. |
| Charge | The conversion of electric energy, provided in the form of a current, into chemical energy within the cell or battery. |
| Cell | A closed electrochemical power source. The minimum unit of a battery comprised of 4 key components including cathode, anode, electrolyte and separator. Li-ion battery cells come in three different shapes (design architecture) being prismatic, cylindrical or pouch. |
| C-rate | C-rate is a measure of the rate at which a battery is charged relative to its maximum capacity. A 1C rate means that the charge current will charge the entire battery in 1 hour (60 minutes), 0.2C means complete charging is made during 5 hours (60minutes/0.2 = 5 hours) and 5C means that complete charging was made in 12 minutes (60 minutes/5 = 12 minutes). |
| Coin cell | An electrochemical device, composed of positive and negative plates and electrolyte, which is capable of storing electrical energy. It is the basic “building block” of a battery in lab scale tests using circular half or full coin shaped cells. |
| Coulombic efficiency |
The ratio (expressed as a percentage) between the energy removed from a battery during discharge compared with the energy used during charging to restore the original capacity. |
| Cylindrical cell | Components of a battery assembled inside a cylindrical metal container. |
| Discharge | The conversion of the chemical energy stored within a cell to electrical energy, and the subsequent withdrawal of this electrical energy into a load. |
| Few layer graphene (FLG) |
Stack of graphene having a total thickness of 5 layers or less. |
| Graphene | A 1-10 atom thick layer of crystalline carbon, with superlative properties of strength, conductivity and transparency. |
http://www.talgaresources.com/irm/PDF/1455/KiskamaIOCGProjectDrillingResults
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| Graphene nanoplatelets (GNP) |
Stack of graphene having a total thickness of 10-100 layers and properties of strength, conductivity and barrier properties that far exceed that of graphite. |
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| Graphite | An allotrope of carbon in which carbon has sp2 hybridisation. Can be found as a natural mineral or can be synthesised using great pressure and temperature. Natural graphite consists of many stacked layers of graphene, approximately 3 million layers of graphene per millimetre of graphite. |
| Lithium | A soft, silvery-white metallic element of the alkali group, the lightest of all metals. |
| Lithium-ion (Li-ion) | Elemental lithium devoid of an electron having an oxidation state of +1. |
| Lithium-ion battery | Rechargeable battery where Li-ion shuttles between graphitic anode and cobalt, manganese, nickel and/or other metals in combinations as cathode. |
| mAh/g | Milliampere hours per gram – a unit for battery capacity/materials. |
| Milling | The process of breaking material into small fine parts by grinding following crushing, or machining/cutting material using rotating equipment. |
| NMC | A Li-ion cathode consisting of Nickel Manganese Cobalt Oxide. |
| Packaging efficiency |
The efficiency with which the battery components (cells, electronic circuits, contacts etc.) can be packed in a given volume. |
| Percolation | The process of a liquid moving slowly through a porous substance. |
| Pouch cell | Battery cell packaged into a flat-shaped flexible, heat-sealable foil pouch. |
| Prismatic cell | A slim rectangular sealed battery cell in a metal or inflexible case. The positive and negative plates are stacked usually in a rectangular shape rather than rolled in a spiral as done in a cylindrical cell. |
| Rate capability | The rate capability specifies the speed a battery is charged or discharged. |
| Reversible capacity | The reversible capacity is the capacity that is available to the load after the electrode is formed. |
| Roll to roll fabrication |
Continuous fabrication of battery cells using rolled sheets of battery components and coating them with the active materials as they roll onto a spool for subsequent cutting and packaging into cells. |
| Shaping/ Spheronising |
The milling of graphite flakes into sub-15 micron sized spherical shaped particles to reduce size and surface area to suit formulations for Li-ion battery anodes. |
| Solid Electrolyte Interface |
A solid electrolyte interface (SEI) is a layer formed on the graphite anode that can act as a barrier, obstructing interaction and resulting in increased internal resistance and capacity loss. |
| Specific energy | Specific energy, or gravimetric energy density, defines battery capacity in weight (Wh/kg); energy density, or volumetric energy density, reflects volume in litres (Wh/l). Products requiring long runtimes at moderate load are optimised for high specific energy; the ability to deliver high current loads can be ignored. |
http://www.talgaresources.com/irm/PDF/1455/KiskamaIOCGProjectDrillingResults
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