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TALGA GROUP LTD Investor Presentation 2018

Oct 23, 2018

65925_rns_2018-10-23_dc278ed3-fe20-43d5-8c3d-954a53f44656.pdf

Investor Presentation

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ASX & Media Release 24 October 2018 ASX:TLG

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Talga Graphene Silicon Product Extends Capacity of Li-ion Battery Anode

  • Positive test results from Talga graphene in Li-ion battery silicon anode

  • ~50% higher anode capacity over commercial graphite reference, resulting in extended battery life (range) for portable and EV markets

  • Development continuing under UK-based Faraday Challenge programs

Australian advanced materials technology company, Talga Resources Ltd (“ Talga ”) ( ASX:TLG ), is pleased to announce positive initial test results from the development of its graphene silicon lithium-ion (“Li-ion”) anode in the UK.

The results are the first under Talga’s UK Government funded “Safevolt” project (see ASX: TLG 26 March 2018) - a Talga-led program run in conjunction with consortia partners, Johnson Matthey, the University of Cambridge and manufacturing research group, TWI.

Under Safevolt Talga is developing a high energy graphene silicon anode product, termed Talnode™-Si, targeting significantly higher capacity than state of the art commercial graphite anodes (see Figure 1 and 2).

Highlights of initial test results include:

  • ~50% higher reversible capacity (~550mAh/g) than commercial graphite (~350mAh/g)

  • Coloumbic efficiency of 99.3% - 99.8%

  • 95% reversible capacity (after 45 cycles - tests ongoing)

Major Li-ion battery manufacturers are requiring higher energy density via increasing amounts of silicon in graphite anodes, however silicon use is hindered by a range of battery life and stability problems. These test results show Talnode™-Si with graphene is effective in stabilising the silicon as it expands, maintaining battery life while enabling much higher energy density.

Talga Managing Director, Mr Mark Thompson : “We are excited to see further success as we progress development of our next generation of battery products and materials to be produced from our Swedish resources.

Talnode™ - Si will suit the growing demand for Li-ion batteries with higher capacity to extend the range of electric vehicles and work time of portable electronic devices.

We are pleased to be at the fore-front of developing a Li-ion anode product that has a fast growing future, and uses both our emerging supplies of graphene and graphite.”

Talga Resources Ltd ABN 32 138 405 419 ASX: TLG & TLGOA Germany: TGX USA: TLGRF 1st Floor, 2 Richardson St, West Perth 6005 Australia

E: [email protected] T: +61 8 9481 6667 F: +61 8 9322 1935 W: www.talgaresources.com

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Figure 1 Scanning electron microscope image of Talnode™-Si.

Figure 2 Initial capacity tests of Talnode™-Si versus commercial graphite reference.

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Project Background

The Safevolt project is an enabler for industry wanting higher Li-ion battery capacity above the level of standard graphite (exceeding maximum 372mAh/g).

In theory, a silicon anode is capable of providing approximately 10 times the gravimetric (or 3 times the volumetric energy) of the standard graphite anode Li-ion battery. However, silicon experiences drastic volume change during charge and discharge cycles, causing sharply shorter battery life and/or failure.

The three keys to solving silicon anode life issues are stabilising the silicon as it expands, maintaining conducting percolation and solid electrolyte interface control.

Market

In some commercial Li-ion batteries (for example: BTR, Panasonic, Hitachi, Maxell among others), small amounts of silicon are already added to the carbon anode to enhance cell energy.

Recently, several automotive manufacturers have stated their intent to move to higher energy-toweight ratios in their next generation battery packs and other large groups in the anode supply chain have communicated the use of silicon technologies in graphite to produce silicon oxidebased graphite, for example:

  • Volkswagen - Estimates that cell energy density will increase by 25% from 2018 to 2025 and are targeting 20% silicon anodes from 2020 ( Volkswagen Modular Electric Platform presentation, Dresden Germany, 17 Sep 2018 ).

  • Hitachi - Piloting a Si-graphite anode to form higher energy density batteries ( Hitachi presentation, AABC 2018, Osaka Japan ).

  • BTR - The worlds largest anode manufacturer has a silicon-graphite anode in production and is looking to increase silicon loadings ( BTR presentation, Benchmark Minerals Graphite + Anodes 2018, Newport Beach USA ).

  • Samsung - Has patented and begun marketing graphene coated silicon anode materials.

Ultimately, higher capacity batteries can benefit industry by extending device operating times (or range in an EV). Higher capacity can also lead to lower costs, as the increased energy density decreases the cost per unit of energy (Kw/hr) for the total battery pack. This increased capacity is a critical metric for customers, and particularly China where lucrative new energy vehicle subsidies are tied to energy density.

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China regulatory authorities stipulate higher capacity targets for automotive Li-ion batteries in its five year plan and features silicon anodes in its roadmap ( China Industrial Association of Power Sources presentation, Advanced Automotive Battery Conference 2018, Osaka Japan ).

Moving Forward

Further cycling tests and optimisation of Talnode™-Si is underway at Talga’s battery material facility in the Maxwell Centre at Cambridge University in the UK. Interim samples are being prepared for delivery to end users in Asia under confidentiality and material transfer agreements.

Progress on the other Faraday projects, “Scale-up” and “Sodium” is continuing according to plan and updates will be provided as the programs proceed through their individual project stages.

