PREMIER1 LITHIUM LIMITED — Share Issue/Capital Change 2025

Nov 5, 2025

Appendix 2A - Application for quotation of securities

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Announcement Summary

Entity name

PREMIER1 LITHIUM LIMITED

Announcement Type

New announcement

Date of this announcement

Thursday November 06, 2025

The +securities to be quoted are:

+Securities issued as part of a transaction or transactions previously announced to the market in an Appendix 3B Total number of +securities to be quoted

ASX +security		Number of +securities to
code	Security description	be quoted	Issue date
PLC	ORDINARY FULLY PAID	66,200,000	06/11/2025
PLCO	OPTION EXPIRING 06-NOV-2028 DEFERRED	33,100,000	06/11/2025

Refer to next page for full details of the announcement

Appendix 2A - Application for quotation of securities

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Appendix 2A - Application for quotation of securities

Part 1 - Entity and announcement details

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1.1 Name of entity

PREMIER1 LITHIUM LIMITED

We (the entity named above) apply for +quotation of the following +securities and agree to the matters set out in Appendix 2A of the ASX Listing Rules.

1.2 Registered number type

Registration number

ABN 16637198531

1.3 ASX issuer code

PLC

1.4 The announcement is

New announcement

1.5 Date of this announcement

6/11/2025

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Appendix 2A - Application for quotation of securities

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Part 2 - Type of Issue

2.1 The +securities to be quoted are:

+Securities issued as part of a transaction or transactions previously announced to the market in an Appendix 3B

Previous Appendix 3B details: Announcement Date and Announcement Title Selected Appendix 3B to submit quotation Time request 04-Nov-2025 08:26 New - Proposed issue of securities - A placement or other type of issue PLC

2.3a.2 Are there any further issues of +securities yet to take place to complete the transaction(s) referred to in the Appendix 3B? No

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Appendix 2A - Application for quotation of securities

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Part 3A - number and type of +securities to be quoted where issue has previously been notified to ASX in an Appendix 3B

Placement Details

ASX +security code and description PLC : ORDINARY FULLY PAID

Issue date

6/11/2025

Distribution Schedule

Provide a distribution schedule for the new +securities according to the categories set out in the left hand column - including the number of recipients and the total percentage of the new +securities held by the recipients in each category.

Total percentage of +securities held Number of +securities held Number of holders For example, to enter a value of 50% please input as 50.00 1 - 1,000 % 1,001 - 5,000 % 5,001 - 10,000 % 10,001 - 100,000 % 100,001 and over %

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Appendix 2A - Application for quotation of securities

Issue details

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Number of +securities to be quoted

66,200,000

Are the +securities being issued for a cash consideration? Yes In what currency is the cash consideration being paid? What is the issue price per +security? AUD - Australian Dollar AUD 0.00500000 Any other information the entity wishes to provide about the +securities to be quoted

ASX +security code and description

PLCO : OPTION EXPIRING 06-NOV-2028 DEFERRED

Issue date

6/11/2025

Distribution Schedule

Provide a distribution schedule for the new +securities according to the categories set out in the left hand column - including the number of recipients and the total percentage of the new +securities held by the recipients in each category.

category.
		Total percentage of +securities held
Number of +securities held	Number of holders	For example, to enter a value of 50%
		please input as 50.00
1 - 1,000		%
1,001 - 5,000		%
5,001 - 10,000		%
10,001 - 100,000		%
100,001 and over		%

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Appendix 2A - Application for quotation of securities

Issue details

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Number of +securities to be quoted 33,100,000 Are the +securities being issued for a cash consideration? No Please describe the consideration being provided for the +securities Attaching option to the follow-on placement Please provide an estimate (in AUD) of the value of the consideration being provided per +security for the +securities to be quoted 0.00000001

Any other information the entity wishes to provide about the +securities to be quoted

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Appendix 2A - Application for quotation of securities

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Appendix 2A - Application for quotation of securities

Part 4 - Issued capital following quotation

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Following the quotation of the +securities the subject of this application, the issued capital of the entity will comprise:

The figures in parts 4.1 and 4.2 below are automatically generated and may not reflect the entity's current issued capital if other Appendix 2A, Appendix 3G or Appendix 3H forms are currently with ASX for processing.

4.1 Quoted +securities (total number of each +class of +securities quoted on ASX following the +quotation of the +securities subject of this application)

4.1 Quoted +securities (total number of each +class of +securities quoted +securities subject of this application)	on ASX following the +quotation of the
	Total number of
ASX +security code and description	+securities on issue
PLC : ORDINARY FULLY PAID	434,260,582
PLCN : ORDINARY FULLY PAID DEFERRED	368,060,582
PLCO : OPTION EXPIRING 06-NOV-2028 DEFERRED	217,130,291

4.2 Unquoted +securities (total number of each +class of +securities issued but not quoted on ASX)

	Total number of
ASX +security code and description	+securities on issue
PLCAF : OPTION EXPIRING 19-MAY-2026 EX $0.375	1,030,000
PLCAE : OPTION EXPIRING 11-FEB-2026 RESTRICTED	1,943,410
PLCAK : OPTION EXPIRING 25-JAN-2027 EX $0.075	6,000,000
PLCAL : OPTION EXPIRING 25-JAN-2027 EX $0.088	8,000,000
PLCAN : OPTION EXPIRING 26-JAN-2027 EX $0.105	7,500,000
PLCAM : OPTION EXPIRING 25-JAN-2027 EX $0.10	12,000,000
PLCAP : OPTION EXPIRING 01-JUN-2027 EX $0.045	7,000,000
PLCAQ : PERFORMANCE RIGHTS EXPIRING 01-JUN-2027	5,500,000
PLCAR : OPTION EXPIRING 24-DEC-2027 EX $0.016	120,262,250
PLCAG : OPTION EXPIRING 13-JUN-2026 EX $0.375	1,097,000
PLCAC : PERFORMANCE RIGHTS RESTRICTED	4,198,965
PLCAD : PERFORMANCE RIGHTS	4,204,455

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Appendix 2A - Application for quotation of securities

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Appendix 2A - Application for quotation of securities
PLCAI : OPTION EXPIRING 07-JUL-2026 EX $0.38	4,500,000
PLCAJ : OPTION EXPIRING 07-JUL-2026 EX $0.375	970,000
PLCAH : OPTION EXPIRING 14-JUN-2026 EX $0.375	800,000

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