About Talga

Talga Resources Ltd is an advanced materials technology company enabling stronger, lighter and more functional products for the multi-billion dollar global coatings, battery, construction and polymer composites markets via graphene and graphite products. The company has significant advantages owing to its 100% owned unique high grade graphite deposits in Sweden and inhouse processing and product technology. Joint development programs are underway with a range of international corporations. Company website: www.talgaresources.com

For further information please contact:

Mr Mark Thompson Managing Director Talga Resources Ltd T: + 61 (08) 9481 6667

Dr Sai Shivareddy Manager Products - Energy Storage Talga Technologies Limited T: +44 (0) 1223 420416

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TECHNICAL GLOSSARY

Anode The negative electrode in a battery during discharge. In Li-ion batteries, it
consists of graphite and other carbons coated on copper.
Aqueous anode
formulation
A chemical formulation that contains graphite mixed in a water based solution
which is suitable to be coated on copper and dried to leave a pure graphite
based layer to form the Li-ion battery anode.
Battery capacity The total battery capacity, usually expressed in mAh/g available to perform
work. The actual capacity of a particular battery is determined by a number of
factors, including the material properties, cut-off voltage, discharge rate,
temperature, method of charge and the age and life history of the battery.
Battery efficiency Refer to coulombic efficiency.
Battery module An assembly of cells in series and parallel encased in a mechanical structure.
Capacity Capacity represents specific energy in ampere hours (Ah) or mAh/g. Ah is the
discharge current a battery can deliver over time.
Capacity fade/
ageing
Permanent loss of capacity with frequent use or the passage of time due to
unwanted irreversible chemical reactions in the cell.
Cathode Electrode that, in effect, oxidises the anode or absorbs the electrons. During
discharge, the positive electrode of a voltaic cell is the cathode. When
charging, that reverses and the negative electrode of the cell is the cathode.
Charge The conversion of electric energy, provided in the form of a current, into
chemical energy within the cell or battery.
Cell A closed electrochemical power source. The minimum unit of a battery
comprised of 4 key components including cathode, anode, electrolyte and
separator. Li-ion battery cells come in three different shapes (design
architecture) being prismatic, cylindrical or pouch.
C-rate C-rate is a measure of the rate at which a battery is charged relative to its
maximum capacity. A 1C rate means that the charge current will charge the
entire battery in 1 hour (60 minutes), 0.2C means complete charging is made
during 5 hours (60minutes/0.2 = 5 hours) and 5C means that complete
charging was made in 12 minutes (60 minutes/5 = 12 minutes).
Coin cell An electrochemical device, composed of positive and negative plates and
electrolyte, which is capable of storing electrical energy. It is the basic
“building block” of a battery in lab scale tests using circular half or full coin
shaped cells.
Coulombic
efficiency
The ratio (expressed as a percentage) between the energy removed from a
battery during discharge compared with the energy used during charging to
restore the original capacity.
Cylindrical cell Components of a battery assembled inside a cylindrical metal container.
Discharge The conversion of the chemical energy stored within a cell to electrical
energy, and the subsequent withdrawal of this electrical energy into a load.
Few layer graphene
(FLG)
Stack of graphene having a total thickness of 5 layers or less.
Graphene A 1-10 atom thick layer of crystalline carbon, with superlative properties of
strength, conductivity and transparency.

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Graphene
nanoplatelets
(GNP)
Stack of graphene having a total thickness of 10-100 layers and properties of
strength, conductivity and barrier properties that far exceed that of graphite.
Graphite An allotrope of carbon in which carbon has sp2 hybridisation. Can be found
as a natural mineral or can be synthesised using great pressure and
temperature. Natural graphite consists of many stacked layers of graphene,
approximately 3 million layers of graphene per millimetre of graphite.
Lithium A soft, silvery-white metallic element of the alkali group, the lightest of all
metals.
Lithium-ion (Li-ion) Elemental lithium devoid of an electron having an oxidation state of +1.
Lithium-ion battery Rechargeable battery where Li-ion shuttles between graphitic anode and
cobalt, manganese, nickel and/or other metals in combinations as cathode.
mAh/g Milliampere hours per gram – a unit for battery capacity/materials.
Milling The process of breaking material into small fine parts by grinding following
crushing, or machining/cutting material using rotating equipment.
NMC A Li-ion cathode consisting of Nickel Manganese Cobalt Oxide.
Packaging
efficiency
The efficiency with which the battery components (cells, electronic circuits,
contacts etc.) can be packed in a given volume.
Percolation The process of a liquid moving slowly through a porous substance.
Pouch cell Battery cell packaged into a flat-shaped flexible, heat-sealable foil pouch.
Prismatic cell A slim rectangular sealed battery cell in a metal or inflexible case. The
positive and negative plates are stacked usually in a rectangular shape rather
than rolled in a spiral as done in a cylindrical cell.
Rate capability The rate capability specifies the speed a battery is charged or discharged.
Reversible capacity The reversible capacity is the capacity that is available to the load after the
electrode is formed.
Roll to roll
fabrication
Continuous fabrication of battery cells using rolled sheets of battery
components and coating them with the active materials as they roll onto a
spool for subsequent cutting and packaging into cells.
Shaping/
Spheronising
The milling of graphite flakes into sub-15 micron sized spherical shaped
particles to reduce size and surface area to suit formulations for Li-ion battery
anodes.
Solid Electrolyte
Interface
A solid electrolyte interface (SEI) is a layer formed on the graphite anode that
can act as a barrier, obstructing interaction and resulting in increased internal
resistance and capacity loss.
Specific energy Specific energy, or gravimetric energy density, defines battery capacity in
weight (Wh/kg); energy density, or volumetric energy density, reflects volume
in litres (Wh/l). Products requiring long runtimes at moderate load are
optimised for high specific energy; the ability to deliver high current loads can
be ignored.

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